Skip to main content
Log in

Effects of Iron Contamination and Hydrogen Passivation on the Electrical Properties of Oxygen Precipitates in CZ-Si

  • Topical Collection: 17th Conference on Defects (DRIP XVII)
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

Oxygen precipitates (OPs) are unavoidably formed in Czochralski silicon (CZ-Si) containing relatively high concentrations of oxygen. The recombination behavior of such defects is also vital for bulk devices like solar cells as they can reduce the minority carrier lifetime and degrade the cell performance. In our experiments, the characteristics of oxygen precipitation in n-type CZ-Si are systematically investigated by means of Fourier transform infrared spectroscopy (FTIR), deep level transient spectroscopy (DLTS) and electron beam induced current (EBIC). It is found that the iron contamination in n-type CZ-Si can strongly influence the OPs generation and their electrical properties, whereas the hydrogen passivation can effectively reduce the recombination activity of OPs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Bender, J. Vanhellemont, in MRS Online Proceedings Library Archive, vol. 262 (1992).

  2. T. Tan and W. Tice, Philos. Mag. 34, 615 (1976).

    Article  Google Scholar 

  3. D.R. Yang, X.Y. Ma, R.X. Fan, J.X. Zhang, L.B. Li, and D.L. Que, Physica B 273–274, 308 (1999).

    Article  Google Scholar 

  4. X.G. Yu, D.R. Yang, X.Y. Ma, and D.L. Que, Microelectron. Eng. 69, 97 (2003).

    Article  Google Scholar 

  5. H. Li, D. Yang, X. Yu, X. Ma, D. Tian, L. Li, and D. Que, J. Phys. Condens. Matter 16, 5745 (2004).

    Article  Google Scholar 

  6. J.H. Chen, D.R. Yang, H. Li, X.Y. Ma, and D.L. Que, J. Appl. Phys. 99, 073509 (2006).

    Article  Google Scholar 

  7. C. Gao, X.Y. Ma, J.J. Zhao, and D.R. Yang, J. Appl. Phys. 113, 093511 (2013).

    Article  Google Scholar 

  8. L. Chen, X. Yu, P. Chen, P. Wang, X. Gu, J. Lu, and D. Yang, Sol. Energy Mater. Sol. Cells 95, 3148 (2011).

    Article  Google Scholar 

  9. J.D. Murphy, K. Bothe, M. Olmo, V.V. Voronkov, and R.J. Falster, J. Appl. Phys. 110, 053713 (2011).

    Article  Google Scholar 

  10. V. Lang, J.D. Murphy, R. Falster, and J. Morton, J. Appl. Phys. 111, 013710 (2012).

    Article  Google Scholar 

  11. J.-M. Hwang and D. Schroder, J. Appl. Phys. 59, 2476 (1986).

    Article  Google Scholar 

  12. J. Vanhellemont, E. Simoen, A. Kaniava, M. Libezny, and C. Claeys, J. Appl. Phys. 77, 5669 (1995).

    Article  Google Scholar 

  13. K. Schmalz, F.G. Kirscht, and K. Tittelbach-Helmrich, Phys. Status Solidi (a) 109, 279 (1988).

    Article  Google Scholar 

  14. J.D. Murphy, K. Bothe, V. Voronkov, and R. Falster, Appl. Phys. Lett. 102, 042105 (2013).

    Article  Google Scholar 

  15. A. Istratov, H. Hieslmair, and E. Weber, Appl. Phys. A 70, 489 (2000).

    Article  Google Scholar 

  16. H. Hieslmair, A. Istratov, C. Flink, S. McHugo, and E. Weber, Phys. B: Condens. Matter 273, 441 (1999).

    Article  Google Scholar 

  17. H. Harada, T. Abe, and J. Chikawa, Abe, and BO Kolbesen (Pennington: The Electrochemical Society, 1986), p. 76.

    Google Scholar 

  18. B. Hackl, K.J. Range, H. Gores, L. Fabry, and P. Stallhofer, J. Electrochem. Soc. 139, 3250 (1992).

    Article  Google Scholar 

  19. B. Shen, J. Jablonski, T. Sekiguchi, and K. Sumino, Jpn. J. Appl. Phys. 35, 4187 (1996).

    Article  Google Scholar 

  20. W. Seifert and J. Vanhellemont, Mater. Sci. Eng. B 42, 260 (1996).

    Article  Google Scholar 

  21. S. Narayanan, S. Wenham, and M. Green, Appl. Phys. Lett. 48, 873 (1986).

    Article  Google Scholar 

  22. S.M. Myers, M. Seibt, and W. Schröter, J. Appl. Phys. 88, 3795 (2000).

    Article  Google Scholar 

  23. I. Périchaud, Sol. Energy Mater. Sol. Cells 72, 315 (2002).

    Article  Google Scholar 

  24. M. Seibt, A. Sattler, C. Rudolf, O. Voß, V. Kveder, and W. Schröter, Phys. Status Solidi (a) 203, 696 (2006).

    Article  Google Scholar 

  25. O. Schultz, S. Glunz, S. Riepe, and G. Willeke, Prog. Photovolt. Res. Appl. 14, 711 (2006).

    Article  Google Scholar 

  26. C. Dube, J. Hanoka, and D. Sandstrom, Appl. Phys. Lett. 44, 425 (1984).

    Article  Google Scholar 

  27. M. Kittler, C. Ulhaq-Bouillet, and V. Higgs, J. Appl. Phys. 78, 4573 (1995).

    Article  Google Scholar 

  28. R. Einhaus, F. Duerinckx, E. Van Kerschaver, J. Szlufcik, F. Durand, P. Ribeyron, J. Duby, D. Sarti, G. Goaer, and G. Le, Mater. Sci. Eng. B 58, 81 (1999).

    Article  Google Scholar 

  29. G. Hahn and A. Schönecker, J. Phys. Condens. Matter 16, R1615 (2004).

    Article  Google Scholar 

  30. L. Song, X. Zheng, J. Fu, and Z. Ji, J. Alloy. Compd. 698, 892 (2017).

    Article  Google Scholar 

  31. L. Song, M. Xie, X. Yu, and D. Yang, Appl. Phys. Lett. 111, 152103 (2017).

    Article  Google Scholar 

  32. L. Song, A. Wenham, and S. Wenham, Sol. Energy Mater. Sol. Cells 149, 221 (2016).

    Article  Google Scholar 

  33. B. Hallam, C. Chan, M. Abbott, and S. Wenham, Sol. Energy Mater. Sol. Cells 141, 125 (2015).

    Article  Google Scholar 

  34. A.Y. Liu, C. Sun, V.P. Markevich, A.R. Peaker, J.D. Murphy, and D. Macdonald, J. Appl. Phys. 120, 193103 (2016).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Xuegong Yu or Deren Yang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Li, J., Song, L., Yu, X. et al. Effects of Iron Contamination and Hydrogen Passivation on the Electrical Properties of Oxygen Precipitates in CZ-Si. J. Electron. Mater. 47, 5039–5044 (2018). https://doi.org/10.1007/s11664-018-6299-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-018-6299-1

Keywords

Navigation