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ONE- AND TWO-QUANTUM UV PHOTO-REACTIONS IN PURE AND DOPED SILICA GLASSES. 2. GERMANIUM OXYGEN DEFICIENT CENTERS (GODC).

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Defects in SiO2 and Related Dielectrics: Science and Technology

Part of the book series: NATO Science Series ((NAII,volume 2))

Abstract

Germanium oxygen deficient centers (GODC) are the most widespread defects in the molecular network of germanosilicate glasses. UV laser induced photodecomposition of GODC plays a key role for the effect of photosensitiviy of germanosilicate glasses [1,2]. This effect involves absorption of light by GODC, photochemical modification of defects and even density of glass, and, as a result, the change of refractive index as high as 10-3-10-2 [3,4]. The UV absorption band of GODC at 242 nm corresponds to the S0—S2 transition (Fig. 1). Concentration of GODC is controlled by glass and fiber fabrication conditions [4], and may amount to as much as NGODC = 1020 cm-3.

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Authors and Affiliations

  1. Institute of Laser and Information Technologies, Russian Academy of Sciences, Pionerskaya 2, Troitsk, Moscow Region, 142190, Russia

    V.N. Bagratashvili & S. I. Tsypina

  2. Science-Research Institute of Nuclear Physics of Moscow State University, Moscow, 1 19899, Russia

    P. V. Chernov, A.O. Rybaltovskii & Yu. S. Zavorotny

Authors
  1. V.N. Bagratashvili
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  2. S. I. Tsypina
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  3. P. V. Chernov
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  4. A.O. Rybaltovskii
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  5. Yu. S. Zavorotny
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Editor information

Editors and Affiliations

  1. Dipartimento di Scienza dei Materiali, Università Milano-Bicocca, Milano, Italy

    G. Pacchioni

  2. Institute of Solid State Physics, University of Latvia, Riga, Latvia

    L. Skuja

  3. Naval Research Laboratory, Washington DC, USA

    D. L. Griscom

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Bagratashvili, V., Tsypina, S.I., Chernov, P.V., Rybaltovskii, A., Zavorotny, Y.S. (2000). ONE- AND TWO-QUANTUM UV PHOTO-REACTIONS IN PURE AND DOPED SILICA GLASSES. 2. GERMANIUM OXYGEN DEFICIENT CENTERS (GODC).. In: Pacchioni, G., Skuja, L., Griscom, D.L. (eds) Defects in SiO2 and Related Dielectrics: Science and Technology. NATO Science Series, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0944-7_18

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  • DOI: https://doi.org/10.1007/978-94-010-0944-7_18

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-6686-7

  • Online ISBN: 978-94-010-0944-7

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