Abstract
A comparative analysis of the possible mechanisms of heterogeneous hydrogen and methane oxidation at mixture pressures below the third ignition limit and during the induction period of ignition was performed. The suggested reaction mechanisms are based on the properties of the well-defined active centers on the surface of quartz. These mechanisms explain the available experimental data on the heterogeneous reactions of the initial stages of hydrogen and methane oxidation at a qualitative level.
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Original Russian Text © E.A. Markevich, S.N. Kozlov, E.N. Aleksandrov, N.M. Kuznetsov, 2014, published in Khimicheskaya Fizika, 2014, Vol. 33, No. 6, pp. 47–52.
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Markevich, E.A., Kozlov, S.N., Aleksandrov, E.N. et al. Comparative analysis of the mechanisms of the heterogeneous stages of hydrogen and methane oxidation. Russ. J. Phys. Chem. B 8, 361–365 (2014). https://doi.org/10.1134/S1990793114030233
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DOI: https://doi.org/10.1134/S1990793114030233