Abstract
The reversible binding of cations to self-assembled monolayers of (6-mercaptohexyloxy) methyl-12-crown-4 (1) and (6-mercaptohexyloxy)methyl-15-crown-5 (2) in aqueous solutions is reported. Binding of the electrochemically inactive cations can be monitored by cyclic voltammetry and impedance spectroscopy using Ru(NH3)6 2+/3+ as“reporter ions”. As a result of the high surface density of crown ether ligands sandwich complexes are probably formed, which accounts for the observed selectivities of the monolayer.
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Flink, S., van Veggel, F.C.J.M., Reinhoudt, D.N. (1998). Binding of Metal Ions to Self-Assembled Monolayers of Crown Ethers. In: van den Berg, A., Bergveld, P. (eds) Sensor Technology in the Netherlands: State of the Art. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5010-1_48
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