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Primary and Secondary Radicals in Thymine Derivatives: Solid State ESR/ENDOR Study of 1-Me-Thymine and Thymidine

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The Early Effects of Radiation on DNA

Part of the book series: NATO ASI Series ((ASIH,volume 54))

Abstract

Single crystals of thymidine (Td) and 1-methylthymine (1MT) have been studied using ESR, ENDOR and FSE techniques subsequent to x-irradition at 8 K. Four base-centered radicals were identified in both systems. In addition, an alkoxy radical and a Cl1 H-abstraction radical were observed in Td (Sagstuen et al. 1989).

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References

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  • Sagstuen E, Hole EO, Nelson WH, Close DM (1989) Structure of the primary reduction product of thymidine after x-irradiation at 10 K. J Phys Chem 93:5974–5977

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© 1991 Springer-Verlag Berlin Heidelberg

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Hole, E.O., Sagstuen, E., Nelson, W.H., Close, D.M. (1991). Primary and Secondary Radicals in Thymine Derivatives: Solid State ESR/ENDOR Study of 1-Me-Thymine and Thymidine. In: Fielden, E.M., O’Neill, P. (eds) The Early Effects of Radiation on DNA. NATO ASI Series, vol 54. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-75148-6_45

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  • DOI: https://doi.org/10.1007/978-3-642-75148-6_45

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-75150-9

  • Online ISBN: 978-3-642-75148-6

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