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Applications of supercritical fluids in polymer analysis

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Applications of Supercritical Fluids in Industrial Analysis

Abstract

The use of supercritical fluids for chromatography and/or extraction is applicable to a wide variety of compound classes. Of all the application areas that have been investigated to date, polymers have probably bene-fitted from the use of supercritical fluids more than any other. Polymers and polymer additives that are found in foods, textiles, surfactants, cosmetics, the environment, and the petroleum industries all have become areas where supercritical fluid chromatography (SFC) and supercritical fluid extraction (SFE) are presently finding widespread acceptance and use.

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References

  • Arpino, P.J., Dillettato, D., Nguyen, K. and Bruchet, A., (1990), Investigation of antioxidants and UV stabilizers from plastics. Part 1: Comparison of HPLC and SFC; Preliminary SFC/MS study. J. High Resolut. Chromatogr., 13, 5–12.

    Article  CAS  Google Scholar 

  • Ashraf, S., Bartle, K.D., Clifford, A.A. and Moulder, R., (1991), Trace analysis of agrochemicals by SFC. J. High Resolut. Chromatogr., 14, 29–32.

    Article  CAS  Google Scholar 

  • Ashraf-Khorassani, M. and Levy, J.M., (1990), Quantitative analysis of polymer additives in low density polyethylene using SFE/SFC. J. High Resolut. Chromatogr.,13, 742–747.

    Article  CAS  Google Scholar 

  • Bartle, K.D., Boddington, T., Clifford, A.A., Cotton, N.J. and Dowle, C.J., (1991), Supercritical fluid extraction and chromatography for the determination of oligomers in poly(ethylene terephthalate) film. Anal. Chem.,63, 2371–2377.

    Article  CAS  Google Scholar 

  • Campbell, C., (1991), Some applications of SFC to petroleum additive development. Federation of Analytical Chemistry and Spectroscopy Societies, 6–11 October, 1991, Anaheim, CA, USA, paper 109.

    Google Scholar 

  • Chester, T.L., Bowling, D.J., Innis, D.P. and Pinkston, J.D., (1990), Capillary supercritical fluid chromatography at pressures above 400 atmospheres. Anal. Chem., 62, 1299–1301.

    Article  CAS  Google Scholar 

  • Cotton, N.J., Bartle, J.D., Clifford, A.A., Ashraf, S., Moulder, R. and Dowle, C.J., (1991), Analysis of low molecular weight constituents of polypropylene and other polymeric materials using on-line SFE—SFC. J. High Resolut. Chromatogr., 14, 164–168.

    Article  CAS  Google Scholar 

  • Fjeldsted, J.C., Jackson, W.P., Peaden, P.A. and Lee, M.L., (1983), Density programming in capillary SFC. J. Chromatogr. Sci., 21, 222–225.

    CAS  Google Scholar 

  • Fujimoto, C., Watanabe, T. and Jinno, K., (1989), Size exclusion chromatography of polystyrenes with supercritical dichloromethane. J. Chromatogr. Sci., 27, 325–328.

    Article  CAS  Google Scholar 

  • Geissler, P.R., (1989), Quantitative analysis of ethoxylated alcohols by SFC. J. Amer. Oil Chem. Soc., 66, 685–689.

    Article  CAS  Google Scholar 

  • Giddings, J.C., Myers, M.N., McLaren, L. and Keller, R.A., (1968), High pressure gas chromatography of nonvolatile species. Science,162, 67–73.

    Article  CAS  Google Scholar 

  • Gitterman, M. and Procaccia, I., (1983), Quantitative theory of solubility in supercritical fluids. J. Chem. Phys., 78, 2648–2654.

    Article  CAS  Google Scholar 

  • Harvey, M.C. and Stearns, S.P., (1984), High-speed switching of liquid chromatographic injection valves. Anal. Chem.,56, 837–839.

    Article  CAS  Google Scholar 

  • Hirata, Y. and Nakata, F., (1984), SFC with fused-silica packed columns. J. Chromatogr., 295, 315–320.

    Article  CAS  Google Scholar 

  • Johnson, A.E., Jr., Geissler, P.R. and Talley, L.D., (1990), Determination of relative ethoxylation rate constants from SFC analysis of ethoxylated alcohols. J. Amer. Oil Chem. Soc., 67, 123–131.

    Article  CAS  Google Scholar 

  • King, J.W., (1989), Fundamentals and applications of supercritical fluid extraction in chromatographic science. J. Chromatogr. Sci., 27, 355–364.

    CAS  Google Scholar 

  • Klesper, E. and Hartmann, W., (1977), Parameters in supercritical fluid chromatography of styrene oligomers. Polymer Lett.,15, 707–712.

    Article  CAS  Google Scholar 

  • Knowles, D.E., Nixon, L., Campbell, E.R., Later, D.W. and Richter, B.E., (1988), Industrial applications of SFC: Polymer analysis. Fresenius Z. Anal. Chem., 330, 225–228.

    Article  CAS  Google Scholar 

  • Later, D.W., Bornhop, D.J., Lee, E.D., Henion, J.D. and Wieboldt, R.C., (1988a), Detection techniques for capillary SFC. Liq. Chromatogr. Gas Chromatogr.,5, 804–816.

    Google Scholar 

  • Later, D.W., Campbell, E.R. and Richter, B.E., (1988b), Synchronised temperature/density programming in capillary supercritical fluid chromatography. J. High Resolut. Chromatogr.,11, 65–69.

    Article  CAS  Google Scholar 

  • Lee, M.L. and Markides, K.E. (Eds), (1990), Analytical Supercritical Fluid Chromatography and Extraction,Chromatography Conferences, Inc., Provo, UT, USA.

    Google Scholar 

  • Moulder, R., Kithinji, J.P., Raynor, M.W., Bartle, K.D. and Clifford, A.A., (1989), Analysis of chemical additives in polypropylene films using capillary SFC. J. High Resolut. Chromatogr., 12, 688–691.

    Article  CAS  Google Scholar 

  • Onuska, F.J. and Terry, K.A., (1988), SFC of alkylene oxide—fatty alcohol condensates: their quantification in water samples. J. High Resolut. Chromatogr.,11, 874–877.

    Article  CAS  Google Scholar 

  • Peaden, P.A. and Lee, M.L., (1983), Theoretical treatment of resolving power in open tubular column SFC. J. Chromatogr.,259, 1–16.

    Article  CAS  Google Scholar 

  • Pekay, L.A. and Olesik, S.V., (1989), SFC/FPD: determination of high molecular weight compounds. Anal. Chem., 61, 2616–2624.

    Article  CAS  Google Scholar 

  • Raynor, M.W., Bartle, K.D., Davies, I.L., Williams, A., Clifford, A.A., Chalmers, J.M. and Cook, B.W., (1988), Polymer additive characterization by capillary SFC/FTIR micro-spectrometry. Anal. Chem., 60, 427–433.

    Article  CAS  Google Scholar 

  • Richter, B.E., (1989), Molecular Weight Determination, Cooper, A.R. (Ed.). Wiley Inter-science, New York, pp. 373–390.

    Google Scholar 

  • Richter, B.E., (1991), National Meeting Assoc. Off. Anal. Chem., Phoenix, AR, USA, 12–15 August, 1991.

    Google Scholar 

  • Richter, B.E., Knowles, D.E., Andersen, M.R. and Later, D.W., (1986), Eastern Analytical Symposium,New York, NY, USA, paper 102.

    Google Scholar 

  • Richter, B.E., Knowles, D.E., Andersen, M.R., Porter, N.L., Campbell, E.R. and Later, D.W., (1988), Reproducibility in capillary SFC: Comparison of injection techniques. J. High Resolut. Chromatogr., 11, 1–5

    Article  Google Scholar 

  • Schmitz, F.P., Gemmel, B. and Leyendecker, D., (1988), Separation of 2-vinylnaphthalene oligomers by open-tubular capillary SFC. J. High Resolut. Chromatogr. 11, 339–340.

    Article  CAS  Google Scholar 

  • Sie, S.T. and Rijnders, G.W.A., (1967), High pressure GC and chromatography with supercritical fluids, II. Permeability and efficiency of packed columns with high-pressure gases as mobile fluids under conditions of incipient turbulence. Sep. Sci., 2, 699–727.

    Article  CAS  Google Scholar 

  • Wenclawiak, B.W., (1988), Negative temperature gradients for density programming in SFC. Fresenius Z. Anal. Chem., 330, 218–221.

    Article  CAS  Google Scholar 

  • White, C.M. and Houck, R.K. (1986), SFC and some of its applications: A review. J. High Resolut. Chromatogr., 9, 4–17.

    Article  Google Scholar 

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© 1993 Springer Science+Business Media Dordrecht

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Knowles, D.E., Hoge, T.K. (1993). Applications of supercritical fluids in polymer analysis. In: Dean, J.R. (eds) Applications of Supercritical Fluids in Industrial Analysis. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2146-0_5

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  • DOI: https://doi.org/10.1007/978-94-011-2146-0_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4951-1

  • Online ISBN: 978-94-011-2146-0

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