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Thermal oxidation and structure of polylactide–polyethylene blends

  • Chemical Physics of Polymer Materials
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Abstract

The thermal oxidation of polylactide–low-density polyethylene mixtures with additives of oxidized polyethylene as an analogue of recyclable materials is studied. It is found that the polylactide is oxidized more slowly than polyethylene, whereas the introduction of up to 30 wt % of oxidized polyethylene accelerates the thermal oxidation of the mixtures, with the physical and mechanical properties of the resultant materials remaining suitable for practical use. It is established that the presence of oxidized polyethylene has virtually no effect on the melting point of polylactide and polyethylene, somewhat increasing, however, the degree of crystallinity of the components of the blend.

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References

  1. F. Cock, A. A. Cuadri, M. Garcia-Morales, and P. Partal, Polym Test. 32, 716 (2013).

    Article  CAS  Google Scholar 

  2. L. S. Shibryaeva, Yu. V. Tertyshnaya, D. D. Pal’mina, and N. S. Levina, Sel’skokhoz. Mashiny Tekhnol., No. 6, 14 (2015).

    Google Scholar 

  3. C. Chen, L. Dong, and M. K. Cheung, Eur. Polym. J. 41, 958 (2005).

    Article  CAS  Google Scholar 

  4. P. Yu. Salikov, Ekol. Prom-st' Ross., No. 3, 16 (2014).

    Google Scholar 

  5. Yu. V. Tertyshnaya and L. S. Shibryaeva, Usp. Med. Mikol. 12, 145 (2014).

    Google Scholar 

  6. M. V. Podzorova, Yu. V. Tertyshnaya, and A. A. Popov, Russ. J. Phys. Chem. B 8, 726 (2014).

    Article  CAS  Google Scholar 

  7. H. Kang, B. Qiao, R. Wang, et al., Polymer 54, 2450 (2013).

    Article  CAS  Google Scholar 

  8. L. Li, W. Huang, B. Wang, et al., Polymer 68, 183 (2015).

    Article  CAS  Google Scholar 

  9. Yu. V. Tertyshnaya, S. G. Karpova, O. V. Shatalova, A. V. Krivandin, and L. S. Shibryaeva, Polymer Sci., Ser. A 58, 50 (2016).

    Article  CAS  Google Scholar 

  10. H.T. Hsu, H. Tan, and Y. L. Yao, Polymer. Degrad. Stabil. 97, 88 (2012).

    Article  CAS  Google Scholar 

  11. Yu. V. Tertyshnaya, Extended Abstract of Cand. Sci. (Chem.) Dissertation (Inst. Biochem. Phys. RAS, Moscow, 2004).

    Google Scholar 

  12. Yu. V. Tertyshnaya, L. S. Shibryaeva, and A. A. Popov, Russ. J. Phys. Chem. B 6, 38 (2012).

    Article  CAS  Google Scholar 

  13. T. V. Monakhova, P. M. Nedorezova, S. V. Pol’shchikov, A. A. Popov, and A. L. Margolin, Russ. J. Phys. Chem. B 8, 874 (2014).

    Article  CAS  Google Scholar 

  14. L.-T. Lim, R. Auras, and M. Rubino, Prog. Polym. Sci. 33, 820 (2008).

    Article  CAS  Google Scholar 

  15. Yu. V. Tertyshnaya and L. S. Shibryaeva, Plast. Massy, No. 1, 46 (2006).

    Google Scholar 

  16. E. T. Denisov, Oxidation and Degradation of Carbochain Polymers (Khimiya, Leningrad, 1990) [in Russian].

    Google Scholar 

  17. V. V. Kireev, Polymers, the Textbook for Higher Schools (Vyssh. Shkola, Moscow, 1992) [in Russian].

    Google Scholar 

  18. A. A. Ol’khov, Cand. Sci. (Tech. Sci.) Dissertation (Mosc. Inst. Fine Chem. Technol., Moscow, 2001).

    Google Scholar 

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Correspondence to M. V. Podzorova or Yu. V. Tertyshnaya.

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Original Russian Text © M.V. Podzorova, Yu.V. Tertyshnaya, T.V. Monakhova, A.A. Popov, 2016, published in Khimicheskaya Fizika, 2016, Vol. 35, No. 9, pp. 64–69.

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Podzorova, M.V., Tertyshnaya, Y.V., Monakhova, T.V. et al. Thermal oxidation and structure of polylactide–polyethylene blends. Russ. J. Phys. Chem. B 10, 825–829 (2016). https://doi.org/10.1134/S1990793116050092

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  • DOI: https://doi.org/10.1134/S1990793116050092

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