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Journal of Mathematical Chemistry

, Volume 52, Issue 9, pp 2411–2422 | Cite as

An exact analytical solution to the master equation for the vibration–dissociation process of Morse oscillators

  • Mikhail L. Strekalov
Original Paper

Abstract

The coupled vibration–dissociation process for Morse oscillators and structureless particles has been examined. A method to solve the appropriate master equation is developed. The case has been studied carefully where the dissociation process starts mainly from the bound level nearest to the dissociation limit. The master equation has an exact analytical solution in this case upon many-quantum transitions and for an arbitrary amount of energy transferred per collision. Simple expressions for the steady-state dissociation rate and for the incubation time are obtained.

Keywords

Vibration–dissociation processes Master equation Transition probability Shock-heated molecules Orthogonalization procedure 

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Copyright information

© Springer International Publishing Switzerland 2014

Authors and Affiliations

  1. 1.Theoretical Chemistry Laboratory, Institute of Chemical Kinetics and CombustionSiberian Branch of the Russian Academy of SciencesNovosibirskRussia

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