Russian Journal of Physical Chemistry B

, Volume 3, Issue 6, pp 987–989 | Cite as

The thermochemical properties of transition metal complex salts with 1,5-diaminotetrazole

  • T. S. Kon’kova
  • Yu. N. Matyushin
  • E. A. Miroshnichenko
  • A. B. Vorob’ev
Chemical Physics of Polymer Materials

Abstract

A method for determining the enthalpies of formation of coordination compounds of Cu(II), Co(II), Zn, and Cd perchlorates was developed. The enthalpies of solution of complex salts in water were measured. The enthalpy of combustion of the 1,5-diaminotetrazole ligand was determined, and the enthalpy of its formation in the standard state calculated. The experimental data were used to calculate the enthalpies of formation of the coordination compounds studied in the standard state.

Keywords

Enthalpy Coordination Compound Standard Enthalpy Hippuric Acid Complex Salt 

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References

  1. 1.
    V. P. Sinditskii, V. I. Sokol, and A. E. Fogel’zang, Zh. Neorg. Khim. 32, 2726 (1987).Google Scholar
  2. 2.
    L. G. Lavrenova, S. V. Larionov, and Z. A. Grankina, Izv. SO RAN, Ser. Khim., No. 5, 88 (1979).Google Scholar
  3. 3.
    Yu. N. Matyushin, T. S. Kon’kova, and A. B. Vorob’ev, USSR Inventor’s Certificate No. 726442, Byull. Izobret. No. 13 (1980).Google Scholar
  4. 4.
    R. L. Montjomery, J. Chem. Thermodyn., No. 9, 915 (1977).Google Scholar
  5. 5.
    Yu. N. Matyushin, T. S. Kon’kova, and A. B. Vorob’ev, USSR Inventor’s Certificate No. 1221568, Byull. Izobret. No. 12 (1986).Google Scholar
  6. 6.
    Yu. N. Matyushin, T. S. Kon’kova, K. V. Titova, and V. Ya. Rosolovskii, Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 498 (1981).Google Scholar
  7. 7.
    J. D. Cox, D. D. Wagman, and V. A. Medvedev, J. Chem. Thermodyn., No. 10, 903 (1978).Google Scholar
  8. 8.
    Thermochemical Constants of Substances, Handbook, Ed. by V. P. Glushko, Vols. 6, 9 (Nauka, Moscow, 1972–1979) [in Russian].Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2009

Authors and Affiliations

  • T. S. Kon’kova
    • 1
  • Yu. N. Matyushin
    • 1
  • E. A. Miroshnichenko
    • 1
  • A. B. Vorob’ev
    • 1
  1. 1.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia

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