Abstract
Graphene has been widely used in many fields due to its unique excellent mechanical, optical, thermal and electrical properties. A simple approach for reducing graphene oxide (GO) with Tea polyphenols (TP) (TRG) was developed by ultrasonic stripping-chemical reduction method. The reduction products of TRG were obtained, and Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy and X-ray-diffraction were introduced to prove the elimination of oxygen-containing groups from GO. It was found that when the weight of TP was 0.225 g, the reduction degree of GO was the highest. Besides, the thermal gravimetric analysis results showed that there was a close relationship between the reduction degree of GO and thermal stability of TRG.
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References
A.K. Geim, K.S. Novoselov, The rise of graphene. Nat. Mater. 6, 183–191 (2007)
K.S. Novoselov, A.K. Geim, S.V. Morozov, D. Jiang, Y. Zhang, S.V. Dubonos, I.V. Grigorieva, A.A. Firsov, Electric field effect in atomically thin carbon films. Science. 306, 666–669 (2004)
T. Yokoyama, J. Linder, Anomalous magnetic transport in ferromagnetic graphene junctions. Phys. Rev. B. 83, 3002–3005 (2011)
E. Cartlidge, Graphene superconductivity seen. Phys. World 28, 6–7 (2015)
C. Cao, M. Long, X. Mao, Giant magnetoresistance effect, rectifying performance and spin filters in graphene-based heterostructure. J. Comput. Theor. Nanos. 12, 4849–4854 (2015)
C. Androulidakis, G. Tsoukleri, N. Koutroumanis, G. Gkikas, P. Pappas, J. Parthenios, K. Papagelis, C. Galiotis, Carbon 81, 322–328 (2015)
S.N. Leung, M.O. Khan, H. Naguib, F. Dawson, Appl. Phys. Lett. 104, 081904 (2014)
H. Hirai, H. Tsuchiya, Y. Kamakura, N. Mori, M. Ogawa, Electron mobility calculation for graphene on substrates. J. Appl. Phys. 116, 083703–083706 (2014)
A. Deshpande, C.H. Sham, J.M.P. Alaboson, J.M. Mullin, G.C. Schatz, M.C. Hersam, J. Am. Chem. Soc. 134, 16759–16764 (2012)
R.T. Thomas, P.A. Rasheed, N. Sandhyarani, J. Colloid. Interf. Sci. 428, 214–221 (2014)
H.H. Chun, J.Y. Lee, J.H. Lee, W.K. Jo, Ind. Eng. Chem. Res. 55, 45–53 (2016)
M. Pumera, Graphene-based nanomaterials for energy storage. Energy Environ. Sci. 4, 668–674 (2011)
R. Raccichini, A. Varzi, S. Passerini, B. Scrosati, The role of graphene for electrochemical energy storage. Nat. Mater. 14, 271–279 (2015)
R. Stine, S.P. Mulvaney, J.T. Robinson, C.R. Tamanaha, P.E. Sheehan, Fabrication, optimization, and use of graphene field effect sensors. Phys. Rev. C. 85, 509–521 (2013)
S. Wu, Q. He, C. Tan, Y. Wang, H. Zhang, Graphene-based electrochemical sensors. Small 9, 1160–1172 (2013)
D. Reddy, L.F. Register, G.D. Carpenter, S.K. Banerjee, Graphene field-effect transistors. J. Phys. D: Appl. Phys. 44, 313001 (2011)
M. Zhang, C.Z. Liao, Y.L. Yao, Z.K. Liu, F.F. Gong, F. Yan, High-performance dopamine sensors based on whole graphene solution-gated transistors. Adv. Funct. Mater. 24, 978–985 (2014)
H.J. Salavagione, G. Martínez, G. Ellis, Recent advances in the covalent modification of graphene with polymers. Macromol. Rapid. Comm. 32, 1771–1789 (2011)
B.M. Yoo, H.J. Shin, H.W. Yoon, H.B. Park, Graphene and graphene oxide and their uses in barrier polymers. J. Appl. Polym. Sci. 131, 1–15 (2014)
B. Jayasena, S. Subbiah, A novel mechanical cleavage method for synthesizing few layer graphene. Nanoscale Res. Lett. 6, 95 (2011)
R.V. Lapshin, S.T.M observation of a box-shaped graphene nanostructure appeared after mechanical cleavage of pyrolytic graphite. Appl. Surf. Sci. 360, 451–460 (2016)
H. Choi, Y. Lim, M. Park, S. Lee, Y. Kang, M.S. Kim, J. Kim, M. Jeon, Precise control of chemical vapor deposition graphene layer thickness using NixCu1-x alloys. J. Mater. Chem. C. 3, 1463–1467 (2015)
T. Ciuk, P. Caban, W. Strupinski, Charge carrier concentration and offset voltage in quasi-free-standing monolayer chemical vapor deposition graphene on SiC. Carbon 101, 431–438 (2016)
J.J. Ma, Y.S. He, W.M. Zhang, J.L. Wang, X.W. Yang, X.Z. Liao, Z.F. Ma, An experimental insight into the advantages of in situ solvothermal route to construct 3D graphene-based anode materials for lithium-ion batteries. Nano Energy 16, 235–246 (2015)
Y. Lei, J. Xu, R. Li, F.F. Chen, Solvothermal synthesis of CdS-graphene composites by varying the Cd/S ratio. Ceram. Int. 41, 3158–3161 (2015)
N.T. Shelke, B.R. Karche, Ultraviolet photosensor based on few layered reduced graphene oxide nanosheets. Appl. Surf. Sci. 418, 374–379 (2017)
X.F. Li, L. Basile, B. Huang, C. Ma, J.W. Lee, I.V. Vlassiouk, A.A. Puretzky, M.W. Lin, M. Yoon, M.F. Chi, J.C. Idrobo, C.M. Rouleau, B.G. Sumpter, D.B. Geohegan, K. Xiao, Van der waals epitaxial growth of two-dimensional single-crystalline GaSe domains on graphene. ACS Nano 9, 8078–8088 (2015)
S. Haar, A. Ciesielski, J. Clough, H.F. Yang, R. Mazzaro, F. Richard, S. Conti, N. Merstorf, M. Cecchini, V. Morandi, C. Casiraghi, P. Samori, Graphene: a supramolecular strategy to leverage the liquid-phase exfoliation of graphene in the presence of surfactants: unraveling the role of the length of fatty acids. Small 11, 1691–1702 (2015)
A. Ciesielski, P. Samor, Supramolecular approaches to graphene: from self-assembly to molecule-assisted liquid-phase exfoliation. Adv. Mater. 28, 6030–6051 (2016)
S. Gurunathan, J.W. Han, E.S. Kim, J.H. Park, J.H. Kim, Reduction of graphene oxide by resveratrol: A novel and simple biological method for the synthesis of an effective anticancer nanotherapeutic molecule. Int. J. Nanomed. 10, 2951–2969 (2015)
H. Pan, Y.D. Zhang, X.D. Wang, L.G. Yu, Z.J. Zhang, Simultaneous surface modification and chemical reduction of graphene oxide using ethylene diamine. J. Nanosci. Nanotechno. 16, 2557–2563 (2016)
W.C. Ye, J. Yu, Y.X. Zhou, D.Q. Gao, D.A. Wang, C.M. Wang, D.S. Xue, Green synthesis of Pt-Au dendrimer-like nanoparticles supported on polydopamine-functionalized graphene and their high performance toward 4-nitrophenol reduction. Appl. Catal. B-Environ. 28, 258–263 (2014)
D.Z. Chen, L.D. Li, L. Guo, An environment-friendly preparation of reduced graphene oxide nanosheets via amino acid. Nanotechnology 22, 325601–325607 (2011)
M. Salavati-Niasari, M. Ranjbar, M. Sabet, Synthesis and characterization of znin2s4 nanoparticles by a facile microwave approach. J. Inorg. Organomet. Polym. Mater. 23, 452–457 (2013)
S. Thakur, N. Karak, Green reduction of graphene oxide by aqueous phytoextracts. Carbon 50, 5331–5339 (2012)
D.R. Dreyer, S. Murali, Y.W. Zhu, R.S. Ruoff, C.W. Bielawski, Reduction of graphite oxide using alcohols. J. Mater. Chem. 21, 3443–3447 (2011)
K. Kakaei, Palladium silver nanoparticle catalysts synthesis on graphene via a green reduction in tea solution for oxygen reduction reaction in PEM fuel cells. Am. J. Phar. E. 76, 1203–1214 (2014)
O. Akhavan, E. Ghaderi, A. Esfandiar, Wrapping bacteria by graphene nanosheets for isolation from environment, reactivation by sonication, and inactivation by near-infrared irradiation. J. Phys. Chem. B. 115, 6279–6288 (2011)
J.B. Liu, S.H. Fu, B. Yuan, Y.L. Li, Z.X. Deng, Toward a universal “adhesive nanosheet” for the assembly of multiple nanoparticles based on a protein-induced reduction/decoration of graphene oxide. J. Am. Chem. Soc. 132, 7279–7281 (2010)
L.C. Soo, Fabrication of glucose sensor using graphene, University Malaysia Pahang, 2015
X.W. Wang, W. Ai, N. Li, T. Yu, P. Chen, Graphene-bacteria composite for oxygen reduction and lithium ion batteries. J. Mater. Chem. A. 3, 12873–12879 (2015)
C.Z. Zhu, S.J. Guo, Y.X. Fang, S.J. Dong, Reducing sugar: new functional molecules for the green synthesis of graphene nanosheets. ACS Nano 4, 2429–2437 (2010)
M.F. Abdullah, R. Zakaria, S.H.S. Zein, Green tea polyphenol-reduced graphene oxide: derivatisation, reduction efficiency, reduction mechanism and cytotoxicity. RSC Adv. 4, 34510–34518 (2014)
H.J. Chu, C.Y. Lee, N.H. Tai, Green reduction of graphene oxide by Hibiscus sabdariffa L. to fabricate flexible graphene electrode. Carbon 80, 725–733 (2014)
Y. Feng, N.N. Feng, G.X. Du, A green reduction of graphene oxide via starch-based materials. RSC Adv. 3, 21466–21474 (2013)
J.K. Ma, X.R. Wang, Y. Liu, T. Wu, Y. Liu, Y.Q. Guo, R.Q. Li, X.Y. Sun, F. Wu, C.B. Li, J.P. Gao, Reduction of graphene oxide with l-lysine to prepare reduced graphene oxide stabilized with polysaccharide polyelectrolyte. J. Mater. Chem. A. 1, 2192–2201 (2013)
R.J. Liao, Z.H. Tang, T.F. Lin, B.C. Guo, Scalable and versatile graphene functionalized with the mannich condensate. ACS Appl. Mat. Interfaces 5, 2174–2181 (2013)
J. Li, G.Y. Xiao, C.B. Chen, R. Li, D.Y. Yan, Superior dispersions of reduced graphene oxide synthesized by using gallic acid as a reductant and stabilizer. J. Mater. Chem. A. 1, 1481–1487 (2013)
O. Akhavan, M. Kalaee, Z.S. Alavi, S.M.A. Ghiasi, A. Esfandiar, Increasing the antioxidant activity of green tea polyphenols in the presence of iron for the reduction of graphene oxide. Carbon 50, 3015–3025 (2012)
B.K. Ahn, J. Sung, Y.H. Li, N. Kim, M. Ikenberry, K. Hohn, N. Mohanty, P. Nguyen, T.S. Sreeprasad, S. Kraft, Synthesis and characterization of amphiphilic reduced graphene oxide with epoxidized methyl oleate. Adv. Mater. 24, 2123–2129 (2012)
Y. Wang, Z.X. Shi, J. Yin, Facile synthesis of soluble graphene via a green reduction of graphene oxide in tea solution and its biocomposites. ACS Appl. Mater. Interfaces 3, 1127–1133 (2011)
Acknowledgements
This work was supported by the Science and Technology Department of Sichuan Province (2017JZ0021, 2017SZ0039) and the Education Department of Sichuan Province (17ZA0298).
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Shi, L., Wang, R., Zhou, D., Liu, Y., Zhang, Y. (2018). A Simplified Ultrasonic Stripping-Chemical Reduction Method for Preparation of Graphene. In: Han, Y. (eds) Advances in Energy and Environmental Materials. CMC 2017. Springer Proceedings in Energy. Springer, Singapore. https://doi.org/10.1007/978-981-13-0158-2_96
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DOI: https://doi.org/10.1007/978-981-13-0158-2_96
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