Skip to main content
Log in

Chemical, Phase, and Structural Transformations in the Combustion of Mixtures with Tungsten Oxide with Aluminum

  • Combustion, Explosion, and Shock Waves
  • Published:
Russian Journal of Physical Chemistry B Aims and scope Submit manuscript

Abstract

In this paper, we studied the regularities of the synthesis of cast carbide-tungsten materials in the combustion of a WO3/Al/Sa/C mixture. The combustion products of the mixture were shown to be cast tungsten carbides with an admixture of Al and an oxide solution of Al2O3-CaO, formed as two layers. A partial replacement of aluminum by calcium in the initial mixture was found to reduce the impurity content of aluminum in W-C. Cast carbide carbide-tungsten materials contain up to 2 wt % C. Their chemical and phase composition and microstructure are determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Kieffer and P. Schwarzkopf, Refractory Hard Metals (Macmillan, New York, 1953; Metallurgizdat, Moscow, 1957).

    Google Scholar 

  2. R. Kieffer and F. Benezovsky, Hartmetalle (Springer, Vienna, 1965).

    Book  Google Scholar 

  3. E. Storms, The Refractory Carbides (Academic, New York, 1967; Mir, Moscow, 1970).

    Google Scholar 

  4. G. V. Samsonov, V. K. Vitryanyuk, and F. I. Chaplygin, The Carbides of Tungsten (Nauk. Dumka, Kiev, 1974) [in Russian].

    Google Scholar 

  5. I. P. Borovinskaya, T. I. Ignat’eva, V. I. Vershinnikov, and N. V. Sachkova, Inorg. Mater. 40, 1043 (2004).

    Article  CAS  Google Scholar 

  6. State Diagrams of Refractory Oxide Systems, The Handbook, Vol. 5: Binary Systems (Nauka, Leningrad, 1985), Part 1, p. 125 [in Russian].

  7. E. A. Levashov, A. S. Rogachev, V. V. Kurbatkina, Yu. M. Maksimov, and V. I. Yukhvid, Perspective Materials and Technologies of Self-Propagating High-Temperature Synthesis (MISiS, Moscow, 2011) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. L. Silyakov.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Silyakov, S.L., Yukhvid, V.I. Chemical, Phase, and Structural Transformations in the Combustion of Mixtures with Tungsten Oxide with Aluminum. Russ. J. Phys. Chem. B 13, 96–100 (2019). https://doi.org/10.1134/S1990793119010123

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1990793119010123

Keywords

Navigation