The interaction of F and Cl atoms with N2 molecule at medium distances

  • A. I. Reznikov
  • S. Ya. Umanskii
  • Yu. A. Chaikina
Elementary Physicochemical Processes
  • 27 Downloads

Abstract

The asymptotic method was used to obtain analytic equations for the elements of the 3 × 3 interaction matrix between an N2 molecule in the ground electronic state X 1 g + and F and Cl atoms in the 2 P j states at interparticle distances that determine halogen atom electronic relaxation processes. Spin-orbit, quadrupolequadrupole, dispersion, and exchange interactions were taken into account.

Keywords

Interaction Matrix Orbit Interaction Halogen Atom Electronic Wave Function Medium Distance 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    L. S. Fletcher and D. Husain, Chem. Phys. Lett. 49, 516 (1977).CrossRefGoogle Scholar
  2. 2.
    R. H. Clark and D. Husain, J. Chem. Soc., Faraday Trans. 2 80, 97 (1984).CrossRefGoogle Scholar
  3. 3.
    A. I. Chichinin and L. N. Krasnoperov, Chem. Phys. Lett. 124, 8 (1986).CrossRefGoogle Scholar
  4. 4.
    A. I. Chichinin, S. A. Chasovnikov, and L. N. Krasnoperov, Chem. Phys. Lett. 138, 371 (1987).CrossRefGoogle Scholar
  5. 5.
    E. Tiemann, H. Kanamori, and E. Hirota, J. Chem. Phys. 88, 2457 (1988).CrossRefGoogle Scholar
  6. 6.
    S. A. Sotnichenko, V. Ch. Bokun, and A. I. Nadkhin, Chem. Phys. Lett. 153, 560 (1988).CrossRefGoogle Scholar
  7. 7.
    J. Park, Y. Lee, and G. W. Flynn, Chem. Phys. Lett. 186, 441 (1991).CrossRefGoogle Scholar
  8. 8.
    A. I. Chichinin, Khim. Fiz. 15, 49 (1996).Google Scholar
  9. 9.
    A. I. Chichinin, J. Chem. Phys. 112, 3772 (2000).CrossRefGoogle Scholar
  10. 10.
    I. H. Zimmerman, Chem. Phys. 7, 323 (1975).CrossRefGoogle Scholar
  11. 11.
    M. Ya. Ovchinnikova, Khim. Fiz. 1, 44 (1982).Google Scholar
  12. 12.
    S. Ya. Umanskii, Khim. Fiz. 9(8), 1011 (1990).Google Scholar
  13. 13.
    A. I. Reznikov and S. Ya. Umanskii, Khim. Fiz. 11(6), 851 (1992).Google Scholar
  14. 14.
    A. I. Reznikov and S. Ya. Umanskii, Russ. J. Phys. Chem. 76(Suppl. 1), 13 (2002).Google Scholar
  15. 15.
    A. I. Reznikov and S. Ya. Umanskii, Khim. Fiz. 23(2), 77 (2004).Google Scholar
  16. 16.
    A. I. Reznikov and S. Ya. Umanskii, Khim. Fiz. 23(10), 5 (2004).Google Scholar
  17. 17.
    E. E. Nikitin and S. Ya. Umanskii, Theory of Slow Atomic Collisions (Atomizdat, Moscow, 1979; Springer, New York, 1984).Google Scholar
  18. 18.
    E. E. Nikitin and S. Ya. Umanskii, Theor. Chim. Acta 28, 121 (1973).CrossRefGoogle Scholar
  19. 19.
    I. A. Kornienko and S. Ya. Umanskii, Khim. Fiz. 5(8), 1011 (1986).Google Scholar
  20. 20.
    B. Bussery, V. Veyret, and S. Ya. Umanskii, Phys. Chem. Chem. Phys. 1, 3395 (1999).Google Scholar
  21. 21.
    L. D. Landau and E. M. Lifshitz, Quantum Mechanics: Non-Relativistic Theory, 3rd ed. (Nauka, Moscow, 1989, 4th ed.; Pergamon, Oxford, 1977).Google Scholar
  22. 22.
    O. Bouty, G. Hadinger, and M. Aubert-Frecon, J. Mol. Struct. 330, 97 (1995).Google Scholar
  23. 23.
    D. A. Varshalovich, A. N. Moskalev, and V. K. Khersonskii, Quantum Theory of Angular Momentum (Nauka, Leningrad, 1975; World Scientific, Singapore, 1988).Google Scholar
  24. 24.
    B. J. Ransil, Rev. Mod. Phys. 32, 245 (1960).CrossRefGoogle Scholar
  25. 25.
    J. D. Poll and L. Wolniewicz, J. Chem. Phys. 68, 3053 (1978).CrossRefGoogle Scholar
  26. 26.
    A. A. Radziyg and B. M. Smirnov, Reference Data on Atoms, Molecules and Ions (Springer, Berlin, 1985).Google Scholar

Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • A. I. Reznikov
    • 1
  • S. Ya. Umanskii
    • 1
  • Yu. A. Chaikina
    • 1
  1. 1.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia

Personalised recommendations