Russian Journal of Physical Chemistry B

, Volume 9, Issue 4, pp 515–520 | Cite as

Radiative lifetimes of the ν'(13 P 2) states of the CdAr, CdKr, HgAr, HgKr, HgXe quasimolecules

  • O. S. Alekseeva
  • A. Z. Devdariani
  • M. G. Lednev
  • A. L. Zagrebin
Elementary Physicochemical Processes
  • 21 Downloads

Abstract

In the present review the results of the theoretical investigatation of the radiative lifetimes of the metastable ν'(13 P 2) states of CdAr, CdKr, HgAr, HgKr, HgXe quasimolecules as functions of the vibrational excitation degree are presented. The semiempirical interaction potential curves of Cd, Hg and rare gas (RG) atoms reconstructed from the available experimental data in the framework of the semiempirical method of quasimiolecular term analysis and the probabilities of the quasimolecular transitions which are the basis for the calculation of the radiative lifetimes are discussed.

Keywords

quasimolecular terms the interaction potential curves the radiative lifetimes transition probabilities 

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Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • O. S. Alekseeva
    • 1
  • A. Z. Devdariani
    • 2
    • 3
  • M. G. Lednev
    • 1
  • A. L. Zagrebin
    • 1
    • 2
  1. 1.Baltic State Technical University “VOENMEKH”St. PetersburgRussia
  2. 2.Fock’s Institute of PhysicsSt. Petersburg State UniversityPeterhofRussia
  3. 3.Herzen State Pedagogical University of RussiaSt. PetersburgRussia

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