Abstract
A new analysis method of reverse leakage current for β-Ga2O3 Schottky barrier diodes is performed by using two models: bias dependence and no bias dependence of barrier height. The method incorporates both the current induced by the tunneling of carriers through the Schottky barrier and the current induced by the thermionic emission of carriers across the metal–semiconductor interface. The experimental reverse transition voltage between thermionic emission and tunneling process can be determined from the intersection of the two components that were separated from the total current. Below the reverse transition voltage, the thermionic emission current dominates, and above it, the tunneling current dominates, while near the reverse transition voltage, neither tunneling nor thermionic emission accurately describes the conduction process because the both currents have the same order of magnitude; therefore, the both mechanisms must be combined together. The experimental reverse transition voltage (bias-dependent model) increases for low and high temperatures and decreases at intermediate temperatures for β-Ga2O3 Schottky barrier diodes. The bias dependence of the barrier height model shows that the barrier height is strongly dependent (increases) on the reverse bias, in particular at low temperatures and low reverse bias. This model can explain the discrepancy between the experimental characteristics and those calculated by no bias dependence of barrier height model.
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1 Introduction
In recent years, the monoclinic beta phase of gallium oxide (β-Ga2O3) is promising for next-generation power electronic devices because of its excellent material properties for high-voltage applications, e.g., a 4.8 eV bandgap, a breakdown field of 8 MV/cm, and a Baliga’s figure of merit that is more than four times larger than those for SiC and GaN [1,2,3,4,5,6,7]. Moreover, it is available as high-quality freestanding β-Ga2O3 substrates grown by inexpensive melt methods [7]. Several authors are conducting early-stage research on β-Ga2O3-based Schottky barrier diodes (SBDs). A few studies on β-Ga2O3 SBDs fabricated on β-Ga2O3 single crystal grown by different growth methods with various crystal orientations have been reported in the literature [8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25]. Most of these studies investigated the electrical characteristics in forward bias conditions where the thermionic emission (TE) mechanism is predominant. Under reverse bias condition, undesirable large leakage currents have been observed for β-Ga2O3 and large bandgap SBDs due to the high electric fields normally encountered in these devices, and hence, this effect can potentially limit operation in the reverse blocking mode as a result of excessive internal heating. It, therefore, becomes critical to analyze the origin of such reverse leakage currents and fundamentally comprehend the underlying physics [26, 27]. Understanding of the various mechanisms contributing to leakage currents will allow, maybe, to improve the performance of these devices. In fact, the total current in a Schottky barrier diode under reverse bias is always made up of the sum of the two contributions by thermionic emission and tunneling process (thermionic field and field emission). However, traditionally, the different regimes of electron transport: thermionic emission and tunneling, are considered separately for analyzing the reverse characteristics I–V of β-Ga2O3 SBDs [12, 18], since they all appear at different conditions and can be exploited independently. In our more recent theoretical study [28], we investigated the conduction mechanisms of the reverse leakage current for 4H-SiC SBDs; we have found that the reverse transition voltage between TE mechanism and tunneling process is strongly dependent on temperature, barrier height, doping concentration, and effective mass. The purpose of the present article is to present precisely a simple analysis of the different contributions to the experimental net leakage current of β-Ga2O3 SBDs. To this end, we propose a combined model for the leakage current of β-Ga2O3 SBDs which takes into account in a common framework the two main sources of leakage current present in Schottky diodes, namely the current due to the thermionic emission of carriers across the Schottky barrier and the current due to the tunneling of carriers through the Schottky barrier. This method will allow us to separate the two components of the total current; hence, we can determine the experimental reverse transition voltage between the two contributed mechanisms.
2 Theory and modeling
The net current density across the metal–semiconductor interface is the algebraic sum of the two components: the electron current density JSM from semiconductor to metal and vice versa, JMS. The current from semiconductor to metal JSM is proportional to the quantum transmission coefficient \(T\left( {E_{x} } \right)\) multiplied by the occupation probability in the semiconductor and the unoccupied probability in the metal [29]. A similar expression can be obtained for the metal–semiconductor current density JMS, which traverses in the opposite direction. The net current density JTot is then given by [27,28,29,30,31,32]
where \(k_{\text{B}}\) is the Boltzmann constant, T is the temperature, \(A^{*}\) is the effective Richardson constant, and \(N\left( {E_{x} } \right)\) is the supply function which is defined as
The total energy E is the sum of a transversal component Ep parallel to the Schottky interface and a transversal component Ex. fS and fM, are the Fermi–Dirac distribution functions for the semiconductor and the metal, respectively. In expression (2), \(\zeta\) denotes a difference between the equilibrium Fermi level and conduction bands. Our calculations are performed by using a Wentzel–Kramers–Brillouin (WKB) approximation of the tunneling probability \(T\left( {E_{x} } \right)\). WKB approximation is known by its reasonable accuracy for calculating the tunneling probability through a reverse-biased Schottky barrier [33] and is expressed as
where x1 and x2 are the two classical turning points. As shown in Fig. 1, the \(U(x)\) is the potential energy profile, for an arbitrary Schottky diode as measured with respect to the energy of the bottom of the conduction band in the bulk of the semiconductor, and it can be given by [27, 34]:
where \(\varepsilon_{\text{S}}\) is the semiconductor permittivity, D is the depletion width, and ND is the doping concentration. The second term in Eq. (4) is the barrier lowering due to the image force effect. We note that the current expression (1) self-consistently includes both the process of conduction of carriers, i.e., tunneling for the lower energy range (Ex < \(U_{\hbox{max} }\)), and TE mechanism for the higher energy range (Ex > \(U_{\hbox{max} }\)) [27].
Here the component of reverse tunneling current density \(J_{Tun}\) can be expressed as [27, 31,32,33,34]
and the component of TE current density \(J_{\text{Therm}}\) can be expressed as [27]
For the energies \(E_{x} > U_{\hbox{max} }\) that correspond to the TE mechanism, the tunneling probability is equal to unity. Including the barrier lowering model and approximating the Fermi–Dirac statistics with the Maxwell–Boltzmann, Eq. (7) can be formulated as [27]
where \(\Delta \phi_{b}\) is the barrier lowering due to the image force lowering effect, and it is given by [35]:
For extracting the barrier height (\(\phi_{\text{b}}\)) from the reverse characteristic I–V, we propose two models: The first model assumes that the barrier height \(\phi_{\text{b}}\) is assumed to be bias dependent due to the presence of an interfacial layer and interface states located between metal and semiconductor contact [36, 37].
For that, we can solve numerically the following equation by Newton’s method.
where \(J_{\exp }^{j} \left( {V_{j} } \right)\) is the reverse current density for each bias voltage measurement, \(J_{\text{Tun}}^{j} \left( {V_{j} } \right)\) and \(J_{\text{Therm}}^{j} \left( {V_{j} } \right)\) are the theoretical components of the current given by Eqs. (6) and (8), respectively.
The second model assumes that the effective barrier height is independent of the applied bias, and it can be determined from the first model by calculating the average value of the barrier height values calculated for each bias voltage measurement.
3 Results and discussion
In order to present our new proposed method, we used experimental data obtained with a Pt Schottky barrier diode on n-type β-Ga2O3 (001) previously published by Higashiwaki et al. [12]. In their experimental study, the doping concentration was \(1.2 \times 10^{16}\) cm−3. Using the effective masses \(m* = 0.342m_{0}\) from [38], the Richardson constant (\(A^{*}\)) is calculated to be 41.1 A K−1 cm−2.
Figure 2 shows the resulting barrier height as a function of the reverse bias for β-Ga2O3 SBD at various temperatures when the both mechanisms are combined. It can be seen that the barrier height increases with an increase in temperature, and it is strongly dependent on the reverse bias, in particular, below the temperature 373 K where the barrier height increases with increasing reverse bias and then starts to decrease slightly. This dependence on reverse bias becomes weak at high temperatures (above 373 K).
In Fig. 3, we show the variation of the average barrier height with the temperature. In this model, we assume that the barrier height is independent of the reverse bias, and the average value is the effective barrier height \(\phi_{{{\text{b}}\,{\text{eff}}}}\). From Fig. 3, it can be seen that the effective barrier height increases exponentially with temperature. We note that for SiC SBDs the Schottky barrier height strongly depends on the reverse bias voltage, temperature, and doping concentration [39]. These dependences are due to the combination of the effects of the interfacial layer and interface states located at the interface between metal and semiconductor contact [39].
Figure 4 shows the calculated and experimental reverse current densities according to tunneling and thermionic models for β-Ga2O3 SBD at various temperatures. The calculated reverse current densities are obtained by using the extracted barrier height which is plotted in Fig. 2. The intersection between the components of thermionic emission and tunneling currents represents the reverse transition voltage (VT) between the both corresponding mechanisms. The thermionic emission (TE) component is seen to be dominant for voltages up to about VT, while the tunneling mechanism becomes larger for bias values beyond VT. Near the reverse transition voltage, neither tunneling nor thermionic emission accurately describes the conduction process because the both currents have the same order of magnitude, and therefore, the both mechanisms must be combined together. In this model, where the barrier height is extracted from each data (Ii–Vi), the total current which presents the sum of the two components has the same value as the experimental current. However, if we use the model that the barrier height is independent of the bias voltage, the total current is in good agreement with the experimental data especially for higher temperatures (above 373 K) as shown in Fig. 5. The discrepancies between calculation and experiment become large at lower temperatures (294 K; see Fig. 5a). This observation was reported in several works in the literature [12, 26, 40, 41]. Because the calculated reverse characteristics are not in good agreement with the experimental reverse characteristics at the lower temperatures in the case of no bias dependence of barrier height (second model), we can conclude that the bias dependence of barrier height model seems more appropriate than the second model for analysis the reverse characteristics I–V of β-Ga2O3 SBDs.
The experimental reverse transition voltage between the thermionic and tunneling currents for the two models is determined from the intersection of the I–V curves and plotted in Fig. 6. The values of the experimental reverse transition voltage for the two models are practically having the same values exception for temperature 294 K, and the reverse transition voltage has different values. As shown in Fig. 6, the reverse transition voltage is strongly dependent on the temperature. In the case of the first model, (\(\phi_{\text{b}}\) is assumed to be bias dependent), for example, the reverse transition voltage increases for temperatures below 323 K, and above 348 K, however, it decreases with increasing temperature for intermediate temperatures (223–348 K). This dependence of the experimental reverse transition voltage on temperature can be explained by the competition between the TE and tunneling mechanisms when the reverse bias and temperature are changed simultaneously [28]. It seems to be well consistent with our recent proposed model for temperature dependence of reverse transition voltage of 4H-SiC SBDs [28]. Note that the tunneling and TE currents are increased either by increasing reverse bias or by increasing temperature, and the increase in the TE current is always smaller than the increase in tunneling current with increasing reverse bias. For low (T < 323 K) and high (T > 348 K) temperatures, the reverse bias should be increased to make the tunneling current component equal to the TE current component that is large compared with tunneling current component with increasing temperature. At the intermediate temperatures (223–348 K), the reverse bias should be decreased to make the tunneling component current equal to the TE current component that becomes smaller than the tunneling current component with increasing temperature.
4 Conclusion
Our study has been based upon a reverse current model which incorporates in a unified way both the current due to the thermionic emission of carriers across the metal–semiconductor interface and the tunneling current through the potential barrier. By means of the analytical method of the model, the different contributions to the net current of the β-Ga2O3 Schottky barrier diode have been identified from experimental data I–V previously published in the literature. The reverse transition voltage (VT) between thermionic emission and tunneling currents represents the value of the intersection of the both curves I–V of the two components. It has been shown that at low biases (V < VT) the current is dominated by the thermionic emission of carriers across the metal–semiconductor interface. At high biases (V > VT), the current is shown to be dominated by the tunneling of carriers through the potential barrier. The experimental reverse transition voltage increases for low and high temperatures, while for intermediate temperatures, the reverse transition voltage decreases with increasing temperature. Our treatment is done with the standard model (no bias dependence of barrier height) and also with bias dependence of barrier height model that maybe can explain the discrepancy between the experimental reverse characteristics and those calculated by the standard model for low temperatures.
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Latreche, A. Combined thermionic emission and tunneling mechanisms for the analysis of the leakage current for Ga2O3 Schottky barrier diodes. SN Appl. Sci. 1, 188 (2019). https://doi.org/10.1007/s42452-019-0192-2
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DOI: https://doi.org/10.1007/s42452-019-0192-2