Abstract
When the semiconductor is exposed to an external electromagnetic field, a phonon field, or an electric field, free carriers can be generated, resulting in semiconductivity or photoconductivity. Carriers can also be generated by high-energy particles, such as fast electrons or ions. Optical carrier generation proceeds as band-to-band direct or indirect generation or from defect levels with photons of sufficient energy. Thermal generation of free carriers is substantially enhanced by defect centers. Shallow centers may absorb a phonon of sufficient energy or a few phonons involving intermediate steps into excited states; generation from deep centers requires multiphonon-induced giant oscillations.
Generation of carriers by an electric field can at low fields be caused by the Frenkel-Poole effect: a field-enhanced thermal generation from Coulomb-attractive defect centers. At high fields, impact ionization from deep centers or band-to-band impact ionization is observed. At still higher fields in the 106 V/cm range, tunneling from deep defect centers or from the valence band occurs. Besides thickness and height of the barrier, the tunneling probability depends on the shape of the barrier potential.
Notes
- 1.
We consider n-type carriers (electrons, indicated by the index n) unless stated otherwise.
- 2.
Except for high-mobility semiconductors for excitation from shallow centers at low temperatures, where impact ionization favorably competes – see Sect. 2.2.
- 3.
This semiclassical approximation of the one-dimensional, stationary Schrödinger equation is named after G. Wentzel, H.A. Kramers, and L. Brillouin.
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Böer, K.W., Pohl, U.W. (2017). Carrier Generation. In: Semiconductor Physics. Springer, Cham. https://doi.org/10.1007/978-3-319-06540-3_29-1
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