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Atomic-Force-Microscopy Analysis of Uranium Bis-Phthalocyanine and Its Pyrolysed Derivatives

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Abstract

The morphology of the surface of thin films of uranium bis-phthalocyanine and its pyrolysed derivatives is analyzed by atomic-force microscopy. During the pyrolysis of samples in an inert atmosphere (400–800°C), the transition from a crystalline to amorphous carbon structure with immobilized metal atoms is observed in uranium bis-phthalocyanine thin films deposited onto a substrate. It is found that at temperatures above 1000°C the pyrolysis is accompanied by the aggregation of nanoscale particles and the formation of ultraporous matrices with a high specific surface area (∼102 m2/g).

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Correspondence to V. Yu. Bairamukov.

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Original Russian Text © V.Yu. Bairamukov, V.T. Lebedev, V.I. Tikhonov, 2018, published in Poverkhnost’, 2018, No. 2, pp. 87–91.

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Bairamukov, V.Y., Lebedev, V.T. & Tikhonov, V.I. Atomic-Force-Microscopy Analysis of Uranium Bis-Phthalocyanine and Its Pyrolysed Derivatives. J. Surf. Investig. 12, 170–174 (2018). https://doi.org/10.1134/S1027451018010226

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  • DOI: https://doi.org/10.1134/S1027451018010226

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