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Formation of chiral strings under various macroscopic conditions

  • Structure of Chemical Compounds. Spectroscopy
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Abstract

It has been established that the growth rate of strings decreases exponentially with time in a closed capillary and increases in inverse proportion to the time remaining until dryout in a drying solution drop. The obtained time dependences indicate that strings are formed simultaneously from a small number of nucleations, and the dissolved substance is condensed on the edge of a growing string, thus confirming the inertness of its side surface; when a solution contains a condensed nonstring phase, its concentration is low, and it does not produce any effect on the kinetics of the growth of strings.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    A. A. Skoblin, A. M. Zanin & S. V. Stovbun

Authors
  1. A. A. Skoblin
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  2. A. M. Zanin
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  3. S. V. Stovbun
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Correspondence to S. V. Stovbun.

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Original Russian Text © A.A. Skoblin, A.M. Zanin, S.V. Stovbun, 2014, published in Khimicheskaya Fizika, 2014, Vol. 33, No. 6, pp. 10–17.

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Skoblin, A.A., Zanin, A.M. & Stovbun, S.V. Formation of chiral strings under various macroscopic conditions. Russ. J. Phys. Chem. B 8, 302–308 (2014). https://doi.org/10.1134/S1990793114030270

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  • DOI: https://doi.org/10.1134/S1990793114030270

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