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Organic Solid-State Reactions

  • Fumio┬áToda

Table of contents

  1. Front Matter
    Pages i-vii
  2. Koichi Tanaka, Fumio Toda
    Pages 1-46
  3. Keiji Kobayashi
    Pages 69-107
  4. Koichi Tanaka, Fumio Toda
    Pages 109-158
  5. J. Sivaguru, J. Shailaja, S. Uppili, K. Ponchot, A. Joy, N. Arunkumar et al.
    Pages 159-188
  6. Back Matter
    Pages 269-275

About this book

Introduction

Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests "molecules do not move and reactions do not occur in the solid state", and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound.

Catalytic reactions also proceed in the solid state. Moreover, the solid-state reactions are more economical and ecologically sound. In the future, pollution-free synthetic procedures in the solid state will become increasingly important, not only in chemical industries but also in university laboratories.

Keywords

Migration crystal dynamics molecule pollution reactions

Editors and affiliations

  • Fumio┬áToda
    • 1
  1. 1.Okayama University of ScienceOkayamaJapan

Bibliographic information

  • DOI https://doi.org/10.1007/978-94-017-0089-4
  • Copyright Information Springer Science+Business Media B.V. 2002
  • Publisher Name Springer, Dordrecht
  • eBook Packages Springer Book Archive
  • Print ISBN 978-90-481-5923-9
  • Online ISBN 978-94-017-0089-4
  • Buy this book on publisher's site
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