Skip to main content
Log in

Influence of SiC Nano Particles on Microhardness and Corrosion Resistance of Electroless Ni–P Coatings

  • Published:
Journal of Bio- and Tribo-Corrosion Aims and scope Submit manuscript

Abstract

Silicon carbide nanoparticles were co-deposited in Ni–P matrix to form Ni–P–SiC composite coating on the mild steel substrate by using electroless coating technique. In the present study, the effect of SiC nanoparticles concentration and heat treatment temperature on microhardness and corrosion resistance of the Ni–P–SiC coating was investigated. The microhardness and corrosion resistance of the coating was further analyzed through the experiments. X-ray diffraction and scanning electron microscope attached with energy dispersive spectroscopy were used to analyze phase structure, morphology, and elemental composition of the coating. Results confirm that incorporation of SiC nanoparticles into the coating greatly influences the microhardness and corrosion resistance of the coating. The phase change from amorphous Ni to crystalline nickel and nickel phosphide at 400 °C further improves the microhardness and corrosion resistance of the composite coating.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Balaraju JN, Selvi VE, Rajam KS (2010) Electrochemical behavior of low phosphorus electroless Ni–P–Si3N4 composite coatings. Mater Chem Phys 120(2–3):546–551

    Article  CAS  Google Scholar 

  2. Sharma S, Sharma S, Agarwala P, Garg R, Gopinath P (2012) A study on Ni–P and Ni–P–ZnO composite coatings developed by electroless technique. Adv Mater Res 585:512–516

    Article  CAS  Google Scholar 

  3. Karthikeyan S, Vijayaraghavan L (2016) Investigation of the surface properties of heat treated electroless Ni–P coating. Trans IMF 94(5):265–273

    Article  Google Scholar 

  4. Yan M, Ying HG, Ma TY (2008) Improved microhardness and wear resistance of the as-deposited electroless Ni–P coating. Surf Coat Technol 202:5909–5913

    Article  CAS  Google Scholar 

  5. Wu YC, Li GH, Zhang L (2000) Wear resistance of electroless deposited Ni–P and Ni–P/SiC composite coatings on low alloy cast iron. Surf Eng 16(6):506–510

    Article  CAS  Google Scholar 

  6. Ping Z, Cheng G, He Y (2010) Mechanically assisted electroless barrel-plating Ni-P coatings deposited on carbon steel. J Mater Sci Technol 26:945–950

    Article  CAS  Google Scholar 

  7. Gao Jiaqiang L, Lei Wu, Yating S, Bin, Wenbin Hu (2005) Electroless Ni–P–SiC composite coatings with superfine particles. Surf Coat Technol 200(20–21):5836–5842

    Google Scholar 

  8. Mafi IR, Dehghanian C (2011) Studying the effects of the addition of TiN nanoparticles to Ni–P electroless coatings. Appl Surf Sci 258(5):1876–1880

    Article  CAS  Google Scholar 

  9. Ranganatha S, Venkatesha TV, Vathsala K (2010) Development of electroless Ni–Zn–P/nano-TiO2 composite coatings and their properties. Appl Surf Sci 256(24):7377–7383

    Article  CAS  Google Scholar 

  10. Farzaneh A, Mohammadi M, Ehteshamzadeh M, Mohammadi F (2013) Electrochemical and structural properties of electroless Ni-P-SiC nanocomposite coatings. Appl Surf Sci 276(1):697–704

    Article  CAS  Google Scholar 

  11. Afroukhteh S, Dehghaniann C, Emamy M (2012) Preparation of electroless Ni–P composite coatings containing nano-scattered alumina in presence of polymeric surfactant. Prog Nat Sci 22(4):318–325

    Article  Google Scholar 

  12. Gawad SAA, Baraka AM, Morsi MS, Eltoum MA (2013) Development of electroless Ni-P-Al2O3 and Ni-P-TiO2 composite coatings from alkaline hypophosphite gluconate baths and their properties. Int J Electrochem Sci 8:1722–1734

    Google Scholar 

  13. Karthikeyan S, Vijayaraghavan L (2015) Effect of co-deposition of Al2O3 particle on the properties of electroless Ni-P coating. Int J Eng Res Technol 3:175–178

    Google Scholar 

  14. Lin CJ, Chen KC, He JL (2006) The cavitation erosion behavior of electroless Ni-P-SiC composite coating. Wear 261(11–12):1390–1396

    Article  CAS  Google Scholar 

  15. Ploof L (2008) Electroless nickel composite coatings. Adv Mater Process 166(5):36–38

    CAS  Google Scholar 

  16. Islam M, Azhar MR, Fredj N et al (2015) Influence of SiO2 nanoparticles on hardness and corrosion resistance of electroless Ni–P coatings. Surf Coat Technol 261:141–148

    Article  CAS  Google Scholar 

  17. Dong XH, Chen WT, Xiao GB, Yang, Zhang PY (2009) Preparation and properties of electroless Ni–P–SiO2 composite coatings. Appl Surf Sci 255:7051–7055

    Article  CAS  Google Scholar 

  18. Alishahi M, Monirvaghefi SM, Saatchi A, Hosseini SM (2012) The effect of carbon nanotubes on the corrosion and tribological behavior of electroless Ni–P–CNT composite coating. Appl Surf Sci 258(7):2439–2446

    Article  CAS  Google Scholar 

  19. Lee CK (2012) Comparative corrosion resistance of electroless Ni-P/nano-TiO2 and Ni-P/nano-CNT composite coatings on 5083 aluminum alloy. Int J Electrochem Sci 7:12941–12954

    CAS  Google Scholar 

  20. Balaraju JN, Raja KS (2012) Electroless deposition and characterization of high phosphorus Ni-P-Si3N4 composite coatings. Int J Electrochem Sci 7:747–761

    Google Scholar 

  21. Soleimani R, Mahboubi F, Kazemi M, Arman SY (2014) Corrosion and tribological behaviour of electroless Ni–P/nano-SiC composite coating on aluminium 6061. Surf Eng 31(9):714–721

    Google Scholar 

  22. Yaghoobi M, Bostani B, Farshbaf PA, Ahmadi NP (2018) An investigation on preparation and effects of post heat treatment on electroless nanocrystalline Ni–Sn–P coatings. Trans Indian Inst Metals 71(2):393–402

    Article  CAS  Google Scholar 

  23. Chen H, Wang Q (2015) Electroless plating of Ni-P-W coatings containing scattered Nb2O5 on sintered NdFeB substrate. Mater Res 18(5):1089–1096

    Article  CAS  Google Scholar 

  24. Araghi A, Paydar MH (2014) Wear and corrosion characteristics of electroless Ni–W–P–B4C and Ni–P–B4C coatings. Tribol-Mater Surf Interfaces 8(3):16–24

    Article  Google Scholar 

  25. Sarika S, Sharma S, Awanish S, Agarwala V (2016) Co-deposition of synthesized ZnO nanoparticles into Ni-P matrix using electroless technique and their corrosion study. J Mater Eng Perform 25(10):4383–4393

    Article  Google Scholar 

  26. Shu X, Wang Y, Liu C, Gao W (2015) Microstructure and properties of Ni–B–TiO2 nano-composite coatings fabricated by electroless plating. Mater Technol 30(1):A41–A45

    Article  CAS  Google Scholar 

  27. Franco M, Sha W, Malinov S, Rajendran R (2013) Phase composition, microstructure and microhardness of electroless nickel composite coating co-deposited with SiC on cast aluminium LM24 alloy substrate. Surf Coat Technol 235:755–763

    Article  CAS  Google Scholar 

  28. Ma C, Wu F, Ning Y, Xia F Liu Y (2014) Effect of heat treatment on structures and corrosion characteristics of electroless Ni–P–SiC nanocomposite coatings. Ceram Int 40(7):9279–9284

    Article  CAS  Google Scholar 

  29. Balaraju JN Rajam KS (2005) Electroless deposition of Ni-Cu-P, Ni-W-P and Ni-W-Cu-P alloy. Surf Coat Technol 195(2–3):154–161,

    Article  CAS  Google Scholar 

  30. Wu X, Mao J, Zhang Z, Che Y (2015) Improving the properties of 211Z Al alloy by enhanced electroless Ni–P–TiO2 nanocomposite coatings with TiO2 sol. Surf Coat Technol 270:170–174

    Article  CAS  Google Scholar 

  31. Balaraju J, Narayana TS (2001) Evaluation of the corrosion resistance of electroless Ni-P and Ni-P composite coating by electrochemical impedance spectroscopy, J Solid State Electrochem 5:334–338

    Article  CAS  Google Scholar 

  32. Zhou YR, Zhang S, Nie LL (2016) Electro deposition and corrosion resistance of Ni–P–TiN composite coating on AZ91D magnesium alloy. Trans Nonferr Metals Soc China 26(11):2976–2987

    Article  CAS  Google Scholar 

  33. Ranganatha S, Venkatesha TV (2012) Studies on the preparation and properties of electroless Ni–W–P alloy coatings and its nano-MoS2 composite. Phys Scr 85(3):035601

    Article  Google Scholar 

  34. Hu J, Fang L, Liao X-L, Shi L-T (2017) Influences of different reinforcement particles on performances of electroless composites. Surf Eng Vol 33(5):362–368

    Article  CAS  Google Scholar 

  35. Faraji S, Faraji AH, Noori SR (2014) An investigation on electroless Cu–P composite coatings with micro and nano-SiC particles. Mater Des 54:570–575

    Article  CAS  Google Scholar 

  36. Allahkaram SR, Alivand RF, Bakhsh MS (2013) Corrosion behavior of electroless Ni-P/Ni-P-ZnO coatings. Iran J Mater Sci Eng 10(1):10–17

    CAS  Google Scholar 

  37. Yang Z, Xu H, Li M, Shi Y, Huang Y, Li H (2004) Preparation and properties of Ni/P single-walled carbon nanotubes composite coatings by means of electroless platin. Thin Solid Films 466:86–91

    Article  CAS  Google Scholar 

  38. Gadhari P, Sahoo P (2014) Effect of process parameters on microhardness of Ni–P–Al2O3 composite coatings. Proc Mater Sci 6:623–632

    Article  CAS  Google Scholar 

  39. Zhang S, Han K, Cheng L (2008) The effect of SiC particles added in electroless Ni–P plating solution on the properties of composite coatings. Surf Coat Technol 202(12):2807–2812

    Article  CAS  Google Scholar 

  40. Wanga H-L, Liu L-Y Dou Y et al (2013) Preparation and corrosion resistance of electroless Ni-P/SiC functionally gradient coatings on AZ91D magnesium alloy. Appl Surf Sci 286:319–327

    Article  Google Scholar 

  41. Chen HJ, Wang LL, Huang WQ Hao L (2010) Corrosion characteristics of electroless Ni–P Coatings deposited on W–Cu composite. Corros Eng Sci Technol 45(3):235–239

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Vinod Babu Chintada.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chintada, V.B., Koona, R. Influence of SiC Nano Particles on Microhardness and Corrosion Resistance of Electroless Ni–P Coatings. J Bio Tribo Corros 4, 68 (2018). https://doi.org/10.1007/s40735-018-0186-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s40735-018-0186-4

Keywords

Navigation