The interaction of F and Cl atoms with N2 molecule at medium distances

  • A. I. Reznikov
  • S. Ya. Umanskii
  • Yu. A. Chaikina
Elementary Physicochemical Processes


The asymptotic method was used to obtain analytic equations for the elements of the 3 × 3 interaction matrix between an N2 molecule in the ground electronic state X 1 g + and F and Cl atoms in the 2 P j states at interparticle distances that determine halogen atom electronic relaxation processes. Spin-orbit, quadrupolequadrupole, dispersion, and exchange interactions were taken into account.


Interaction Matrix Orbit Interaction Halogen Atom Electronic Wave Function Medium Distance 
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Copyright information

© Pleiades Publishing, Ltd. 2007

Authors and Affiliations

  • A. I. Reznikov
    • 1
  • S. Ya. Umanskii
    • 1
  • Yu. A. Chaikina
    • 1
  1. 1.Semenov Institute of Chemical PhysicsRussian Academy of SciencesMoscowRussia

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