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Abstract

Gelation of polymers was first investigated in 1931 by Carothers who polymerized multifunctional monomers by polycondensation. He suggested that this phenomenon is a result of linking polymer molecules into a three-dimensional network of infinitely large size [2]. Since the polymer network consists of inter- and intramolecularly connected polymer chains, the entire gel network can indeed be considered as one macroscopic molecule whose size is theoretically only limited by the dimensions of the containing vessel [3].

Parts of this chapter are published as: Klinger D., Landfester K.: Stimuli-responsive microgels for the loading and release of functional compounds: fundamental concepts and applications. Polymer 53(23), 5209 (2012). Reprinted with permission from [1]. Copyright 2012 Elsevier.

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Klinger, D. (2013). Theoretical Part. In: Light-Sensitive Polymeric Nanoparticles Based on Photo-Cleavable Chromophores. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-00446-4_3

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