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Equations of State for Phase Equilibrium Computations

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Supercritical Fluids

Part of the book series: NATO ASI Series ((NSSE,volume 273))

Abstract

In these lectures we review the field of volumetric equations of state for pure fluids, their origin, the mixing and combining rules that allow their application to mixtures, and the use of such models for the calculation of phase equilibrium and thermodynamic properties.

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References

  1. Sandler, S. I.; Orbey, H.; Lee, B.-I. In Models for Thermodynamic and Phase Equilibria Calculations; Sandler, S. I., ed.; Marcel Dekker: New York, 1993; Chapter 2.

    Google Scholar 

  2. Redlich, O.; Kwong, J. N. S. Chem. Rev. 1949, 44, 233.

    Article  CAS  Google Scholar 

  3. Soave, G. Chem. Eng. Sci., 1972, 27, 1197.

    Article  CAS  Google Scholar 

  4. Peng, D. Y.; Robinson, D. B. Ind. Eng. Chem. Fundam., 1976, 15, 59.

    Article  CAS  Google Scholar 

  5. Abbott, M. M. Adv. Chem. Ser., 1979, 182, 47.

    Article  CAS  Google Scholar 

  6. Patel, N. C.; Teja, A. S. Chem. Eng. Sci., 1982, 37, 463.

    Article  CAS  Google Scholar 

  7. Peneloux, A.; Rauzy, E.; Fneze, R. Fluid Phase Eq., 1982, 8, 7.

    Article  CAS  Google Scholar 

  8. Tang, S.; Sengers, J. V. Journal of Supercritical Fluids 1991, 4, 209.

    Article  CAS  Google Scholar 

  9. Hildebrand, J. H.; Prausnitz, J. M.; Scott, R. L. Regular and Related Solutions; Van Nostrand Reinhold Company: New York, 1970.

    Google Scholar 

  10. Vidal, J. J.Chem. Eng. Sci. 1978, 33, 787.

    Article  CAS  Google Scholar 

  11. Huron, M.-J.; Vidal, J. Fluid Phase Eq. 1979, 3, 255.

    Article  CAS  Google Scholar 

  12. Mollerup, J. Fluid Phase Eq. 1986 25, 323.

    Article  CAS  Google Scholar 

  13. Gupte, P. A.; Rasmussen P.; Fnedenslund, A. Ind. Eng. Chem. Fundam. 1986 25, 636.

    Article  CAS  Google Scholar 

  14. Michelsen, M. L. Fluid Phase Eq. 1990a 60, 47.

    Article  CAS  Google Scholar 

  15. Michelsen, M.L. Fluid Phase Eq. 1990b, 60, 213.

    Article  CAS  Google Scholar 

  16. Heidemann, R. A.; Kokal, S. L. Fluid Phase Eq. 1990 56, 17.

    Article  CAS  Google Scholar 

  17. Panagiotopoulos, A. Z.; Reid, R. C. New Mixing rules for Cubic Equations of State for Highly Polar Asymmetric Mixtures ACS Symposium Series 300; American Chemical Society:Washington, DC, 1986.

    Google Scholar 

  18. Michelsen, M. L.; Kistenmacher, H. Fluid Phase Eq. 1990 58, 229.

    Article  CAS  Google Scholar 

  19. Wong, D. S. H.;Sandler, S. I. AIChE J. 1992 38, 67.

    Article  Google Scholar 

  20. Wong, D. S. H.; Orbey, H.; Sandler, S.I. Ind. Eng. Chem. Res. 1992, 31, 2033.

    Article  CAS  Google Scholar 

  21. Stryjek, R.; Vera, J. H. Can. J. Chem. Eng. 1986, 64, 334.

    Article  CAS  Google Scholar 

  22. Thiesen, M. Ann. Phys. 1885, 24, 467.

    Article  Google Scholar 

  23. Kamerlingh Onnes, H. K. Archives Neelandaises 1901, 6, 874.

    Google Scholar 

  24. Mason, E. A.; Spurting, T. H., “The Virial Equation of State” In The International Encyclopedia of Physical Chemistry and Chemical Physics, Pergamon Press:Elmsford, New York, 1969.

    Google Scholar 

  25. Dymond, J. H.; Smith, E. B. The Virial Coefficients of Pure Gases and Mixtures Clarendon Press:Oxford, 1980.

    Google Scholar 

  26. Tsonopoulos, C. AIClhE J., 1974, 20, 263.

    Article  CAS  Google Scholar 

  27. Hayden J. G.; O’Connell, J. P. Ind. Eng. Chem. Process Des. Dev. 1975, 14, 209.

    Article  CAS  Google Scholar 

  28. Beattie, J. A.;Bridgeman, O. C. Proc. Am. Acad. Arts Sci. 1928, 63, 229.

    Article  Google Scholar 

  29. Benedict, M; Webb, G. B.; Rubin, L. C. J. Chem. Phys. 1940, 8, 334.

    Article  CAS  Google Scholar 

  30. Strobridge, T. R. “Thermodynamic Properties of Nitrogen from 64 to 300 K between 0.1 and 200 atm.”; NBS Technical Note (U.S.) 1962, No. 129.

    Google Scholar 

  31. Bender, E. Equations of State Exactly Representing the Phase Behavior of Pure Substances Proc. 5th Symposium on Thermophysical Properties; Amer. Soc. Mech. EngnNew York, 1970.

    Google Scholar 

  32. Starling, K. E. Hydrocarbon Process 1971, 50 (March), 101.

    CAS  Google Scholar 

  33. Jacobsen, R. T.; Stewart, R. B. J. Phys. Chem. Ref. Data 1973, 2, 757.

    Article  CAS  Google Scholar 

  34. Schmidt, R.; Wagner, W.A. Fluid Phase Eq. 1985, 19, 175.

    Article  CAS  Google Scholar 

  35. Starling, K. E.; Fitz, C. W.; Chen, Y. C.; Rondon, E.; Jacobsen, R. T.; Beyerlin, S. W.; Clarke, W. P.; Lemmon, E. GRI High Accuracy Natural Gas Equation of State for Gas Measurement Applications, 1991 Revision of AGA No. 8 Equation Gas Research Institute-Chicago, 1991.

    Google Scholar 

  36. Benedict, M.; Webb, G. B.; Rubin, L.C. J. Chem. Phys. 1942, 10, 747.

    Article  CAS  Google Scholar 

  37. Stotler, H. H.; Benedict, M. Chem. Eng. Progr. Symp. Ser. 1953, 49(6), 25.

    CAS  Google Scholar 

  38. Joffe, J. Chem. Eng. Progress 1949, 45, 160.

    CAS  Google Scholar 

  39. Starling, K. E.; Han, M. S. Hydrocarbon Process. 1972, 51(May), 129.

    CAS  Google Scholar 

  40. Pitzer, K. S. J. Am. Chem. Soc. 1955, 77, 3427.

    Article  CAS  Google Scholar 

  41. Pitzer, K. S.; Lippmann, D. Z.; Curl, Jr., R. F.; Huggins, C. M.;Petersen, D. E. J. Am. Chem. Soc. 1955, 77, 3433.

    Article  CAS  Google Scholar 

  42. Pitzer, K. S.;Curl, Jr., R. F. J. Am. Chem. Soc. 1957, 79, 2369.

    Article  CAS  Google Scholar 

  43. Curl, Jr., R. F.; Pitzer, K. S. Ind. Eng. Chem. 1958, 50, 265.

    Article  CAS  Google Scholar 

  44. Lee, B. I.;Kesler, M. G. AIChE J. 1975, 21, 510.

    Article  CAS  Google Scholar 

  45. Wu, G. Z. A.; Stiel, L. I. AIChE J. 1985, 31, 1632.

    Article  CAS  Google Scholar 

  46. Benedict, M.; Webb, G. B.; Rubin, L. C. Chem. Eng. Progress 1951, 47, 449.

    CAS  Google Scholar 

  47. Reid, R. C.; Prausnitz, J. M.; Poling, B. E. The Properties of Gases and Liquids McGraw Hill:New York, 1986.

    Google Scholar 

  48. Joback, K. G. M.S Thesis, Massachusetts Institute of Technology, Cambridge, MA, 1982.

    Google Scholar 

  49. Schwartzentruber, J.; Renon, H. Fluid Phase Eq. 1989, 52, 127.

    Article  CAS  Google Scholar 

  50. Schwartzentruber, J.;Renon, H. Ind. Eng. Chem. Res. 1989, 28, 1049.

    Article  CAS  Google Scholar 

  51. Georgeton, G. K.; Teja, A. S. Chem. Eng. Sci. 1989, 44, 2703.

    Article  CAS  Google Scholar 

  52. Kim, C.-H.; Vimalchand, P.; Donohue, M. D.; Sandler, S.I. AIChE J. 1986, 32, 1726.

    Article  CAS  Google Scholar 

  53. Cunningham, J.; Wilson, G. M. Proceedings Ann. Conv. Gas Processors Assoc. 1974, 53, 77.

    CAS  Google Scholar 

  54. Moshfeghian, M.;Shariat, A.; Erbar, J. H. Application of the PFGC-MES Equation of State to Synthetic and Natural Gas System ACS Symposium Ser. 133; American Chemical Society:Washington DC, 1980.

    Google Scholar 

  55. Nicolas, J. J.;Gubbins, K. E.; Streett, W. B.; Tildesley, D. J.Molec. Phys. 1979, 37, 1429.

    Article  CAS  Google Scholar 

  56. Hirschfelder, J. O.; Curtiss, C. F.; Bird, R. B. Molecular Theory of Gases and Liquids J. Wiley &; SonsrNew York, 1954.

    Google Scholar 

  57. Carnahan, N. F.; Starling, K. E. AIChE J. 1972, 18, 1184.

    Article  CAS  Google Scholar 

  58. Barker, J. A.; Henderson, D. J. J. Chem. Phys. 1967, 47, 4714.

    Article  CAS  Google Scholar 

  59. Weeks, J. D.;Chandler, D.; Andersen, H. C. J. Chem Phys. 1971, 54, 5237.

    Article  CAS  Google Scholar 

  60. Alder, B. J.; Young, D. A.;Mark, M. A. J. Chem. Phys. 1972, 56, 3013.

    Article  CAS  Google Scholar 

  61. Boublik, T. J. Chem. Phys. 1975, 63, 4084.

    Article  CAS  Google Scholar 

  62. Tildesley, D. J.; Streett, W. D. Molec. Phys. 1980, 41, 85.

    Article  CAS  Google Scholar 

  63. Honnell, K. G.; Hall, C. K. J. Chem. Phys. 1989, 90, 1841.

    Article  CAS  Google Scholar 

  64. Beret, S.; Prausnitz, J. M. Macromolecules 1975a, 8, 878.

    Article  CAS  Google Scholar 

  65. Beret, S.; Prausnitz, J. M. AIChE J. 1975b, 21, 1123.

    Article  CAS  Google Scholar 

  66. Donohue, M. D.; Prausnitz, J. M. AIChE J. 1978, 24, 849.

    Article  CAS  Google Scholar 

  67. Ikonomou, G. D.; Donohue, M. D. AIChE J. 1986, 32, 1716.

    Article  CAS  Google Scholar 

  68. Ikonomou, G. D.; Donohue, M. D. Fluid Phase Eq. 1987, 33, 61.

    Article  CAS  Google Scholar 

  69. Ikonomou, G. D.; Donohue, M. D. Fluid Phase Eq. 1988, 39, 129.

    Article  CAS  Google Scholar 

  70. Lee, K. H.; Lombardo, M.; Sandler, S. I. Fluid Phase Eq. 1985, 21, 177.

    Article  CAS  Google Scholar 

  71. Sandler, S. I., Fluid Phase Eq. 1985, 19, 235.

    Article  Google Scholar 

  72. Peters, C. J.;deSwaan Arons, J.; Levelt, H.; Sengers, J. M.;Gallagher, J. S. AIChE J. 1988, 34, 834.

    Article  CAS  Google Scholar 

  73. Kim, H.; Lin, H.-M.; Chao, K. C. IEC Fund. 1986, 25, 75.

    Article  CAS  Google Scholar 

  74. Chien, C. H.; Greenkorn, R. A.; Chao, K. C. AIChE J. 1983, 29, 560.

    Article  CAS  Google Scholar 

  75. Lin, H. M.; Kim, H.;Guo, T. M.; Chao, K. C. Fluid Phase Eq. 1983, 13, 143.

    Article  CAS  Google Scholar 

  76. Chen, S. S.; Kreglewski, A. Phys. Chem. 1911, 81, 1048.

    Google Scholar 

  77. Lee, M. J.; Chao, K. C. AIChE J. 1988, 34, 825.

    Article  CAS  Google Scholar 

  78. Cotterman, R. L.; Schwarz, B. J.; Prausnitz, J. M. AIChE J. 1986, 32, 1787.

    Article  CAS  Google Scholar 

  79. Cotterman, R. L.; Prausnitz, J. M. AIChE J. 1986, 32, 1799.

    Article  CAS  Google Scholar 

  80. Dimitrelis, D.; Prausnitz, J. M. Chem. Eng. Sci. 1990, 45, 1503.

    Article  CAS  Google Scholar 

  81. Chapman, W. G.; Gubbins, K. E.; Jackson, G.; Radosz, M. Ind. Eng. Chem. Res. 1990, 29, 1709.

    Article  CAS  Google Scholar 

  82. Huang, S. H.; Radosz, M. Ind. Eng. Chem. Res. 1990, 29, 2284.

    Article  CAS  Google Scholar 

  83. Werthheim, M. S. J. Stat. Phys. 1984a, 35, 19.

    Article  Google Scholar 

  84. Werthheim, M. S. J. Stat. Phys. 1984b, 35, 35.

    Article  Google Scholar 

  85. Werthheim, M. S., J. Stat. Phys. 1986a, 42, 459.

    Article  Google Scholar 

  86. Werthheim, M. S. J. Stat. Phys. 1986b, 42, 477.

    Article  Google Scholar 

  87. Wertheim, M. S. J. Chem. Phys. 1986c, 85, 2929.

    Article  CAS  Google Scholar 

  88. Chapman, W. G. J. Phys. Chem. 1990, 93, 4299.

    Article  Google Scholar 

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Author information

Authors and Affiliations

  1. Center for Molecular and Engineering Thermodynamics Department of Chemical Engineering, University of Delaware, Newark, DE, 19716, USA

    Stanley I. Sandler

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  1. Stanley I. Sandler
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Editor information

Editors and Affiliations

  1. Department of Chemical Engineering, University of Maine, Orono, Maine, USA

    Erdogan Kiran

  2. Thermophysics Division, National Institute of Standards and Technology, Gaithersburg, Maryland, USA

    Johanna M. H. Levelt Sengers

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© 1994 Springer Science+Business Media Dordrecht

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Sandler, S.I. (1994). Equations of State for Phase Equilibrium Computations. In: Kiran, E., Sengers, J.M.H.L. (eds) Supercritical Fluids. NATO ASI Series, vol 273. Springer, Dordrecht. https://doi.org/10.1007/978-94-015-8295-7_6

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  • DOI: https://doi.org/10.1007/978-94-015-8295-7_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-90-481-4427-3

  • Online ISBN: 978-94-015-8295-7

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