Skip to main content
Log in

Self-Propagating High-Temperature Synthesis in a Ti−Al−C Powder System Using Different Carbon Precursors

  • Published:
Surface Engineering and Applied Electrochemistry Aims and scope Submit manuscript

Abstract

The processes associated with self-propagating high-temperature synthesis (SHS) in the Ti−Al−C powder system are studied, with hexamethylenetetramine amine (С6H12N4), polytetrafluoroethylene, and amorphous carbon (aC) used as carbon precursors. The key parameters of SHS and way the it unfolds are shown to be determined by the carbon precursor used and a technique employed for preparing initial powder samples. With the indicated carbon precursors, we are able to prepare nanostructured composite materials containing titanium carbide and the Ti2AlC MAX phase, while the Ti3AlC2 MAX phase is formed under specific conditions in the Ti−Al−С6H12N4 and Ti−Al−aC powder systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.

Similar content being viewed by others

REFERENCES

  1. Zhu, C.-C., Zhu, J., Wu, H., and Lin, H., Rare Met., 2015, vol. 34, no. 2, pp. 107–110.

    Article  Google Scholar 

  2. Varma, A., Adv. Chem. Eng., 1998, vol. 24, pp. 78–226.

    Google Scholar 

  3. Bystrzejewski, M., Szala, M., Kiciński, W., Kaszuwara, W., et al., New Carbon Mater., 2010, vol. 25, no. 2, pp. 81–88.

    Article  Google Scholar 

  4. Amosov, A.P., Borovinskaya, I.P., and Merzhanov, A.G., Poroshkovaya tekhnologiya samorasprostranyayushchegosya vysokotemperaturnogo sinteza materialov (Powder Self-Propagating High-Temperature Synthesis of Materials), Antsiferov, V.N., Ed., Moscow: Mashinostorenie, 2007.

    Google Scholar 

  5. Barsoum, M.W., El-Raghy, T. and Ali, M., Metall. Mater. Trans. A, 2000, vol. 31, pp. 1857–1865.

    Article  Google Scholar 

  6. Yan, M., Mei, B, Zhu, J., et al., Ceram. Int. J., 2008, vol. 34, no. 6, pp. 1439–1442.

    Article  Google Scholar 

  7. Starostina, A.V., Prikhna, T.A., Karpets, M.V., et al., J. Superhard Mater., 2011, vol. 33, no. 5, pp. 307–314.

    Article  Google Scholar 

  8. Prikhna, T.A., Dub, S.N., Starostina, A.V., Karpets, M.V., et al., J. Superhard Mater., 2012, vol. 34, no. 2, pp. 102–109.

    Article  Google Scholar 

  9. Nagub, M., Kurtoglu, M., Presser, V., Lu J., et al., Adv. Mater., 2011, vol. 23, no. 37, pp. 4248–4253.

    Article  Google Scholar 

  10. Syzonenko, O., Sheregii, E., Prokhorenko, S., Torpakov, A., et al., Mach., Technol., Mater., 2017, no. 4, pp. 171–173.

  11. Sizonenko, O.M., Lipyan, E.V., Zaichenko, A.D., Torpakov, A.S., Pristash, M.S., et al., UA Patent 121019, Byull. Izobret., 2017, no. 22.

  12. Kuskova, N.I., Baklar’, V.Yu., Terekhov, A.Yu., Yushchishina, A.N., et al., Surf. Eng. Appl. Electrochem., 2014, vol. 50, no. 2, pp. 101–105.

    Article  Google Scholar 

  13. Chelpanov, D.I., Kuskova, N.I., and Smal’ko, A.O., UA Patent 104443, Byull. Izobret., 2016, no. 2.

  14. Chelpanov, D.I., Baklar’, V.Yu., Kuskova, N.I., and Korzinova, A.N., Visn. Nats. Tekh. Univ. KhPI, 2016, no. 51, pp. 115–120.

  15. Rogachev, A.S. and Mukasyan, A.S., Combustion for Material Synthesis, Boca Raton, FL: CRC Press, 2014.

    Book  Google Scholar 

  16. Sheludyak, Yu.E., Kashporov, L.Ya., Malinin, L.A., and Tsalkov, V.N., Teplofizicheskie svoistva komponentov goryuchikh sistem (Thermophysical Properties of the Components of Combustible Systems), Moscow: Inform TEI, 1992.

  17. Suryanarayana, C. and Grant Norton, M., X-ray Diffraction: A Practical Approach, New York: Springer-Verlag, 1998.

    Book  Google Scholar 

  18. Mote, V., Purushotham, Y., and Dole, B., J. Theor. Appl. Phys., 2012, vol. 6, pp. 1–8.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to D. I. Chelpanov.

Additional information

Translated by A. Kukharuk

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chelpanov, D.I., Yushchishina, A.N. & Kuskova, N.I. Self-Propagating High-Temperature Synthesis in a Ti−Al−C Powder System Using Different Carbon Precursors. Surf. Engin. Appl.Electrochem. 55, 349–356 (2019). https://doi.org/10.3103/S1068375519030049

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1068375519030049

Keywords:

Navigation