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Reasons Why Organometallic Intramolecular-Coordination Five-Membered Ring Compounds Are Extremely Easily Synthesized Through Cyclometalation Reactions

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Cyclometalation Reactions

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Abstract

There are three reasons why organometallic intramolecular-coordination five-membered ring compounds are extremely easily synthesized through cyclometalation reactions: The first is metal activation by the coordination of lone electron pair of a hetero atom to a metal atom. The second is the chelate effect caused by the formation of a five-membered ring. The third is also metal activation by ligands, such as hetero atom groups (e.g., bipyridines, phosphines, and carboxylates), unsaturated groups (e.g., aryl, allyl, Cp, and Cp*), carbonyl groups, and halogen atoms (F, Cl, Br, Cl), which are bonded to a central metal atom. Many articles including title words, such as C–H activation, C–X activation, C–H functionalization, and chelation-assisted reactions, related to the abovementioned metal activation and chelate effect in cyclometalation reactions have been published recently.

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  1. Omae Research Laboratories, Sayama, Japan

    Iwao Omae

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Omae, I. (2014). Reasons Why Organometallic Intramolecular-Coordination Five-Membered Ring Compounds Are Extremely Easily Synthesized Through Cyclometalation Reactions. In: Cyclometalation Reactions. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54604-7_6

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