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Experimental Determination of Impurity and Interdiffusion Coefficients in Seven Ti and Zr Binary Systems Using Diffusion Multiples

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Abstract

Diffusion coefficients of seven binary systems (Ti-Mo, Ti-Nb, Ti-Ta, Ti-Zr, Zr-Mo, Zr-Nb, and Zr-Ta) at 1200 °C, 1000 °C, and 800 °C were experimentally determined using three Ti-Mo-Nb-Ta-Zr diffusion multiples. Electron probe microanalysis (EPMA) was performed to collect concentration profiles at the binary diffusion regions. Forward simulation analysis (FSA) was then applied to extract both impurity and interdiffusion coefficients in Ti-rich and Zr-rich part of the bcc phase. Excellent agreements between our results and most of the literature data validate the high-throughput approach combining FSA with diffusion multiples to obtain a large amount of systematic diffusion data, which will help establish the diffusion (mobility) databases for the design and development of biomedical and structural Ti alloys.

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Acknowledgments

All diffusion profile data produced in this study have been deposited to the NIST Materials Data Repository (http://hdl.handle.net/11256/602). The authors are thankful to Ms. Julie Chouinard for her help with EPMA performed at the CAMCOR Facilities of the University of Oregon. This study is supported by the U.S. National Science Foundation (NSF) under Grant number CMMI-1333999, and it is part of the NSF Designing Materials to Revolutionize and Engineer our Future (DMREF) program.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, The Ohio State University, Columbus, OH, 43210, USA

    Zhangqi Chen & Ji-Cheng Zhao

  2. Department of Materials Science and Engineering, The Pennsylvania State University, University Park, PA, 16802, USA

    Zi-Kui Liu

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  1. Zhangqi Chen
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  2. Zi-Kui Liu
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  3. Ji-Cheng Zhao
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Correspondence to Ji-Cheng Zhao.

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Manuscript submitted December 5, 2017.

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Chen, Z., Liu, ZK. & Zhao, JC. Experimental Determination of Impurity and Interdiffusion Coefficients in Seven Ti and Zr Binary Systems Using Diffusion Multiples. Metall Mater Trans A 49, 3108–3116 (2018). https://doi.org/10.1007/s11661-018-4645-9

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  • DOI: https://doi.org/10.1007/s11661-018-4645-9

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