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Siting and Stability of Metal Cations in Zeolites

  • Chapter
Catalysis by Unique Metal Ion Structures in Solid Matrices

Part of the book series: NATO Science Series ((NAII,volume 13))

Abstract

Zeolites containing cation-exchanged transition metal cations are effective catalysts for a variety of reactions. The distribution of metal cations amongst different cation-exchange sites depends on a variety of factors including, the charge on the cation, the Si/Al ratio of the zeolite, and the distribution of Al atoms in the zeolite framework. An overview is presented of recent theoretical efforts aimed at determining the distribution of charge- exchange sites in ZSM-5 as a function of Si/Al ratio and the stability of mono- and divalent cations located at specific charge-exchange sites. Stability is defined with reference to either reduction to metallic particles or demetallation to form metal oxide particles. The siting requirements and stability of binuclear cations, viz. [M-O-M]2+, are also examined.

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Author information

Authors and Affiliations

  1. Chemical Sciences Division, Lawrence Berkeley National Laboratory, USA

    Alexis T. Bell

  2. Department of Chemical Engineering, University of California, Berkeley, CA, 94720-1462, USA

    Alexis T. Bell

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  1. Alexis T. Bell
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Editor information

Editors and Affiliations

  1. University of Messina, Messina, Italy

    Gabriele Centi

  2. Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Blanka Wichterlová

  3. University of California at Berkeley, Berkeley, CA, USA

    Alexis T. Bell

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© 2001 Springer Science+Business Media Dordrecht

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Bell, A.T. (2001). Siting and Stability of Metal Cations in Zeolites. In: Centi, G., Wichterlová, B., Bell, A.T. (eds) Catalysis by Unique Metal Ion Structures in Solid Matrices. NATO Science Series, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-0782-5_4

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  • DOI: https://doi.org/10.1007/978-94-010-0782-5_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-6875-5

  • Online ISBN: 978-94-010-0782-5

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