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Radiative lifetimes of the ν'(13 P 2) states of the CdAr, CdKr, HgAr, HgKr, HgXe quasimolecules

  • Elementary Physicochemical Processes
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Abstract

In the present review the results of the theoretical investigatation of the radiative lifetimes of the metastable ν'(13 P 2) states of CdAr, CdKr, HgAr, HgKr, HgXe quasimolecules as functions of the vibrational excitation degree are presented. The semiempirical interaction potential curves of Cd, Hg and rare gas (RG) atoms reconstructed from the available experimental data in the framework of the semiempirical method of quasimiolecular term analysis and the probabilities of the quasimolecular transitions which are the basis for the calculation of the radiative lifetimes are discussed.

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References

  1. J. Koperski, Van der Waals Complexes in Supersonic Beams (Wiley-VCH, Weinheim, 2003).

    Google Scholar 

  2. O. S. Alekseeva, A. Z. Devdariani, M. G. Lednev, and A. L. Zagrebin, Chem. Phys. Lett. 572, 141 (2013).

    Article  CAS  Google Scholar 

  3. A. L. Zagrebin and M. G. Lednev, Opt. Spectrosc. 78, 159 (1995).

    Google Scholar 

  4. A. L. Zagrebin and M. G. Lednev, Opt. Spectrosc. 78, 681 (1995).

    Google Scholar 

  5. A. Z. Devdariani, A. L. Zagrebin, and K. B. Blagoev, Ann. Phys. Fr. 14, 467 (1989).

    Article  CAS  Google Scholar 

  6. O. S. Alekseeva, A. Z. Devdariani, M. G. Lednev, and A. L. Zagrebin, Russ. J. Phys. Chem. B 5, 946 (2011).

    Article  CAS  Google Scholar 

  7. D. J. Funk, A. Kvaran, and W. H. Breckenridge, J. Chem. Phys. 90, 2915 (1989).

    Article  CAS  Google Scholar 

  8. M. Ruszczak, M. Strojecki, and J. Koperski, Chem. Phys. Lett. 416, 147 (2005).

    Article  CAS  Google Scholar 

  9. A. Kvaran, D. J. Funk, A. Kowalski, and W. H. Breckenridge, J. Chem. Phys. 88, 6069 (1989).

    Google Scholar 

  10. J. Koperski, Sz. M. Kie basa, and M. Czajkowski, Spectrochim. Acta A 56, 1613 (2000).

    Article  Google Scholar 

  11. J. Koperski, M. ukomski, and M. Czajkowski, Spectrochim. Acta A 58, 2709 (2002).

    Article  CAS  Google Scholar 

  12. M. Krauss and F. H. Mies, Top. Appl. Phys. 30, 5 (1984).

    Article  Google Scholar 

  13. A. A. Radtsig and B. M. Smirnov, Parameters of Atoms and Atomic Ions: A Handbook (Energoatomizdat, Moscow, 1986) [in Russian].

    Google Scholar 

  14. K. Yamanouchi, S. Isogai, M. Okunishi, and S. Tsuchiya, J. Chem. Phys. 88, 205 (1988).

    Article  CAS  Google Scholar 

Download references

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Correspondence to O. S. Alekseeva.

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Published in Russian in Khimicheskaya Fizika, 2015, Vol. 34, No. 8, pp. 9–14.

The article was translated by the authors.

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Alekseeva, O.S., Devdariani, A.Z., Lednev, M.G. et al. Radiative lifetimes of the ν'(13 P 2) states of the CdAr, CdKr, HgAr, HgKr, HgXe quasimolecules. Russ. J. Phys. Chem. B 9, 515–520 (2015). https://doi.org/10.1134/S1990793115040156

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  • DOI: https://doi.org/10.1134/S1990793115040156

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