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Silicon–Nitrogen Dehydrocoupling

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Group 2 Mediated Dehydrocoupling

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Abstract

Silicon–nitrogen coupling is a reaction of significant interest. Compounds containing Si–N bonds are utilised as silylating agents [1], bases [2], ligands and ceramic precursors [3] and furthermore silanes act as protecting groups for amides, and vice versa [4]. Current synthetic routes to these compounds rely on the atom uneconomical aminolysis of chlorosilanes yielding the desired product and HCl, which creates highly acidic reaction conditions, reducing functional group tolerance and acts as a waste stream [5].

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  1. Department of Chemistry, University of Bath, Bath, UK

    David J. Liptrot

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Liptrot, D.J. (2016). Silicon–Nitrogen Dehydrocoupling. In: Group 2 Mediated Dehydrocoupling. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-21036-0_3

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