Hypervalent Iodine Chemistry

1. Front Matter

   Pages i-viii

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2. Hypervalent Iodine-Induced Oxidative Couplings (New Metal-Free Coupling Advances and Their Applications in Natural Product Syntheses)

   • Toshifumi Dohi, Yasuyuki Kita

   Pages 1-23

3. Phenol Dearomatization with Hypervalent Iodine Reagents

   • Stéphane Quideau, Laurent Pouységu, Philippe A. Peixoto, Denis Deffieux

   Pages 25-74

4. Oxidative Heterocycle Formation Using Hypervalent Iodine(III) Reagents

   • Sandip Murarka, Andrey P. Antonchick

   Pages 75-104

5. Aminations with Hypervalent Iodine

   • Kilian Muñiz

   Pages 105-133

6. Arylation with Diaryliodonium Salts

   • Berit Olofsson

   Pages 135-166

7. Iodanes as Trifluoromethylation Reagents

   • Natalja Früh, Julie Charpentier, Antonio Togni

   Pages 167-186

8. Alkynylation with Hypervalent Iodine Reagents

   • Jerome Waser

   Pages 187-222

9. Rearrangements Induced by Hypervalent Iodine

   • Gaëtan Maertens, Sylvain Canesi

   Pages 223-241

10. Asymmetric Synthesis with Hypervalent Iodine Reagents

    • Ravi Kumar, Thomas Wirth

    Pages 243-261

11. Organoiodine(III) Reagents as Active Participants and Ligands in Transition Metal-Catalyzed Reactions: Iodosylarenes and (Imino)iodoarenes

    • John D. Protasiewicz

    Pages 263-288

12. Halogen Bonding in Hypervalent Iodine Compounds

    • Luca Catalano, Gabriella Cavallo, Pierangelo Metrangolo, Giuseppe Resnati, Giancarlo Terraneo

    Pages 289-309

13. Back Matter

    Pages 311-316

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The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

• Alkynylation
• Arylation with Salts
• Cyclic Iodane Derivatives
• Halogen Bonding
• Oxidative Coupling Reactions
• Oxidative Heterocycle formation
• Phenol Dearomatization
• Stereoselective Reactions
• Transition Metal Catalysis
• Trifluromethylation

• School of Chemistry, Cardiff University , Cardiff, United Kingdom

  Thomas Wirth

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