Abstract
Magnesite formed at relatively low temperatures, 40°C, and atmospheric pressure using the experimental duplications is described in Deelman (1999). The original experiment itself is a variation of Liebermann’s (1967) experiments on dolomite formation. The initial products of the reaction were metastable carbonates, aragonite and dypingite which will change during the course of the experiment into magnesite. This work reports to have found evidence in support of an active role of alternations between precipitation and dissolution in bringing about a formation of the thermodynamically stable phase in the magnesite formation.
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References
Brady PV, Krumhansl JL, Papenguth HW (1996) Surface complexation clues to dolomite growth. Geochim Cosmochim Acta 60:727–731
Deelman JC (1999) Low-temperature nucleation of magnesite and dolomite. Neues Jahrbuch für Mineralogie, Monatshefte 7:289–302
Deelman JC (2001) Breaking Ostwald’s rule. Chemie der Erde 61:224–235
Kinsman DJ (1967) Huntite from a carbonate-evaporite environment. Am Mineral 52:1332–1340
Langmuir D (1965) Stability of carbonates in the system MgO–CO2–H2O. J Geol 73:730–754
Liebermann O (1967) Synthesis of dolomite. Nature 213:241–245
Möller P (1989) Nucleation processes of magnesite. In: Möller P (ed) Magnesite, pp 287–292. Geology, mineralogy, geochemistry, formation of Mg-carbonates: Berlin u. Stuttgart, Borntraeger, p 300
Sayles FL, Fyfe WS (1973) The crystallization of magnesite from aqueous solution. Geochim Cosmochim Acta 37:87–99
von der Borch CC (1965) The distribution and preliminary geochemistry of modern carbonate sediments of the Coorong area, South Australia. Geochim Cosmochim Acta 29:781–799
Warren JK (1990) Sedimentology and mineralogy of dolomitic Coorong lakes, South Australia. J Sed Petrol 60:843–858
Acknowledgments
This work was financed by the Institut de Recherche pour le Développement (IRD), Paris, France. We would like to thank Dr. J. C. Deelman (Eindhoven, The Netherlands) for numerous e-mails on the finer details of his experiments.
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dos Anjos, A.P.A., Sifeddine, A., Sanders, C.J. et al. Synthesis of magnesite at low temperature. Carbonates Evaporites 26, 213–215 (2011). https://doi.org/10.1007/s13146-011-0063-4
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DOI: https://doi.org/10.1007/s13146-011-0063-4