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Aminations with Hypervalent Iodine

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Hypervalent Iodine Chemistry

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 373))

Abstract

Recent progress in the area of hypervalent iodine-mediated and catalyzed amination reaction of hydrocarbons is reviewed. These reactions comprise processes under both intra and intermolecular control and include the functionalization of aromatic C–H bonds as well as conversion of sp-, sp2-, and sp3-hybridized carbon atoms. These developments demonstrate that hypervalent iodine(III) methodology has reached a high level in amination chemistry. The individual reactions are discussed with a focus on mechanistic details and emphasis is made to the underlying hypervalent iodine reagents, for which structural information is available.

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Author information

Authors and Affiliations

  1. Institute of Chemical Research of Catalonia (ICIQ), 16 Avgda. Països Catalans, 43007, Tarragona, Spain

    Kilian Muñiz

  2. Catalan Institution for Research and Advanced Studies (ICREA), Pg. Lluís Companys 23, 08010, Barcelona, Spain

    Kilian Muñiz

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  1. Kilian Muñiz
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Correspondence to Kilian Muñiz .

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Editors and Affiliations

  1. School of Chemistry, Cardiff University , Cardiff, United Kingdom

    Thomas Wirth

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Muñiz, K. (2015). Aminations with Hypervalent Iodine. In: Wirth, T. (eds) Hypervalent Iodine Chemistry. Topics in Current Chemistry, vol 373. Springer, Cham. https://doi.org/10.1007/128_2015_663

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