Synonyms
Definition
A photodesorption event occurs when the absorption of a UV (or X-ray) photon by a molecule condensed on a surface results in its desorption (direct photodesorption), in the “kick-out” of a nearby molecule (indirect photodesorption), or in dissociation followed by recombination and desorption (photochemical desorption). In space, photodesorption can regulate the locations of “snow-lines,” the transition regions where the dominant phase of volatiles changes from gas to ice (particularly in protoplanetary disks). Photodesorption from ices and other surfaces that mimic interstellar grain compositions is characterized experimentally to determine molecule-specific desorption efficiencies and mechanisms.
Overview
In dense and cold regions in space, atoms and molecules freeze out on interstellar grains, forming icy mantles that continue to evolve chemically. Photodesorption connects the surface/ice chemistry with the gas phase in regions...
References and Further Reading
Andersson S, van Dishoeck EF (2008) Photodesorption of water ice. A molecular dynamics study. J Astron Astrophys 491:907–916
Andrade DPP, Rocco MLM, Boechat-Roberty HM (2010) X-ray photodesorption from methanol ice. Mon Not R Astron Soc 409:1289–1296
Avouris P, Walkup RE (1989) Fundamental mechanisms and desorption and fragmentation induced by electronic transitions at surfaces. Annu Rev Phys Chem 40:173–206
Basalgète R, Dupuy R, Féraud G, Romanzin C, Philippe L, Michaut X, Michoud J, Amiaud L, Lafosse A, Fillion J-H, Bertin M (2021a) Complex organic molecules in protoplanetary disks: X-ray photodesorption from methanol-containing ices. I. Pure methanol ices. Astron Astrophys 647:id.A35
Basalgète R, Ocaña AJ, Féraud G, Romanzin C, Philippe L, Michaut X, Fillion J-H, Bertin M (2021b) Photodesorption of acetonitrile CH3CN in UV-irradiated regions of the interstellar medium: an experimental evidence. eprint arXiv:2110.04021
Bertin M, Fayolle EC, Romanzin C, Öberg KI, Michaut X, Moudens A, Philippe L, Jeseck P, Linnartz H, Fillion J-H (2012) UV photodesorption of interstellar CO ice analogues: from excitation to surface desorption. Phys Chem Chem Phys 14:9929–9935
Cruz-Diaz GA, Martín-Doménech R, Moreno E, Caro M, Guillermo M, Chen Y-J (2018) New measurements on water ice photodesorption and product formation under ultraviolet irradiation. Mon Not R Astron Soc 474(3):3080–3089
Cruz-Diaz GA, Martín-Doménech R, Muñoz Caro GM, Chen Y-J (2016) Negligible photodesorption of methanol ice and active photon-induced desorption of its irradiation products. Astron Astrophys 592:id.A68
Dupuy R, Bertin M, Féraud G, Michaut X, Jeseck P, Doronin M, Philippe L, Romanzin C, Fillion J-H (2017) Spectrally-resolved UV photodesorption of CH4 in pure and layered ices. Astron Astrophys 603:id.A61
Dupuy R, Bertin M, Féraud G, Hassenfratz M, Michaut X, Putaud T, Philippe L, Jeseck P, Angelucci M, Cimino R, Baglin V, Romanzin C, Fillion J-H (2018) X-ray photodesorption from water ice in protoplanetary disks and X-ray-dominated regions. Nature Astron 2:796–801
Fillion J-H, Dupuy R, Féraud G, Romanzin C, Philippe L, Putaud T, Baglin V, Cimino R, Marie-Jeanne, P, Jeseck P, Michaut X, Bertin M (2021) Vacuum-UV photodesorption from compact amorphous solid water : photon energy, isotopic and temperature effects. eprint arXiv:2103.15435
Hama T, Yokoyama M, Yabushita A, Kawasaki M, Andersson S, Western CM, Ashfold MNR, Dixon RN, Watanabe N (2010) A desorption mechanism of water following vacuum-ultraviolet irradiation on amorphous solid water at 90 K. J Chem Phys 132:164508–164616
Öberg KI, Visser R, van Dishoeck EF, Linnartz H (2009a) Photodesorption of ices. II. H2O and D2O. Astrophys J 93:1209–1218
Öberg KI, van Dishoeck EF, Linnartz H (2009b) Photodesorption of ices. I. CO, N2 and CO2. J Astron Astrophys 496:281–293
Westley MS, Baragiola RA, Johnson RE, Baratta GA (1995) Photodesorption from low-temperature water ice in interstellar and circumsolar grains. Nature 373:405–407
Zhen J, Linnartz H (2014) UV-induced photodesorption and photochemistry of O2 ice. Mon Not R Astron Soc 437(4):3190–3201
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 Springer-Verlag GmbH Germany, part of Springer Nature
About this entry
Cite this entry
Öberg, K.I. (2022). Photodesorption. In: Gargaud, M., et al. Encyclopedia of Astrobiology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-27833-4_1195-5
Download citation
DOI: https://doi.org/10.1007/978-3-642-27833-4_1195-5
Received:
Accepted:
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-27833-4
Online ISBN: 978-3-642-27833-4
eBook Packages: Springer Reference Physics and AstronomyReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics
Publish with us
Chapter history
-
Latest
Photodesorption- Published:
- 16 March 2023
DOI: https://doi.org/10.1007/978-3-642-27833-4_1195-5
-
Original
Photodesorption- Published:
- 29 April 2015
DOI: https://doi.org/10.1007/978-3-642-27833-4_1195-4