Oxygen Complexes and Oxygen Activation by Transition Metals

1. Front Matter

   Pages i-ix

   PDF

2. Opening Remarks

   1. Opening Remarks

      • F. Basolo

      Pages 1-2

3. Dioxygen Complexes with Transition Metals

   1. Bonding of Dioxygen to Transition Metals

      • Michael B. Hall

      Pages 3-16

   2. Oxygen Binding by the Metalloproteins Hemerythrin, Hemocyanin, and Hemoglobin

      • Thomas M. Loehr

      Pages 17-32

   3. Metal Oxo Complexes and Oxygen Activation

      • Thomas J. Meyer

      Pages 33-47

   4. Kinetics of Formation of Biological Oxygen Carriers

      • Ralph G. Wilkins

      Pages 49-60

   5. Synthetic Dioxygen Carriers for Dioxygen Transport

      • Daryle H. Busch

      Pages 61-85

   6. Formation and Degradation of Cobalt Dioxygen Complexes

      • Arthur E. Martell

      Pages 87-106

   7. Reversible Complexes for the Recovery of Dioxygen

      • John A. T. Norman, Guldo P. Pez, David A. Roberts

      Pages 107-125

   8. Summary — Dioxygen Complexes with Transition Metal

      • F. Basolo

      Pages 127-128

4. Oxygen Activation by Transition Metals

   1. Summary — Oxygen Activation by Transition Metals

      • D. T. Sawyer

      Pages 129-130

   2. The Chemistry and Activation of Dioxygen Species (O2, O2 -., and HOOH) in Biology

      • Donald T. Sawyer

      Pages 131-148

   3. Oxygen Activation by Neutrophils

      • James K. Hurst

      Pages 149-174

   4. Mechanisms of Dioxygen Activation in Metal-Containing Monooxygenases: Enzymes and Model Systems

      • Joan Selverstone Valentine, Judith N. Burstyn, Lawrence D. Margerum

      Pages 175-187

   5. Radical Cation Pathways for Selective Catalytic Oxidation by Molecular Oxygen

      • Dennis P. Riley, Milton R. Smith

      Pages 189-201

   6. Vanadium Catalyzed Autoxidation of Hydrogen Sulfide

      • H. W. Gowdy, D. D. Delaney, D. M. Fenton

      Pages 203-213

   7. Copper Catalyzed Oxidative Carbonylation of Methanol to Dimethyl Carbonate

      • G. Lee Curnutt, A. Dale Harley

      Pages 215-232

   8. Dependence of Reaction Pathways and Product Distribution on the Oxidation State of Palladium Catalysts for the Reactions of Olefinic and Aromatic Substrates with Molecular Oxygen

      • James E. Lyons

      Pages 233-251

   9. Oxygen Activation and Oxidation Reactions on Metal Surfaces

      • Robert J. Madix

      Pages 253-264

   10. Methane Oxidation at Metal Oxide Surfaces

       • J. H. Lunsford

       Pages 265-272

This monograph consists of manuscripts, summary statements, and poster abstracts submitted by invited speakers and poster contributors who participated in the symposium "Oxygen Complexes and Oxygen Activation by Transition Metals," held March 23-26, 1987, at Texas A&M University. This meeting was the fifth annual international symposium sponsored by the Texas A&M Industry-University Cooperative Chemistry Program (IUCCP). The co­ chairmen of the conference were Professors Arthur E. Martell and Donald T. Sawyer of the Texas A&M University Chemistry Department. The program was developed by an academic-industrial steering committee consisting of the co-chairmen and members appointed by the sponsoring chemical companies Dr. James F. Bradzil, The Standard Oil Company, Ohio; Dr. Jerry R. Ebner, Monsanto Company; Dr. Craig Murchison, Dow Chemical Company; Dr. Donald C. Olsen, Shell Development Company; Dr. Tim R. Ryan, Celanese Chemical Company; and Dr. Ron Sanderson, Texaco Chemical Company. The subject of this conference reflects the intense interest that has developed in academic institutions and industry on several aspects of dioxygen chemistry. These include the formation of dioxygen complexes and their applications in facilitated transport and oxygen separation; homo­ geneous and heterogeneous catalysis of oxidation; and oxygenation of organic substrates by molecular oxygen. The conference differs in two respects from several other symposia on dioxygen chemistry held during the past few years. First, there is extensive industrial participation, especially with respect to oxygen activation.

• Calcium
• Oxidation
• base
• biology
• catalysis
• chemistry
• development
• enzymes
• metals
• oxygen
• protein
• proteins
• synthesis
• transition metal
• transport

• Texas A&M University, College Station, USA

  Arthur E. Martell, Donald T. Sawyer

Policies and ethics