Group 2 Mediated Dehydrocoupling

  • David J. Liptrot

Part of the Springer Theses book series (Springer Theses)

Table of contents

  1. Front Matter
    Pages i-xv
  2. David J. Liptrot
    Pages 1-40
  3. David J. Liptrot
    Pages 41-61
  4. David J. Liptrot
    Pages 63-101
  5. David J. Liptrot
    Pages 103-129
  6. David J. Liptrot
    Pages 147-147
  7. David J. Liptrot
    Pages 149-150
  8. Back Matter
    Pages 151-162

About this book

Introduction

This book presents an in-depth study into the utility of σ-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner.  Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with σ-bond metathesis allows a novel hydrogen release from silanes.

Keywords

Boron-nitrogen dehydrocoupling Group 2 Hydrogen storage S-block hydrides Sigma-bond metathesis Silicon-nitrogen dehydrocoupling Single electron transfer

Authors and affiliations

  • David J. Liptrot
    • 1
  1. 1.Department of ChemistryUniversity of BathBathUnited Kingdom

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-319-21036-0
  • Copyright Information Springer International Publishing Switzerland 2016
  • Publisher Name Springer, Cham
  • eBook Packages Chemistry and Materials Science
  • Print ISBN 978-3-319-21035-3
  • Online ISBN 978-3-319-21036-0
  • Series Print ISSN 2190-5053
  • Series Online ISSN 2190-5061
  • About this book
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