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Electrospinning Engineering Enables High-Performance Sodium-Ion Batteries

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Abstract

As a promising energy storage device, sodium-ion batteries (SIBs) have received continuous attention due to their low-cost and environmental friendliness. However, the sluggish kinetics of Na ion usually makes SIBs hard to realize desirable electrochemical performance when compared to lithium-ion batteries (LIBs). The key to addressing this issue is to build up nanostructured materials which enable fast Na-ion insertion/extraction. One-dimensional (1D) nanocarbons have been considered as both the anode and the matrix to support active materials for SIB electrodes owing to their high electronic conductivity and excellent mechanical property. Because of their large surface areas and short ion/electron diffusion path, the synthesized electrodes can show good rate performance and cyclic stability during the charge/discharge processes. Electrospinning is a simple synthetic technology, featuring inexpensiveness, easy operation and scalable production, and has been largely used to fabricate 1D nanostructured composites. In this review, we first give a simple description of the electrospinning principle and its capability to construct desired nanostructures with different compositions. Then, we discuss recent developments of carbon-based hybrids with desired structural and compositional characteristics as the electrodes by electrospinning engineering for SIBs. Finally, we identify future research directions to realize more breakthroughs on electrospun electrodes for SIBs.

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Fig. 1
Fig. 2

Reproduced with permission [54]. Copyright 2014, Wiley–VCH. Reproduced with permission [56]. Copyright 2015, Elsevier. Reproduced with permission [59]. Copyright 2017, Elsevier. Reproduced with permission [60]. Copyright 2018, Frontiers S.A. c Photographs, SEM image and application of Na2VTi(PO4)3/CNFs, image illustration and schematic of hierarchical structure of the hybrid nanofiber. Reproduced with permission [61]. Copyright 2017, Royal Society of Chemistry. d SEM image and photographs of NaFePO4/CNFs, galvanostatic charge/discharge profiles at a current density of 20 mA g−1. Reproduced with permission [63]. Copyright 2018, Wiley–VCH

Fig. 3

Reproduced with permission [65]. Copyright 2017, Wiley–VCH. b Schematic of the synthetic process and SEM image of NFPO/C and NFPO/rGO/C composites. Reproduced with permission [69]. Copyright 2017, Royal Society of Chemistry. c Schematic illustration for the preparation process and image illustration of Na2+2xFe2−x(SO4)3/porous CNFs hybrid film. Reproduced with permission [71]. Copyright 2016, Royal Society of Chemistry

Fig. 4

Reproduced with permission [86]. Copyright 2016, Elsevier. Reproduced with permission [47]. Copyright 2017, Elsevier. b SEM images of N-doped CNFs, N,S-doped CNFs, and P-doped CNFs. Reproduced with permission [102]. Copyright 2018, Elsevier. Reproduced with permission [106]. Copyright 2018, American Chemical Society. c Schematic illustration of the synthetic process and SEM and TEM images of graphene/CNFs. Reproduced with permission [24]. Copyright 2017, Royal Society of Chemistry

Fig. 5

Reproduced with permission [107]. Copyright 2013, American Chemical Society. Reproduced with permission [107]. Copyright 2014, Royal Society of Chemistry. Reproduced with permission [108]. Copyright 2014, Elsevier. Reproduced with permission [111]. Copyright 2014, Wiley–VCH. Reproduced with permission [114]. Copyright 2017, American Chemical Society. b Two-step method combined electrospinning with calcination to synthesize porous CNFs combined with alloy nanoparticles, image illustration of SnSb/PCNFs, SnSb/CNFs and Sn nanodots/porous N-doped CNFs. Reproduced with permission [115]. Copyright 2014, Wiley–VCH. Reproduced with permission [116]. Copyright 2015, Royal Society of Chemistry. Reproduced with permission [117]. Copyright 2015, Wiley–VCH

Fig. 6

Reproduced with permission [119]. Copyright 2017, Wiley–VCH. Reproduced with permission [118]. Copyright 2017, Elsevier. Reproduced with permission [120]. Copyright 2017, Royal Society of Chemistry. Reproduced with permission [124]. Copyright 2016, Wiley–VCH. c Image illustrations of MnCoNiOx@double-carbon nanofibers, Na2Ti3O7@CNFs, T-Nb2O5@CNFs and MnFe2O4@CNFs; and MnFe2O4 particle size distribution diagram. Reproduced with permission [121]. Copyright 2016, American Chemical Society. Reproduced with permission [122]. Copyright 2017, Wiley–VCH. Reproduced with permission [123]. Copyright 2017, Wiley–VCH. Reproduced with permission [99]. Copyright 2016, American Chemical Society

Fig. 7

Reproduced with permission [132]. Copyright 2016, Elsevier. Reproduced with permission [133]. Copyright 2014, Wiley–VCH. Reproduced with permission [134]. Copyright 2018, Elsevier. Reproduced with permission [135]. Copyright 2016, American Chemical Society. Reproduced with permission [136]. Copyright 2017, Elsevier. Reproduced with permission [137]. Copyright 2019, American Chemical Society. Reproduced with permission [138]. Copyright 2018, American Chemical Society. Reproduced with permission [139]. Copyright 2019, Elsevier. b Preparation process of heteroatom-doped CNFs combined with alloy nanoparticles, SEM image of N-doped CNFs@MoS2, SnS/CNTs@S-CNFs, SnS@SNCF-55, SnS2/NSDC nanofibers, and cycle stability of different SnS/C ratio. Reproduced with permission [145]. Copyright 2019, Elsevier. Reproduced with permission [141]. Copyright 2018, Elsevier. Reproduced with permission [143]. Copyright 2018, Elsevier. Reproduced with permission [144]. Copyright 2019, Elsevier

Fig. 8

Reproduced with permission [148]. Copyright 2019, Royal Society of Chemistry. Reproduced with permission [149]. Copyright 2020, Royal Society of Chemistry

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  1. Chuanping Li and Min Qiu contributed equally.

Authors and Affiliations

  1. College of Environmental Science and Engineering, Fujian Normal University, Fuzhou, 350000, Fujian, China

    Chuanping Li, Ruiling Li, Xuan Li, Manxi Wang, Jiabo He, Qingrong Qian, Qinghua Chen, Xiaoyan Li & Yuming Chen

  2. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350000, China

    Min Qiu & Liren Xiao

  3. State Grid Fujian Maintenance Company, Fuzhou, 350000, Fujian, China

    Ganggang Lin

  4. Department of Mechanical Engineering, The Hong Kong Polytechnic University, Kowloon, Hong Kong, China

    Junxiong Wu

  5. Centre for Advanced Materials Technology (CAMT), School of Aerospace, Mechanical and Mechatronics Engineering J07, The University of Sydney, Sydney, NSW, 2006, Australia

    Yiu-Wing Mai

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  1. Chuanping Li
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Correspondence to Junxiong Wu, Xiaoyan Li, Yiu-Wing Mai or Yuming Chen.

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Li, C., Qiu, M., Li, R. et al. Electrospinning Engineering Enables High-Performance Sodium-Ion Batteries. Adv. Fiber Mater. 4, 43–65 (2022). https://doi.org/10.1007/s42765-021-00088-6

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