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Preparation and Characterization of A Binuclear Iron(III)-Hydroxo-µ-Hydroxyperoxy Complex[(PH3PO)4(HO)FeIII(HOOH)FeIII (OH)(OPPh3)4](C104)4

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Oxygen Complexes and Oxygen Activation by Transition Metals

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Abstract

The combination of [FeII(OPPh3)4](C104)2 with H2O2, m-ClC6H4C(O)OOH, Me3COOH, PhIO, PhI(OAc)2, Bu4N(IO4), O3, or NaOCl in anhydrous acetonitrile results in the formation of the binuclear complex [(Ph3PO)4(HO)FeIII(HOOH)FeIII(OH)(OPPh3)4](C104)4, 1. The same material is produced from the addition of H2O2to [FeIII(Ph3P0)4](C104)3in aceto-nitrile. The complex has been charactrized by elemental analysis; electronic, vibrational, and ESR spectroscopy; solid- and solution-phase magnetic susceptibility measurements; and electrochemistry. A mechanism is proposed for the formation of 1, and for its reactivity with halide ions.

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Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, 77843-3255, USA

    M. Steven McDowell, Lee Spencer, Paul K.-S. Tsang & Donald T. Sawyer

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  1. M. Steven McDowell
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  2. Lee Spencer
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  3. Paul K.-S. Tsang
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  4. Donald T. Sawyer
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Editors and Affiliations

  1. Texas A&M University, College Station, Texas, USA

    Arthur E. Martell  & Donald T. Sawyer  & 

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© 1988 Plenum Press, New York

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McDowell, M.S., Spencer, L., Tsang, P.KS., Sawyer, D.T. (1988). Preparation and Characterization of A Binuclear Iron(III)-Hydroxo-µ-Hydroxyperoxy Complex[(PH3PO)4(HO)FeIII(HOOH)FeIII (OH)(OPPh3)4](C104)4. In: Martell, A.E., Sawyer, D.T. (eds) Oxygen Complexes and Oxygen Activation by Transition Metals. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0955-0_34

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  • DOI: https://doi.org/10.1007/978-1-4613-0955-0_34

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4612-8263-1

  • Online ISBN: 978-1-4613-0955-0

  • eBook Packages: Springer Book Archive

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