Abstract
The crystal of (NH4)3H(SO4)2 is of special interest due to the possible influence of ammonium ion on the series of phase transitions: I↔II↔ III↔IV↔V↔VII. Earlier, the x-ray single-crystal diffraction study of phase II of the (NH4)3H(SO4)2 crystal showed that the crystal structure of this compound had two crystallographically independent groups of the ammonium ions NH4(1) and NH4(2) but orientational positions of these ammonium ions were not determined exactly. The refinement of the NH4(1) and NH4(2) orientational positions in phase II was carried out by the x-ray and neutron single-crystal diffraction study. The analysis of difference Fourier maps of electron charge density and nuclear density suggested the possibility of disordering of NH4(2) ammonium ions.
Similar content being viewed by others
References
K. Gesi, Phys. Status Solidi A 23, 479 (1976).
K. Gesi, J. Phys. Soc. Jpn. 43, 1941 (1977).
S. Suzuki, J. Phys. Soc. Jpn. 47, 1205 (1979).
K. Sooryanarayana and T. N. Guru Row, Phase Transitions 58, 263 (1996).
T. Fukami, K. Horiuchi, K. Nakasone, and K. Furukawa, Jpn. J. Appl. Phys. 35, 2253 (1996).
S. Suzuki and Y. Makita, Acta Crystallogr. B 34, 732 (1978).
A. Leclaire, M. Ledesret, J. C. Monier, et al., Acta Crystallogr. B 41, 209 (1985).
P. M. Dominiak, J. Herold, W. Kolodziejski, and K. Wozniak, Inorg. Chem. 42, 1590 (2003).
M. Kamoun, M. H. Ben Ghozlen, and A. Daoud, Phase Transition 9, 247 (1987).
M. Fujimoto and B. V. Sinha, Ferroelectrics. 46, 227 (1983).
M. Tanaka and Y. Shiozaki, and Acta Crystallogr. 37, 1171 (1981).
A. Loose, K. Wozniak, P. M. Dominiak, et al., JINR Preprint E14-2006-59 (Dubna, 2006).
A. I. Baranov, V. V. Dolbinina, E. D. Yakushkin, et al., Ferroelectrics 217, 285 (1998).
L. S. Smirnov, A. I. Baranov, L. A. Shuvalov, et al., Fiz. Tverd. Tela 43, 115 (2001) [Phys. Solid State 43, 117 (2001)].
http://www.hmi.de/bensc/instrumentation/pdf_files/BENSC_E5.pdf.
G. M. Sheldrick, Acta Crystallogr. A 46, 467 (1990).
G. M. Sheldrick, SHELXTL97: Program for the Refinement of Crystal Structures (University of Göttingen, Göttingen, Germany).
B. K. Vainshtein, Modern Crystallography (Nauka, Moscow, 1979), vol. 1, p. 324 [in Russian].
Author information
Authors and Affiliations
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Reehuis, M., Wozniak, K., Dominiak, P. et al. Refinement of the (NH4)3H(SO4)2 crystal structure: II. X-ray and neutron single-crystal diffraction from phase II at room temperature. J. Surf. Investig. 1, 637–644 (2007). https://doi.org/10.1134/S1027451007060031
Received:
Issue Date:
DOI: https://doi.org/10.1134/S1027451007060031