Abstract
The asymptotic method was used to obtain analytic equations for the elements of the 3 × 3 interaction matrix between an N2 molecule in the ground electronic state X 1∑ +g and F and Cl atoms in the 2 P j states at interparticle distances that determine halogen atom electronic relaxation processes. Spin-orbit, quadrupolequadrupole, dispersion, and exchange interactions were taken into account.
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References
L. S. Fletcher and D. Husain, Chem. Phys. Lett. 49, 516 (1977).
R. H. Clark and D. Husain, J. Chem. Soc., Faraday Trans. 2 80, 97 (1984).
A. I. Chichinin and L. N. Krasnoperov, Chem. Phys. Lett. 124, 8 (1986).
A. I. Chichinin, S. A. Chasovnikov, and L. N. Krasnoperov, Chem. Phys. Lett. 138, 371 (1987).
E. Tiemann, H. Kanamori, and E. Hirota, J. Chem. Phys. 88, 2457 (1988).
S. A. Sotnichenko, V. Ch. Bokun, and A. I. Nadkhin, Chem. Phys. Lett. 153, 560 (1988).
J. Park, Y. Lee, and G. W. Flynn, Chem. Phys. Lett. 186, 441 (1991).
A. I. Chichinin, Khim. Fiz. 15, 49 (1996).
A. I. Chichinin, J. Chem. Phys. 112, 3772 (2000).
I. H. Zimmerman, Chem. Phys. 7, 323 (1975).
M. Ya. Ovchinnikova, Khim. Fiz. 1, 44 (1982).
S. Ya. Umanskii, Khim. Fiz. 9(8), 1011 (1990).
A. I. Reznikov and S. Ya. Umanskii, Khim. Fiz. 11(6), 851 (1992).
A. I. Reznikov and S. Ya. Umanskii, Russ. J. Phys. Chem. 76(Suppl. 1), 13 (2002).
A. I. Reznikov and S. Ya. Umanskii, Khim. Fiz. 23(2), 77 (2004).
A. I. Reznikov and S. Ya. Umanskii, Khim. Fiz. 23(10), 5 (2004).
E. E. Nikitin and S. Ya. Umanskii, Theory of Slow Atomic Collisions (Atomizdat, Moscow, 1979; Springer, New York, 1984).
E. E. Nikitin and S. Ya. Umanskii, Theor. Chim. Acta 28, 121 (1973).
I. A. Kornienko and S. Ya. Umanskii, Khim. Fiz. 5(8), 1011 (1986).
B. Bussery, V. Veyret, and S. Ya. Umanskii, Phys. Chem. Chem. Phys. 1, 3395 (1999).
L. D. Landau and E. M. Lifshitz, Quantum Mechanics: Non-Relativistic Theory, 3rd ed. (Nauka, Moscow, 1989, 4th ed.; Pergamon, Oxford, 1977).
O. Bouty, G. Hadinger, and M. Aubert-Frecon, J. Mol. Struct. 330, 97 (1995).
D. A. Varshalovich, A. N. Moskalev, and V. K. Khersonskii, Quantum Theory of Angular Momentum (Nauka, Leningrad, 1975; World Scientific, Singapore, 1988).
B. J. Ransil, Rev. Mod. Phys. 32, 245 (1960).
J. D. Poll and L. Wolniewicz, J. Chem. Phys. 68, 3053 (1978).
A. A. Radziyg and B. M. Smirnov, Reference Data on Atoms, Molecules and Ions (Springer, Berlin, 1985).
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Original Russian Text © A.I. Reznikov, S.Ya. Umanskii, Yu.A. Chaikina, 2007, published in Khimicheskaya Fizika, 2007, Vol. 26, No. 7, pp. 14–21.
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Reznikov, A.I., Umanskii, S.Y. & Chaikina, Y.A. The interaction of F and Cl atoms with N2 molecule at medium distances. Russ. J. Phys. Chem. B 1, 435–442 (2007). https://doi.org/10.1134/S1990793107050016
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DOI: https://doi.org/10.1134/S1990793107050016