Abstract
Natural products and fermentation broths are complex systems. Extraction processes such as emulsion extraction, a process derived from the industrial liquid-liquid extraction, can be used to remove molecules. This chapter presents preview studies dealing with these two processes for bio-products and notably for organic acids from biomass: different parameters were described. Then, a study on eco-conception of these processes for gallic acid with bio-diluents (one hydrogenated terpene and three ethylic fatty acid esters) was presented and compared with results using dodecane, a current petrochemical diluent. A pre-study about eco-conception of liquid-liquid extraction for gallic acid was performed. An extractant as tributyl phosphate (TBP) was necessary, and extraction yield was higher with TBP diluted in ethylic fatty acid esters than in dodecane. So it is possible with esters to reduce the TBP concentration. In extraction by emulsion with the esters as diluents, there was no need of an extractant, gallic acid being slightly soluble in these esters. However, emulsion containing these bio-diluents swelled, which do not exist with dodecane.
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References
Anastas PT, Warner JC (1998) Green chemistry theory and practice. Oxford University Press, Oxford
Salic A, Tusek A, Fabek D, Rukavina I, Zelic B (2011) Aqueous two-phase extraction of polyphenols using a microchannel system – process optimization and intensification. Food Technol Biotechnol 49:495–501
Filipa A, Claudio M, Ferreira AM, Freire CSR, Silvestre AJD, Freire MG, Coutinho JAP (2012) Optimization of the gallic acid extraction using ionic-liquid-based aqueous two-phase systems. Sep Purif Technol 97:142–149
Saraji M, Mousavi F (2010) Use of hollow fiber-based liquid–liquid–liquid microextraction and high-performance liquid chromatography–diode array detection for the determination of phenolic acids in fruit juices. Food Chem 123:1310–1317
Rydberg J, Cox M, Musikas C, Choppin GR (2004) Solvent extraction: principles and practice. Marcel Dekker, New York
Li NN (1968) Separating hydrocarbons with liquid membranes. US Patent 3,410,794
Yankov D, Molinier J, Albet J, Malmary G, Kyuchoukov G (2004) Lactic acid from aqueous solutions with tri-n-octylamine dissolved in decanol and dodecane. Biochem Eng J 21:63–71
Yunhai S, Houyoung S, Deming L, Qinghua L, Dexing C, Yongchuan Z (2006) Separation of glycolic acid from glycolonitrile hydrolysate by reactive extraction with tri-n-octylamine. Sep Purif Technol 49:20–26
Jun YS, Lee EZ, Huh YS, Hong YK, Hong WH, Lee SH (2007) Kinetic study for the extraction of succinic acid with TOA in fermentation broth; effect of pH, salt and contaminated acid. Biochem Eng J 36:8–13
Keshav A, Wasewar KL, Chand S (2008) Extraction of propionic acid with tri-n-octyl amine in different diluents. Sep Purif Technol 63:179–183
Uslu H, Kirbaslar SI (2010) Extraction of aqueous of malic acid by trioctylamine extractant in various diluents. Fluid Phase Equilib 287:134–140
Alkaya E, Kaptan S, Ozkan L, Uludag-Demirer S, Demirer GN (2009) Recovery of acids from anaerobic acidification broth by liquid-liquid extraction. Chemosphere 77:1137–1142
Keshav A, Wasevar KL, Chand S (2009) Recovery of propionic acid from an aqueous stream by reactive extraction: effect of diluents. Desalination 244:12–23
Patnaik PR (1995) Liquid emulsion membranes: principles, problems and applications in fermentation processes. Biotechnol Adv 13:175–208
Nakano K, Kato S, Noritomi H, Nagahama K (1996) Extraction of polyunsaturated fatty acid ethyl esters from sardine oil using Ag+-containing o/w/o emulsion liquid membranes. J Membr Sci 110:219–227
Nakano K, Kato S, Noritomi H, Nagahama K (1997) Extraction of eicosapentaenoic acid ethyl ester from a model media using Ag(I)-containing o/w/o-type emulsion liquid membranes. J Membr Sci 136:127–139
Reis MTA, De Freitas OMF, Ferreira LM, Carvalho JMR (2006) Extraction of 2-(4-hydroxyphenyl)ethanol from aqueous solution by emulsion liquid membranes. J Membr Sci 269:161–170
Lee SC (2008) Development of a more efficient emulsion liquid membrane system with a dilute polymer solution for extraction of penicillin G. J Ind Eng Chem 14:207–212
Lee SC (2011) Extraction of succinic acid from simulated media by emulsion liquid membranes. J Membr Sci 381:237–243
Chanuya BS, Rastogi NK (2013) Extraction of alcohol from wine and color extracts using liquid emulsion membrane. Sep Purif Technol 105:41–47
Lee SC (2013) Development of an emulsion liquid membrane system for removal of acetic acid from xylose and sulfuric acid on a simulated hemicellulosic hydrolysate. Sep Purif Technol 118:540–546
Berrios J, Pyle DL, Aroca G (2010) Gibberellic acid extraction from aqueous solutions and fermentation froths by using emulsion liquid membranes. J Membr Sci 348:91–98
Vicente G, Paiva A, Fornari T, Najdanovic-Visak V (2011) Liquid-liquid equilibria for separation of tocopherol from olive oil using ethyl lactate. Chem Eng J 172:879–884
Wang W, Yang H, Liu Y, Cui H, Chen J (2011) The application of biodiesel and sec-octylphenoxyacetic acid (CA-12) for the yttrium separation. Hydrometallurgy 109:47–53
Datta S, Bals BD, Lin Y, Negri MC, Datta R, Pasieta L, Ahmad SF, Moradia A, Dale BE, Snyder SW (2010) An attempt towards simultaneous biobased solvent based extraction of proteins and enzymatic saccharification of cellulosic materials from distiller’s grains and soluble. Bioresour Technol 101:5444–5448
Graille J (2003) Lipides et corps gras alimentaires. Tec et Doc, Paris
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This work was financially supported by the “Conseil Général de la Marne” in France.
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Ho Yim, K., Stambouli, M., Pareau, D. (2014). Emulsion Extraction of Bio-products: Influence of Bio-diluents on Extraction of Gallic Acid. In: Chemat, F., Vian, M. (eds) Alternative Solvents for Natural Products Extraction. Green Chemistry and Sustainable Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-43628-8_10
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DOI: https://doi.org/10.1007/978-3-662-43628-8_10
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