Abstract
The topology and energetic characteristics of hydrogen bonded clusters in methanol and methanol-heptane mixtures are investigated by IR spectroscopy over a wide temperature range. The average number of hydrogen bonds per methanol molecule was calculated. Based on an analysis of changes in the spectral parameters of O...H intramolecular bonds, conclusions on structural rearrangements in the mixture under study at elevated temperatures are drawn.
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Original Russian Text © A.A. Dyshin, R.D. Oparin, M.G. Kiselev, 2012, published in Sverkhkriticheskie Flyuidy: Teoriya i Praktika, 2012, Vol. 7, No. 2, pp. 67–74.
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Dyshin, A.A., Oparin, R.D. & Kiselev, M.G. Order structure of methanol along the 200-bar isobar in the temperature range of 60–320°C according to IR spectroscopy. Russ. J. Phys. Chem. B 6, 868–872 (2012). https://doi.org/10.1134/S1990793112080106
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DOI: https://doi.org/10.1134/S1990793112080106