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One-electron ligands

  • Chapter
Organometallic Compounds

Abstract

These are considered after π-bonding ligands for several reasons. They are frequently found in complexes which contain other organic ligands, such as the π-C5H5 group. There is sometimes uncertainty whether a group should be regarded as π-ethylenic in character or bound by α-bonds. Since the bonding of π-ligands is less conventional than that of the σ-bonded 1-electron ligands, it is desirable to be familiar with the former before considering their role in complexes containing the latter. Further, a 1-electron ligand occupies essentially only one co-ordination position on the metal and therefore has less influence on the chemistry of complexes containing it than those organic ligands which occupy several co-ordination positions and whose bonding involves a larger proportion of the metal electrons. For these reasons the classification of complexes with 1-electron ligands, as given below, is diverse.

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  1. University of Durham, USA

    G. E. Coates M.A., D.Sc., F.R.I.C. (Professor of Chemistry) & K. Wade B.Sc., Ph.D. (Lecturer in Chemistry)

  2. Balliol College, Oxford, UK

    M. L. H. Green Ph.D., M.A. (Fellow and Tutor in Inorganic Chemistry)

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Coates, G.E., Green, M.L.H., Wade, K. (1968). One-electron ligands. In: Organometallic Compounds. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-6893-9_8

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