Organometallic Compounds

Volume Two. The Transition Elements

  • G. E. Coates
  • M. L. H. Green
  • K. Wade

Table of contents

  1. Front Matter
    Pages i-xiii
  2. G. E. Coates, M. L. H. Green, K. Wade
    Pages 1-6
  3. G. E. Coates, M. L. H. Green, K. Wade
    Pages 7-38
  4. G. E. Coates, M. L. H. Green, K. Wade
    Pages 39-64
  5. G. E. Coates, M. L. H. Green, K. Wade
    Pages 65-89
  6. G. E. Coates, M. L. H. Green, K. Wade
    Pages 90-164
  7. G. E. Coates, M. L. H. Green, K. Wade
    Pages 165-189
  8. G. E. Coates, M. L. H. Green, K. Wade
    Pages 203-287
  9. G. E. Coates, M. L. H. Green, K. Wade
    Pages 288-311
  10. G. E. Coates, M. L. H. Green, K. Wade
    Pages 312-348
  11. Back Matter
    Pages 349-376

About this book

Introduction

to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis­ tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.

Keywords

chromium copper gold manganese metals molybdenum nickel olefine organometallic chemistry palladium platinum rhodium silver titanium transition metal

Authors and affiliations

  • G. E. Coates
    • 1
  • M. L. H. Green
    • 2
  • K. Wade
    • 1
  1. 1.University of DurhamUSA
  2. 2.Balliol CollegeOxfordUK

Bibliographic information

  • DOI https://doi.org/10.1007/978-94-011-6893-9
  • Copyright Information Springer Science+Business Media B.V. 1968
  • Publisher Name Springer, Dordrecht
  • eBook Packages Springer Book Archive
  • Print ISBN 978-94-011-6895-3
  • Online ISBN 978-94-011-6893-9
  • About this book