Fabrication and Characterization of ZnO Nano-Clips by the Polyol-Mediated Process
- 681 Downloads
ZnO nano-clips with better monodispersion were prepared successfully using zinc acetate hydrate (Zn(OAc)2·nH2O) as Zn source and ethylene glycol (EG) as solvent by a simple solution-based route-polyol process. The effect of solution concentration on the formation of ZnO nano-clips has been investigated deeply. We first prove that the 0.01 M Zn(OAc)2·nH2O can react with EG without added water or alkaline, producing ZnO nano-clips with polycrystalline wurtzite structure at 170 °C. As-synthesized ZnO nano-clips contain a lot of aggregated nanocrystals (~ 5 to 15 nm) with high specific surface area of 88 m2/g. The shapes of ZnO nano-clips basically keep constant with improved crystallinity after annealing at 400–600 °C. The lower solution concentration and slight amount of H2O play a decisive role in ZnO nano-clip formation. When the solution concentration is ≤ 0.0125 M, the complexing and polymerization reactions between Zn(OAc)2·nH2O and EG predominate, mainly elaborating ZnO nano-clips. When the solution concentration is ≥ 0.015 M, the alcoholysis and polycondensation reactions of Zn(OAc)2·nH2O and EG become dominant, leading to ZnO particle formation with spherical and elliptical shapes. The possible growth mechanism based on a competition between complexing and alcoholysis of Zn(OAc)2·nH2O and EG has been proposed.
KeywordsZnO Nano-clips Polyol process Morphology Growth mechanism
Fourier-transform infrared spectra
Full width at half maximum
High-resolution transmission electron microscopy
Near infrared ray
Scanning electron microscopy
Transmission electron microscopy
Thermogravimetry-differential thermal gravity
Zinc oxide (ZnO) with a direct wide band gap of 3.37 eV and a large excitation binding energy of 60 meV has attracted great attention in recent years, owing to its applications in photocatalysts, solar cells, and electrical and optical devices [1, 2, 3, 4, 5, 6, 7, 8, 9, 10]. ZnO has extremely abundant nanostructures, such as nanospheres, nanorods, nanowires, and nanoflowers [11, 12, 13, 14, 15, 16]. Various synthesis methods have been utilized to produce ZnO nanostructures [17, 18, 19, 20, 21, 22]. Among these methods, solution-based polyol process exhibits splendid advantages in preparing inorganic compounds (metal, oxide, hydroxyacetate) due to the unique solvents’ characteristics, such as high boiling point (up to 250 °C) and complexing, reducing, and surfactant properties, in addition to their amphiprotic character [23, 24, 25]. In the past decades, ZnO nanoparticles with various sizes and morphologies derived from the polyol-mediated approach have been studied extensively. The processing parameters of polyol, reaction temperature and concentration, anion, hydrolysis or alkaline ratio, and additive have great influence on the size and morphology of ZnO particles [11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31]. The spherical oxide particles with the size of 20–500 nm are frequent morphologies when using ethylene glycol (EG) as solvent and Zn(OAc)2·2H2O as Zn source [23, 28, 30]. The aggregation behavior of the ZnO nanocrystal units to form polycrystalline spheres has been confirmed [18, 24, 26, 27].
In this work, we successfully prepared ZnO nano-clips for the first time by the simple polyol process with zinc acetate hydrate (Zn(OAc)2·nH2O, n < 2) and EG without additional H2O or other additives. The effect of solution concentration on morphology has been investigated deeply, and the possible growth mechanism has been proposed.
All reagents were of analytical grade and used without further purification. 9.2 mg zinc acetate hydrate (Zn(OAc)2·nH2O, n < 2) was dissolved in 5 mL ethylene glycol (EG) to obtain about 0.01 mol/L (M) colorless solution. The solution was then heated on a hot plate to 170 °C under magnetic stirring for 1–3 h. The solution began to become turbid after 6~7 min with milky floccule formation. While the reaction was over, the precipitate was centrifuged, washed several times at 2000–3000 rpm with ethanol and deionized water (volume ratio of 4:1), and dried in room temperature overnight for structural and morphological characterization. Some samples were also annealed at 400 and 600 °C for 2 h in a tube furnace with a ramp rate of 2 °C/min in air. The solutions with various Zn(OAc)2·nH2O concentrations of 0.005, 0.125, 0.015, 0.05, and 0.2 M were also prepared so as to investigate the effect of solution concentration.
The crystallinity and phases of the samples were evaluated by an X-ray diffractometer (D/max 2000, Rigaku) with Cu kα radiation (λ = 1.5405 Å). The morphological observations were performed by scanning electron microscopy (SEM; Quanta™ 50, FEI) and transmission electron microscopy (TEM; Tecnai G2 F20, Philips). The thermal stability of as-prepared samples was characterized by thermogravimetry-differential thermal gravity analyses (TG-DTG; STA 409 PC, Netszch) in the air flow with a heating rate of 20 °C/min. The Fourier-transform infrared spectra (FTIR) of as-prepared and annealed samples were collected in the 4000–400 cm− 1 range with a FTIR spectrometer (FTIR; Spectrum, PerkinElmer) using pressed KBr pellets. The Brunauer-Emmett-Teller (BET) specific surface area was estimated by the surface area apparatus (TriStar-3000, Micromeritics). In addition, the optical property of the annealed sample was also measured via an ultraviolet-visible-near infrared ray (UV–visible–NIR) spectrophotometer (UV-3600, Shimadzu).
Results and Discussion
Morphology of ZnO Nano-Clips
Structure of ZnO Nano-Clips
Figure 2b records the TG-DTG curves of as-prepared ZnO nano-clips with a heating rate of 20 °C/min in air up to 700 °C. The DTG curve shows three weight loss peaks at around 118, 180, and 400 °C, related to the volatilization of acetic acid and EG, and the severe decomposition and burning of the ester, respectively. The TG curve confirms a small amount (~ 7%) of weight loss from room temperature to 600 °C. After 600 °C, the weight basically is kept unchanged due to the complete removal of organic species in ZnO nano-clips, in accordance with the following FTIR result of ZnO sample annealed at 600 °C (Fig. 2c).
Figure 2c illustrates the FTIR spectra of as-prepared, 400 and 600 °C annealed ZnO nano-clip samples. The as-prepared product shows several absorption bands, which are ascribed to some organic groups or ZnO. The strong adsorption band at 400–600 cm− 1 originates from the stretching vibration mode of Zn–O in the low wavenumber region, demonstrating the formation of ZnO. The peak at around 800 cm− 1 is assigned to the stretching vibration mode of OH bond in alcohol, and the absorption band in the range of 1020–1090 cm− 1 belongs to C–OH bond, which indicates that the as-prepared samples contain a slight amount of polyol. The peaks at 1260 and 1727 cm− 1 result from the stretching vibration of C–O and C=O bonds, which implies the presentence of ester or glycolate in as-prepared ones. Two absorption bands at approximately 1587 and 1413 cm− 1 correspond to the asymmetric and symmetric stretching vibrations of C=O and C–O in the acetate (COO) groups, respectively [3, 20, 26]. A splitting between the asymmetric and symmetric carboxylate stretching bands (Δ) in the range 130–200 cm− 1 is typical of bridging complexes . Herein, the Δ value of 174 cm− 1 suggests the bridging bonding mode in as-synthesized ZnO nano-clips. Additionally, the small absorption peak (denoted by *) at 1343 cm− 1 is due to weakly bound acetic acid molecules, suggesting that slight acetic acid is adsorbed onto the surface of the as-synthesized ZnO nano-clips, in consistent with the previous reports [11, 26].
After 400 °C annealing, except the extremely weak absorption peak (denoted by ☆) at 1587 cm− 1 of C=O, the other IR absorption bands from HAc, ester, and EG have disappeared, in agreement with the TG-DTG results in Fig. 2b. Furthermore, the absorption band at 1628 cm− 1 is ascribed to the bending vibration of hydration or water adsorption . The weak broad band in the high wavenumber range of 3440 cm− 1 confirms the existence of hydroxyl group in the surface of metal oxide both before and after 400 °C annealing. After 600 °C annealing, the organic compounds and hydroxyl group are removed completely. Only the strong band at 434 cm− 1 from Zn–O stretching vibrations can be observed, indicating the pure ZnO formation at 600 °C. The Zn–O peak shift and broadening after 400 and 600 °C annealing might be related to the improved crystallinity, crystallite size, and reduced organic species/impurity.
Optical Property and Specific Surface Area of ZnO Nano-Clips
Figure 2d shows the UV–visible absorbance spectra of as-prepared, 400 and 600 °C annealed ZnO nano-clip samples. The inset in (d) is the corresponding curves of (αhv)2 dependence on hv. The strong absorption occurs below around 390 nm.
The direct band gap (Eg) of ZnO can be estimated by (αhv)2 = c(hv − Eg) , where α is the absorption coefficient and hv is the emission photon energy. The calculated bandgap of as-prepared, 400 and 600 °C ZnO samples is 3.24, 3.28, and 3.27 eV, respectively, in consistent with 3.2 eV of ZnO nanoparticles by polyol synthesis . Why does the bandgap increase initially and then slightly decrease with the annealing temperature? We think that several factors will be responsible for this. On the one hand, the bandgap of nanomaterials decreases with increasing the nanocrystal size. On the other hand, the crystalline powders have larger bandgap than the amorphous ones. Meanwhile, the reduced carbon impurity in metal oxide might enhance the bandgap. Based on the XRD and FTIR results, 400 °C ZnO samples have exhibited better crystallinity and lower carbon content. Although the nanocrystal size in 400 °C ZnO nano-clips becomes larger, the evidently improved crystallinity and reduced carbon impurity predominate, which lead to the increased bandgap. When further annealed in 600 °C, the slightly reduced bandgap is mainly ascribed to the grain size effect.
The specific surface area of as-prepared ZnO nano-clip is about 88 m2/g. After 400 °C annealing, it decreases to ~ 59 m2/g, which is related to the increased crystallite size, the enhanced grain density, and the decreased pores and defects after thermal treatment .
Effect of Solution Concentration on ZnO Morphology
The Possible Growth Mechanism of ZnO Nano-Clips
Under low magnification view (× 5000), ZnO samples obtained at 12 min and 2.5 h exhibit similar morphologies with feather-like aggregates in Fig. 4a, d. Further increasing the magnification (× 50,000), for a 12-min sample, we cannot observe clear features and details in Fig. 4b; however, for a 2.5-h sample, accumulated nano-clips can be seen clearly in Fig. 4e. It is worth noticing that the early morphology of nano-clip such as nano-ring or half-ring has been found in the 12-min sample in Fig. 4c. This is an important hint to explain the formation mechanism of ZnO nano-clips. Moreover, we also recognize some parts of nano-clips in the 2.5-h sample, such as nanowire, nano-stick, and unclosed clip in Fig. 4f.
In our ZnO nano-clip preparation process, the Zn(OAc)2·nH2O solution concentration is 0.01 M and evidently lower than most references [23, 24, 28, 29, 30]; meanwhile, no extra water or alkaline such as NaOH or capping agent of polyvinyl pyrrolidone (PVP) are added into 5 mL EG solvent. Moreover, our used Zn source contains relatively less water of hydrate (n < 2) due to water loss caused by longer storage. The possible formation of ZnO nano-clips can be described as follows:
Intriguing ZnO nano-clips with better monodispersion were prepared by a simple polyol-mediated route for the first time. The effect of solution concentration on the formation of ZnO nano-clips has been investigated deeply. We prove that the Zn(OAc)2·nH2O can react with EG without added water or alkaline, producing pure ZnO phase with polycrystalline wurtzite structure at 170 °C. The shape of ZnO nano-clips keeps constant with improved crystalline quality after annealing at 400–600 °C. The possible growth mechanism based on a competition between complexing and alcoholysis between Zn(OAc)2·nH2O and EG has been proposed. When the solution concentration is ≤ 0.0125 M in 5 mL solution at 170 °C, the complexing and polymerization reactions predominate, mainly elaborating ZnO nano-clips. When the solution concentration is ≥ 0.015 M, the alcoholysis and polycondensation reactions become dominant, leading to ZnO particle formation with spherical or elliptical shapes. Due to special nanostructures and larger specific surface area, ZnO nano-clips are a promising material as photocatalyst for degrading the harmful pollutants in waste water and gas, anode material of lithium battery or supercapacitor for electrochemical energy storage, and sensor for detecting dangerous gas.
This project is supported by the Natural Science Foundation of China and Jiangsu Province (51571111, 51721001, BK2016230, and BK20170645) and a grant from the State Key Program for Basic Research of China (2015CB921203), Fundamental Research Funds for the Central Universities (021314380075) and the open project of NLSSM (M30038).
Availability of Data and Materials
All data are fully available without restriction.
ADL designed the experiments. MW and ADL finished the sample fabrication and SEM and XRD characterizations. JZK measured the IR, TG-DTG, and XPS. YPG and CZ carried out the TEM tests. YFT did the BET measurements. DW participated in the discussion of the results. MW drafted the manuscript. ADL modified the manuscript and supervised all the projects. All authors read and approved the final manuscript.
The authors declare that they have no competing interests.
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
- 5.Dai H, Zhou Y, Chen L, Guo BL, Li AD, Liu JG, Yu T, Zou ZG (2013) Porous ZnO nanosheet arrays constructed on weaved metal wire for flexible dye-sensitized solar cells. Nano 5:5102–5108Google Scholar
- 14.Wang Z-L (2004) Nanostructures of zinc oxide. Materialstoday 7:26–33Google Scholar
- 22.Li C, Zhao Y, Wang L, Li G, Shi Z, Feng S (2010) Polyol-mediated synthesis of highly water-soluble ZnO colloidal nanocrystal clusters. Eur J Inorg Chem 2:217–220Google Scholar
- 34.Poul L, Jouini N, Fiévet F, Herson P (1998) A new two-dimensional alkoxy acetate of zinc: structure of μ-acetato-μ-[ethane-l,2-olato(-l)]-diacetatodizinc. Z kristallogr 213:416–418Google Scholar
- 35.Poul L (2000) Ph.D-ThesisUniversity. Pierre-Marie Curie, Paris, FranceGoogle Scholar
Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.