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Catalysis by Unique Metal Ion Structures in Solid Matrices

From Science to Application

  • Book
  • © 2001

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Editors:
  1. Gabriele Centi

    1. University of Messina, Messina, Italy

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  2. Blanka Wichterlová

    1. Academy of Sciences of the Czech Republic, Prague, Czech Republic

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    You can also search for this editor in PubMed   Google Scholar

  3. Alexis T. Bell

    1. University of California at Berkeley, Berkeley, USA

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    You can also search for this editor in PubMed   Google Scholar

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry (NAII, volume 13)

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Table of contents (19 chapters)

  1. Front Matter

    Pages i-viii
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  2. Towards a better understanding and terminology of the Oxide / Transition Metal Complex interactions

    • J. F. Lambert, M. Che
    Pages 1-19

  3. Ion Exchange of Non-Framework Cations in Zeolites for Catalysis

    • J. N. Armor
    Pages 21-29

  4. Single Metal Ions in Host Zeolite Matrices. Structure-Activity-Selectivity-Relationships

    • B. Wichterlová, J. Dědeček, Z. Sobalík
    Pages 31-53

  5. Siting and Stability of Metal Cations in Zeolites

    • Alexis T. Bell
    Pages 55-73

  6. Mono- and Multinuclear Oxo-Cations in Zeolite Cavities

    • H.-Y. Chen, El M. El. Malki, X. Wang, W. M. H. Sachtler
    Pages 75-84

  7. Exafs Study of Fe/ZSM-5 Prepared by Chemical Vapour Deposition and Co/FER, MOR, MFI Prepared by Ion Exchange

    • L. Drozdová, P. Marturano, B. Wichterlová, A. Kogelbauer, R. Prins
    Pages 85-94

  8. Advances in the Determination of the Architecture of Active Sites in Solid Catalysts

    • G. Sankar, R. Raja, J. M. Thomas, D. Gleeson
    Pages 95-114

  9. Electronic Structure of Transition-Metal Ion Containing Zeolites

    • K. Klier
    Pages 115-133

  10. Migration of Ti and Fe from Framework to Extraframework Positions in Zeolitic Materials: Spectroscopic Studies

    • A. Zecchina, G. Berlier
    Pages 135-147

  11. Identification of Active Oxygen Species over Fe Complexes in Zeolites

    • Gennady I. Panov, Konstantin A. Dubkov, Yevgeny A. Paukshtis
    Pages 149-163

  12. Catalysis Using Guest Single and Mixed Oxides in Host Zeolite Matrices

    • G. Centi, S. Perathoner, F. Vazzana
    Pages 165-186

  13. Reactivity Theory of Zinc Cation Species in Zeolites

    • R. A. Van Santen, G. M. Zhidomirov, A. A. Shubin, A. L. Yakovlev, L. A. M. M. Barbosa
    Pages 187-204

  14. Local Site Deformations in Zeolites by the Coordination of Cu(II)

    • M. H. Groothaert, R. A. Schoonheydt, A. Delabie, K. Pierloot
    Pages 205-219

  15. Ab Initio Simulation of Cu-Species in Zeolites: Siting, Coordination, UV-Vis Spectra and Reactivity

    • Joachim Sauer, Dana Nachtigallova, Petr Nachtigall
    Pages 221-234

  16. Asymmetric Oxidation of Sulphide on Metal Ion Planted in Mesoporous MCM-41

    • Masakazu Iwamoto, Maki Yonemitsu, Hiroyuki Kunishima, Jiro Hirosumi, Nozomu Kita, Yasuhiro Tanaka
    Pages 235-248

  17. Photocatalysis of Cations Incorporated within Zeolites

    • Masaya Matsuoka, Masakazu Anpo
    Pages 249-262

  18. Direct Addition of Amine N-H to CC Triple Bonds

    • Jochen Penzien, Thomas E. Müller, Johannes A. Lercher
    Pages 263-278

  19. Immobilisation of Chiral Homogeneous Catalysts and Their Use for Oxidation and Hydrogenation Reactions

    • Wolfgang F. Hölderich, Hans H. Wagner
    Pages 279-293

  20. Catalysis by Novel Carbon-Based Materials

    • V. A. Likholobov
    Pages 295-306
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Keywords

About this book

Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices.
The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.

Editors and Affiliations

  • University of Messina, Messina, Italy

    Gabriele Centi

  • Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Blanka Wichterlová

  • University of California at Berkeley, Berkeley, USA

    Alexis T. Bell

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