Abstract
Based on a kinetic model of “living” radical polymerization of butyl acrylate with reversible chain-transfer, the characteristics of altering the molecular weight properties of the polymer by varying the initial concentrations of the reactants and temperature are established.
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N. V. Ulitin, I. I. Nasyrov, T. R. Deberdeev, and A. A. Berlin, Russ. J. Phys. Chem. B 6, 752 (2012).
N. V. Ulitin, T. R. Deberdeev, and A. A. Berlin, Russ. J. Phys. Chem. B 8, 227 (2014).
N. V. Ulitin, I. I. Nasyrov, T. R. Deberdeev, and A A. Berlin, Russ. J. Phys. Chem. B 6, 761 (2012).
P. B. Zetterlund and S. Perrier, Macromolecules 44, 1340 (2011).
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Original Russian Text © N.V. Ulitin, T.R. Deberdeev, D.Sh. Kalinina, E.V. Samarin, A.A. Berlin, 2014, published in Khimicheskaya Fizika, 2014, Vol. 33, No. 5, pp. 82–88.
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Ulitin, N.V., Deberdeev, T.R., Kalinina, D.S. et al. Molecular weight properties of poly(butyl acrylate): Computational experiment based on a kinetic model of “living” radical polymerization with reversible addition-fragmentation chain transfer. Russ. J. Phys. Chem. B 8, 396–402 (2014). https://doi.org/10.1134/S1990793114030142
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DOI: https://doi.org/10.1134/S1990793114030142