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Aging and Stabilization of Polymers

  • Book
  • © 1965

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Editors:
  1. M. B. Neiman
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Table of contents (12 chapters)

  1. Front Matter

    Pages i-x
    Download chapter PDF

  2. Introduction Significance and Prospects of the Stabilization of Polymers and Articles Made from Them

    • M. B. Neiman
    Pages 1-3

  3. Mechanism of the Thermooxidative Destruction and Stabilization of Polymers

    • M. B. Neiman
    Pages 4-41

  4. Stable Radicals of Inhibitors of Oxidative Processes

    • M. B. Neiman
    Pages 42-55

  5. Synthesis of Stabilizers for Polymer Materials

    • M. B. Neiman
    Pages 56-93

  6. Aging and Stabilization of Polyolefins

    • M. B. Neiman
    Pages 94-136

  7. Aging and Stabilization of Polyformaldehyde

    • M. B. Neiman
    Pages 137-160

  8. Aging and Stabilization of Polyvinyl Chloride and Copolymers of Vinyl Chloride

    • M. B. Neiman
    Pages 161-226

  9. Aging and Stabilization of Polyamides

    • M. B. Neiman
    Pages 227-268

  10. Aging of Certain Condensation Polymers

    • M. B. Neiman
    Pages 269-291

  11. Aging of Polymers with Inorganic Principal Chains of the Molecules, Framed by Organic Groups

    • M. B. Neiman
    Pages 292-311

  12. Aging and Stabilization of Raw and Cured Rubbers

    • M. B. Neiman
    Pages 312-346

  13. Mechanochemical Processes in Highly Elastic Polymers

    • M. B. Neiman
    Pages 347-365
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Keywords

About this book

The need for a broad development of the production of polymer ma­ terials has become evident. All these materials are subject to various types of aging (destruction); hence, stabilizers which permit the stor­ age, reprocessing, and use of polymer materials without any appreci­ able change in their properties must be introduced into them. In recent years, this problem of stabilizing polymers has attracted the attention of many scientists and technologists, both in the USSR and abroad. The scientific basis of the foreign studies will be found in a number of theo­ retical premises, but chiefly the theory of chain reactions with un­ branched chains. In the Soviet Union, the concepts of Academician N. N. Semenov on chain reactions with degenerate branches have become the starting point of theoretical studies of the stabilization and destruction of polymers. Soviet scientists have developed a theory of critical concentrations of antioxidants and have shown that the processes of stabilization have a very complex chemical character. The nature of the polymers them­ selves greatly affects these processes and consequently, different stabil­ izers are required for polymers of different structures. In addition, it has been shown that the antioxidants used thus far can not only cause chain termination, but can also initiate oxidation and give rise to de­ generate branches.

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