Definitions
Wollastonite is a naturally occurring calcium silicate mineral with an acicular (needlelike) particle shape when carefully processed. The acicular shape allows it to give useful properties in many polymers, especially polypropylene, polyamides, and thermosets such as epoxies and phenolics.
Introduction
Wollastonite is named after William Hyde Wollaston (1766–1828), an English chemist and physicist who discovered the chemical elements rhodium and palladium. The mineral was named after Wollaston because he rendered outstanding services to crystallography and mineralogy.
Wollastonite is a metasilicate having an inosilicate (chain silicate) structure. It belongs to the pyroxenoid group of minerals. It is the only white acicular mineral and became famous and widely used in the industry in the 1970s–1980s as a nonhazardous replacement for asbestos fibers. The applications are widely spread reaching from additive in metallurgy (protective slag, welding electrodes) over ceramics,...
Abbreviations
- PA:
-
Polyamide
- PP:
-
Polypropylene
- PUR R-RIM:
-
Polyurethane for reinforced reaction injection molding
References
Albertson CE, Nibert RK (1984) Patentnr US4477605 A. USPTO
Anderson JN, Santosa M (1985) Patentnr US4530881 A. US/EP
Auinger T, Stadlbauerl W (2010) Increasing modulus and impact strength of high, medium and low filled submicronized wollastonite/polypropylene masterbatch compounds by injection moulding process. In: Proceedings of the polymer processing society 26th annual meeting – PPS-26. Polymer Processing Society, Banff
Beisele C (1999) Patentnr US 6001902 A. USPTO
Carr DD (1994) Industrial minerals and rocks. Society for Mining, Metallurgy, and Exploration, Littleton
Chu J, Xiang C, Sue H-J (2000) Scratch resistance of mineral-filled polypropylene materials. Polym Eng Sci 40:944–955
Grebenstein R, Hollstein W (1999) Patentnr US 5872163 A. USPTO
HPF – The Mineral Engineers (2008) Use of TREMIN 939 in friction linings. HPF – The Mineral Engineers, Frechen
HPF – The Mineral Engineers (2009) Unpublished results from DESIGNOBERFLÄCHEN II Kunststoffinstitut Lüdenscheid. HPF – The Mineral Engineers, Frechen
HPF – The Mineral Engineers (2010) Duroplaste/Thermosets. HPF – The Mineral Engineers, Frechen
HPF – The Mineral Engineers (2011) Elastomers. HPF – The Mineral Engineers, Frechen
HPF – The Mineral Engineers (2012) Special silicates in technical compounds. HPF-The Mineral Engineers, Frechen
HPF – The Mineral Engineers (2013a) Mechanical and electrical data of epoxy-composites for mid voltage applications. HPF – The Mineral Engineers, Frechen
HPF – The Mineral Engineers (2013b) Verbesserung der Eigenschaften in Polyethylenfolien durch den Einsatz von high performance fillers. HPF The Minerals Engineers, Frechen
Jacobson RE, Caulfield DF (2003) Hybrid composites: combining cellulose fibers and wollastonite mineral fibers into a nylon 6 matrix. In: The seventh international conference on woodfiber-plastic composites. Forest Products Society, Madison
Järvelä P (1986) Polyamide 6/wollastonite composites: strength properties and their dependence on humidity and temperature. J Mater Sci 21:4193–4198
Nolte-Ernsting B (2004) Wollastonit – ein Hochleistungsfüllstoff. Kunststoffe 9:261–263
R.T. Vanderbilt Company, Inc Micro-acicular wollastonite in thermoplastics. R.T. Vanderbilt Company, Norwalk
Robinson SM, Sheridan MF (2002) The advantages of wollastonite, a non-traditional filler, in fluorohydrocarbon (FKM) elastomers. In: Meeting of the rubber division, American chemical society (S. paper 16). American Chemical Society, Savannah
Shen J, Ji G (1993) Effect of filler size and surface treatment on impact and rheological properties of wollastonite-polypropylene composite. J Mater Sci Lett 12:1344–1345
Spero AR, Merchant D (2006) www.dtic.mil . Abgerufen am von. http://www.dtic.mil/cgi-bin/GetTRDoc?AD=ADA449112. Accessed 8 Mar 2013
Stamm B (1996) Filled and reinforced thermoplastic polyolefins towards engineering applications. In: Functional fillers 1996. Intertech Conferences, Portland Intertech Conferences, Houston
Švab I et al (2005) The adhesion phenomena in polypropylene/wollastonite composites. Acta Chim Slovenika 52:264–271
Virta RL (2013) U.S. geological survey, mineral commodity summaries.USGS Publishing
Xian G, Walter R (2006) Comparative study of the mechanical and wear performance of short carbon fibers and mineral particles (Wollastonite CaSiO3) filled epoxy composites. Wiley InterScience 44(5):854–863
Zilles JU (2010) Improvement of material characteristics with high performance fillers. In: Minerals in compounding. AMI Plastics, Atlanta, AMI LLC
Zilles JU, Nolte-Ernsting B (2005) HAR wollastonite fiber functional fillers. SPE conference 2005. Society of Plastics Engineers, Aachen
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Zilles, J.U. (2013). Wollastonites. In: Palsule, S. (eds) Encyclopedia of Polymers and Composites. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-37179-0_4-5
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DOI: https://doi.org/10.1007/978-3-642-37179-0_4-5
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Latest
Wollastonites- Published:
- 22 April 2016
DOI: https://doi.org/10.1007/978-3-642-37179-0_4-6
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Original
Wollastonites- Published:
- 19 March 2014
DOI: https://doi.org/10.1007/978-3-642-37179-0_4-5