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Effect of solution concentration on the functional properties of ZnO nanostructures: Role of Hexamethylenetetramine

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Abstract

In this research, ZnO nanorods have been successfully synthesized via wet chemical method. XRD results revealed the single phase nature with the wurtzite structure of the as prepared ZnO nanorods. By only varying the concentration of Hexamethylenetetramine (HMT) in the solution, morphology of ZnO changed from hexagonal facet nanorods to pencil like nanorods and size of nanorods also changed. The band gap of as-synthesized ZnO nanorods was found to increase with increasing the concentration of HMT in the solution. The narrow full-width at half-maximum (FWHM) of the UV emission of PL spectra indicated that the grown ZnO nanorods have high crystal quality and is well matched with the obtained XRD results. These results revealed that the concentration of Hexamethylenetetramine plays a vital role to control the properties of ZnO nanorods.

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References

  1. U. Ozgur, Y. I. Alivov, C. Liu, A. Teke, M. A. Reshchikov, S. Dogan, V. Avrutin, S. J. Cho, and H. Morkoć, J. Appl. Phys. 98, 041301 (2005).

    Article  Google Scholar 

  2. D. P. Norton, Y. W. Heo, M. P. Ivill, K. Ip, S. J. Pearton, M. F. Chisholm, and T. Steiner, Mater. Today 7, 34 (2004).

    Article  CAS  Google Scholar 

  3. S. Sahoo and A. K. Bhowmick, J. Appl. Polym. Sci. 106, 3077 (2007).

    Article  CAS  Google Scholar 

  4. Z. P. Sun, L. Liu, L. Zhang, and D. Z. Jia, Nanotechnology 17, 2266 (2006).

    Article  CAS  Google Scholar 

  5. C. W. Nahm, Ceram. Int. 35, 541 (2009).

    Article  CAS  Google Scholar 

  6. L. Zhang, Y. Jiang, Y. Ding, M. Povey, and D. York, J. Nanopart. Res. 9, 479 (2007).

    Article  Google Scholar 

  7. M. S. Kim, T. H. Kim, D. Y. Kim, D. Y. Lee, S. O. Kim, and J. Y. Leem, Electron. Mater. Lett. 8, 123 (2012).

    Article  CAS  Google Scholar 

  8. H. H. Kim, J. Y. Moon, and H. S. Lee, Electron. Mater. Lett. 7, 59 (2011).

    Article  CAS  Google Scholar 

  9. G. M. Nam and M. S. Kwon, Electron. Mater. Lett. 7, 127 (2011).

    Article  CAS  Google Scholar 

  10. A. M. Morales and C. M. Libber, Science 279, 208 (1998).

    Article  CAS  Google Scholar 

  11. H. Dai, E. W. Wong, Y. Z. Lu, F. Shoushan, and C. M. Libber, Nature 375, 769 (1995).

    Article  CAS  Google Scholar 

  12. W. Q. Ham, S. S. Fan, Q. Q. Li, and Y. D. Hu, Science 277, 1287 (1997).

    Article  Google Scholar 

  13. J. H. Zhang, X. G. Yang, D. W. Wang, S. D. Li, Y. Xie, Y. N. Xia, and Y. T. Qian, Adv. Mater. 12, 1348 (2000).

    Article  Google Scholar 

  14. J. H. Hu, T. W. Odom, and C. M. Libber, Acc. Chem. Res. 32, 435 (1999).

    Article  CAS  Google Scholar 

  15. X. Wang and Y. Li, J. Am. Chem. Soc. 124, 2880 (2002).

    Article  CAS  Google Scholar 

  16. Y. W. Zhu, H. Z. Zhang, X. C. Sun, S. Q. Feng, J. Xu, Q. Zhao, B. Xiang, R. M. Wang, and D. P. Yu, Appl. Phys. Lett. 83, 144 (2003).

    Article  CAS  Google Scholar 

  17. K. B. Lee, K. S. Cho, and H. Kwon, Met. Mater. Int. 15, 649 (2009).

    Article  CAS  Google Scholar 

  18. J. S. Yi, J. Y. Kim, H. G. Jin, S. M. Song, C. H. Choi, W. T. Nichols, and W. I. Park, Met. Mater. Int. 18, 845 (2012).

    Article  CAS  Google Scholar 

  19. W. I. Park, Met. Mater. Int. 14, 659 (2008).

    Article  CAS  Google Scholar 

  20. Y. Qin, X. D. Wang, and Z. L. Wang, Nature 451, 809 (2008).

    Article  CAS  Google Scholar 

  21. M. Yang, G. F. Yin, Z. B. Huang, X. M. Liao, Y. Q. Kang, and Y. D. Yao, Appl. Surf. Sci. 254, 2917 (2008).

    Article  CAS  Google Scholar 

  22. F. Ahmed, S. Kumar, N. Arshi, M. S. Anwar, B. H. Koo, and C. G. Lee, Thin Solid Films 519, 8199 (2011).

    Article  CAS  Google Scholar 

  23. N. G. N. Angwafor and D. J. Riler, Phys. Status Solidi A, 205, 2351 (2008).

    Article  Google Scholar 

  24. P. X. Gao, Y. Ding, W. J. Mai, W. L. Hughes, C. S. Lao, and Z. L. Wang, Science 309, 1700 (2005).

    Article  CAS  Google Scholar 

  25. Y. J. Kim, J. Yoo, B. H. Kwon, Y. J. Hong, C. H. Lee, and G. C. Yi, Nanotechnology 19, 315202–1 (2008).

    Article  Google Scholar 

  26. F. Ahmed, S. Kumar, N. Arshi, M. S. Anwar, B. H. Koo, and C. G. Lee, Funct. Mater. Lett. 4, 1 (2011).

    Article  Google Scholar 

  27. M. H. Huang, Y. Y. Wu, H. Feick, N. Tran, E. Weber, and P. H. Yang, Adv. Mater. 13, 113 (2001).

    Article  CAS  Google Scholar 

  28. Y. Segawa, A. Ohtomo, M. Kawasaki, H. Koinuma, Z. K. Tang, P. Yu, and G. K. L. Wong, Phys. Status Solid. 202, 669 (1997).

    Article  CAS  Google Scholar 

  29. J. Y. Park, D. J. Lee, and S. S. Kim, Nanotechnology, 16, 2044 (2005).

    Article  CAS  Google Scholar 

  30. M. Ohyama, H. Kozuka, and T. Yoko, Thin Solid Films 306, 78 (1997).

    Article  CAS  Google Scholar 

  31. A. Dev, S. Kar, S. Chakrabarti, and S. Chaudhuri, Nanotechnology 17, 1533 (2006).

    Article  CAS  Google Scholar 

  32. L. Guo, Y. L. Ji, H. Xu, P. Simon, and Z. Wu, J. Am. Chem. Soc. 124, 14864 (2002).

    Article  CAS  Google Scholar 

  33. J. Zhang, L. D. Sun, C. S. Liao, and C. H. Yan, Chem. Commun. 262 (2002).

  34. O. Milosevic and D. Uskokovic, Mater. Sci. Eng. A. 168, 249 (1993).

    Article  Google Scholar 

  35. L. Vayssieres, Adv. Mater. 15, 464 (2003).

    Article  CAS  Google Scholar 

  36. J. H. Kim, D. Andeen, and F. F. Lange, Adv. Mater. 18, 2453 (2006).

    Article  CAS  Google Scholar 

  37. S. T. Tan, B. J. Chen, X. W. Sun, W. J. Fan, H. S. Kwok, X. H. Zhang, and S. J. Chua, J. Appl. Phys. 98, 013505 (2005).

    Article  Google Scholar 

  38. J. J. Wu and S. C. Liu, Adv. Mater. 14, 215 (2002).

    Article  CAS  Google Scholar 

  39. A. F. Kohan, G. Ceder, D. Morgan, and C. G. Van de Walle, Phys. Re. 61, 15019 (2000).

    Article  CAS  Google Scholar 

  40. C. G. Van de Walle, Physica B. 899, 308 (2001).

    Google Scholar 

  41. C. H. Hung and W. T. Whang, Mater. Chem. Phys. 82, 705 (2003).

    Article  CAS  Google Scholar 

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Correspondence to Bon Heun Koo.

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Heo, S.N., Park, K.Y., Seo, Y.J. et al. Effect of solution concentration on the functional properties of ZnO nanostructures: Role of Hexamethylenetetramine. Electron. Mater. Lett. 9, 261–265 (2013). https://doi.org/10.1007/s13391-013-2223-2

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  • DOI: https://doi.org/10.1007/s13391-013-2223-2

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