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Complex [Ag(PPh3)4][2-B10H9NH3 · 2DMF]: Synthesis and Structure

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Abstract

The formation of complex salt [Ag(PPh3)4][2-B10H9NH3 ∙ 2DMF] (I) by the reaction of the salts of the [2-B10H9NH3]– anion with [Ag(PPh3)4]NO3 is studied. The anionic moiety of complex I is a stable solvate linked by hydrogen bonds of two types. Compound I is identified by IR spectroscopy and elemental, X-ray structure, and X-ray diffraction analyses (CIF file CCDC no. 1884451).

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  1. Figures 2 and 3 were drawn using the OLEX2 program software [24].

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ACKNOWLEDGMENTS

Analysis to boron was carried out at the Center for Collective Use of the Research Center Kurchatov Institute—IREA. The XRD and X-ray structure analyses were conducted using the equipment of the Center for Collective Use of Physical Methods of Investigation at the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) functioning in the framework of the state task of the Kurnakov Institute of General and Inorganic Chemistry (Russian Academy of Sciences) in the area of basic research.

Funding

This work was supported by the Russian Science Foundation, project no. 18-13-00459.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. P. Zhdanov, V. V. Voinova, I. N. Klyukin, G. A. Buzanov, K. Yu. Zhizhin & N. T. Kuznetsov

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. S. Grigor’ev

Authors
  1. A. P. Zhdanov
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  2. V. V. Voinova
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  3. I. N. Klyukin
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  4. G. A. Buzanov
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  5. M. S. Grigor’ev
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  6. K. Yu. Zhizhin
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  7. N. T. Kuznetsov
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Corresponding authors

Correspondence to A. P. Zhdanov or K. Yu. Zhizhin.

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Translated by E. Yablonskaya

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Zhdanov, A.P., Voinova, V.V., Klyukin, I.N. et al. Complex [Ag(PPh3)4][2-B10H9NH3 · 2DMF]: Synthesis and Structure. Russ J Coord Chem 45, 563–568 (2019). https://doi.org/10.1134/S1070328419080098

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  • DOI: https://doi.org/10.1134/S1070328419080098

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