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High-Nuclearity Silver-alkynyl Cluster Encapsulating Two Carbonates Generated from Atmospheric Carbon Dioxide Fixation and Co-protected by Diphenylphosphinate Ligands

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Abstract

For investigating the template effects and the ligand roles in constructing structurally charming silver clusters, we isolated and analyzed a new cluster compound, namely, [(CO3)2@Ag25(C≡CtBu)15(CF3CO2)3(Ph2PO2)2I],1. We report here the synthesis, crystal structure, characterization by various spectroscopic (IR, solid-state NMR, XPS) techniques and the luminescent property of this cluster. Its X-ray crystal structure reveals that the cluster is a 25-nuclearity silver cage with double CO32− ions encapsulated in. Two diphenylphosphinates in new coordination mode (μ2:O1,O1) are co-protecting on the surface of cluster 1. Also, the cluster emits orange-red light in the solid-state at 77 K.

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References

  1. Z. Wang, R. K. Gupta, G. Luo, and D. Sun (2019). Chem. Rec. https://doi.org/10.1002/tcr.201900049.

    Article  PubMed  Google Scholar 

  2. A. K. Gupta and A. Orthaber (2018). Chem. Eur. J. 24, 7536–7559.

    CAS  PubMed  Google Scholar 

  3. Y. Xie, J. Jin, G. Duan, X. Lu, and T. C. W. Mak (2017). Coord. Chem. Rev. 331, 54–72.

    CAS  Google Scholar 

  4. G. Luo, Z. Wang, L. P. Cheng, Q. Q. Zhao, X. P. Wang, and D. Sun (2017). Sci. Sin. Chim. 47, 695–704.

    Google Scholar 

  5. Z. Lei, X. Wan, S. F. Yuan, J. Wang, and Q. M. Wang (2017). Dalton Trans. 46, 3427–3434.

    CAS  PubMed  Google Scholar 

  6. Q.-M. Wang, Y.-M. Lin, and K.-G. Liu (2015). Acc. Chem. Rev. 48, 1570–1579.

    CAS  Google Scholar 

  7. R. A. J. O’Hair (2019). Aust. J. Chem. 72, 923–926.

    Google Scholar 

  8. H. Schmidbaur and A. Schier (2015). Angew. Chem. Int. Ed. 54, 746–784.

    CAS  Google Scholar 

  9. J.-Y. Wang, K.-G. Liu, Z.-J. Guan, Z.-A. Nan, Y.-M. Lin, and Q.-M. Wang (2016). Inorg. Chem. 55, 6833–6835.

    CAS  PubMed  Google Scholar 

  10. J.-Z. Li, F. Bigdeli, X.-M. Gao, R. Wang, X.-W. Wei, X.-W. Yan, M.-L. Hu, K.-G. Liu, and A. Morsali (2019). Inorg. Chem. 58, 5397–5400.

    CAS  PubMed  Google Scholar 

  11. K.-G. Liu, X.-Y. Liu, Z.-J. Guan, K. Shi, Y.-M. Lin, and Q.-M. Wang (2016). Chem. Commun. 52, 3801–3804.

    CAS  Google Scholar 

  12. K.-G. Liu, S.-K. Chen, Y.-M. Lin, and Q.-M. Wang (2015). Chem. Commun. 51, 9896–9898.

    CAS  Google Scholar 

  13. S.-D. Bian, H.-B. Wu, and Q.-M. Wang (2009). Angew. Chem. Int. Ed. 48, 5363–5365.

    CAS  Google Scholar 

  14. B. Li, J. Liao, Y. Li, and C. W. Liu (2013). Cryst. Eng. Comm. 15, 6140–6143.

    CAS  Google Scholar 

  15. S. C. K. Hau, P. Cheng, and T. C. W. Mak (2014). Organometallics 33, 3231–3234.

    CAS  Google Scholar 

  16. J. Qiao, K. Shi, and Q.-M. Wang (2010). Angew. Chem. Int. Ed. 49, 1765–1767.

    CAS  Google Scholar 

  17. Y. Li, F. Gao, J. E. Beves, Y. Li, and J. Zuo (2013). Chem. Commun. 49, 3658–3660.

    CAS  Google Scholar 

  18. Z.-G. Jiang, K. Shi, Y.-M. Lin, and Q.-M. Wang (2014). Chem. Commun. 50, 2353–2355.

    CAS  Google Scholar 

  19. D. B. Dell’Amico, F. Calderazzo, L. Labella, F. Marchetti, and G. Pampaloni (2003). Chem. Rev. 103, 3857–3898.

    PubMed  Google Scholar 

  20. J. Shi, X. Gao, Y. Feng, K. Zhou, J. Ji, and Y. Bi (2019). Inorg. Chim. Acta 497, 119107.

    CAS  Google Scholar 

  21. S. D. Bian, J. H. Jia, and Q. M. Wang (2009). J. Am. Chem. Soc. 131, 3422–3423.

    CAS  PubMed  Google Scholar 

  22. F. Gruber and M. Jansen (2010). Angew. Chem. Int. Ed. 49, 4924–4926.

    CAS  Google Scholar 

  23. D. Sun, H. Wang, H. Lu, S. Feng, Z. Zhang, G. Sun, and D.-F. Sun (2013). Dalton Trans. 42, 6281–6284.

    CAS  PubMed  Google Scholar 

  24. K. Zhou, C. Qin, X. Wang, K. Shao, L. Yan, and Z. M. Su (2014). Cryst. Eng. Comm. 16, 7860–7864.

    CAS  Google Scholar 

  25. Z. Wang, X. Li, L. Liu, S. Yu, Z. Feng, C. Tung, and D. Sun (2016). Chem. Eur. J. 22, 6830–6836.

    CAS  PubMed  Google Scholar 

  26. P. Liao, K. Liu, C. Fang, Y. Wu, and C. W. Liu (2019). J. Cluster Sci. 30, 1185–1193.

    CAS  Google Scholar 

  27. K.-G. Liu, X.-W. Wei, F. Bigdeli, X.-M. Gao, J.-Z. Li, X.-W. Yan, M.-L. Hu, and A. Morsali (2020). Inorg. Chem. 59, 2248–2254.

    CAS  PubMed  Google Scholar 

  28. C. E. Housecroft (1994). Coord. Chem. Rev. 131, 1–43.

    CAS  Google Scholar 

  29. X.-J. Zou, S. Jin, and W.-J. Du (2017). Nanoscale 9, 16800–16805.

    CAS  PubMed  Google Scholar 

  30. M. S. Bootharaju, R. Dey, L. E. Gevers, M. N. Hedhili, J. M. Basset, and O. M. Bakr (2016). J. Am. Chem. Soc. 138, 13770–13773.

    CAS  PubMed  Google Scholar 

  31. Z. Han, X. Dong, P. Luo, S. Li, Z. Wang, S. Zang, and T. C. W. Mak (2020). Sci. Adv. 6, eaay0107.

    CAS  PubMed  PubMed Central  Google Scholar 

  32. Z. Wang, H.-F. Su, Y.-Z. Tan, S. Schein, S.-C. Lin, W. Liu, S.-A. Wang, W.-G. Wang, C.-H. Tung, D. Sun, and L.-S. Zheng (2017). Proc. Natl. Acad. Sci. 114, 12132–12137.

    CAS  PubMed  Google Scholar 

  33. Z. Wang, H.-F. Su, M. Kurmoo, C.-H. Tung, D. Sun, and L.-S. Zheng (2018). Nat. Commun. 9, 2094.

    PubMed  PubMed Central  Google Scholar 

  34. Z. Wang, H.-F. Su, C.-H. Tung, D. Sun, and L.-S. Zheng (2018). Nat. Commun. 9, 4407.

    PubMed  PubMed Central  Google Scholar 

  35. J.-W. Liu, L. Feng, H.-F. Su, Z. Wang, Q.-Q. Zhao, X.-P. Wang, C.-H. Tung, D. Sun, and L.-S. Zheng (2018). J. Am. Chem. Soc. 140, 1600–1603.

    CAS  PubMed  Google Scholar 

  36. K. Tang, X.-L. Jin, H. Yan, X.-J. Xie, C.-L. Liu, and Q.-H. Gong (2001). J. Chem. Soc., Dalton Trans. 8, 1374–1377.

    Google Scholar 

  37. I. Chakraborty, W. Kurashige, K. Kanehira, L. Gell, H. Häkkinen, Y. Negishi, and T. Pradeep (2013). J. Phys. Chem. Lett. 4, 3351–3355.

    CAS  PubMed  Google Scholar 

  38. C. Nitschke, A. I. Wallbank, D. Fenske, and J. F. Corrigan (2007). J. Clust. Sci. 18, 131–140.

    CAS  Google Scholar 

  39. I. Chakraborty and T. Pradeep (2014). J. Phys. Chem. Lett. 6, 14190–14194.

    CAS  Google Scholar 

  40. S.-S. Zhang, F. Alkan, H.-F. Su, C. M. Aikens, C.-H. Tung, and D. Sun (2019). J. Am. Chem. Soc. 141, 4460–4467.

    CAS  PubMed  Google Scholar 

  41. Z. Wang, H.-T. Sun, M. Kurmoo, Q.-Y. Liu, G.-L. Zhuang, Q.-Q. Zhao, X.-P. Wang, C.-H. Tung, and D. Sun (2019). Chem. Sci. 10, 4862–4867.

    CAS  PubMed  PubMed Central  Google Scholar 

  42. Y.-P. Xie and T. C. W. Mak (2011). J. Am. Chem. Soc. 133, 3760–3763.

    CAS  PubMed  Google Scholar 

  43. L. Zhao, C. Wan, J. Han, X. Chen, and T. C. W. Mak (2008). Chem. Eur. J. 14, 10437–10444.

    CAS  PubMed  Google Scholar 

  44. G. M. Sheldrick SADABS (University of Göttingen, Germany, 1996).

    Google Scholar 

  45. G. M. Sheldrick (1990). Acta Crystallogr. A 46, 467–473.

    Google Scholar 

  46. G. M. Sheldrick (2015). Acta Crystallogr. C Struct. Chem. 71, 3–8.

    PubMed  PubMed Central  Google Scholar 

  47. G. M. Sheldrick Program for the Solution and Refinement of Crystal Structures (University of Göttingen, Germany, 1997), p. 1997.

    Google Scholar 

  48. G. M. Sheldrick, SHELXTL: release 4.1 for Siemens Crystallographic Research Systems (1990).

  49. A. L. Spek (2015). Acta Cryst. C71, 9–18.

    Google Scholar 

  50. M. S. Fallah, C. E. Anson, D. Fenske, and A. Rothenberger (2005). Dalton Trans. 13, 2300–2304.

    Google Scholar 

  51. J. Yan, C. Wang, H. Xu, Y. Xu, X. She, J. Chen, Y. Song, H. Li, and Q. Zhang (2013). Appl. Surf. Sci. 287, 178–186.

    CAS  Google Scholar 

  52. P. Käll, J. Grins, M. Fahlman, and F. Söderlind (2001). Polyhedron. 20, 2747–2753.

    Google Scholar 

  53. J. F. Moulder, W. F. Stickle, P. E. Sobol, and K. D. Bomben Handbook of X-ray Photoelectron Spectroscopy (Perkin-Elmer Corporation, Eden Prairie, 1992).

    Google Scholar 

  54. V. W. W. Yam and K. K. W. Lo (1999). Chem. Soc. Rev. 28, 323–334.

    CAS  Google Scholar 

  55. C. Yu, L. Wei, J. Chen, Y. Xie, W. Zhou, and Q. Fan (2014). Ind. Eng. Chem. Res. 53, 5759–5766.

    CAS  Google Scholar 

Download references

Acknowledgments

This work was also supported by the National Natural Science Foundation of China (Grand. No. 21601097), the Project of Key Research Plan of Ningxia (2018BEE03006), the Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering (Grant No. 2019-KF-01).

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Authors and Affiliations

  1. State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, Ningxia University, Yin-Chuan, 750021, People’s Republic of China

    Hong-Jing Li, Xue-Wen Wei & Kuan-Guan Liu

  2. Ningxia Key Laboratory for Photovoltaic Materials, Ningxia University, Yin-Chuan, 750021, People’s Republic of China

    Hong-Jing Li, Xue-Wen Wei & Kuan-Guan Liu

  3. College of Materials and Environmental Engineering and Guangxi Key Laboratory of Calcium Carbonate Resources Comprehensive Utilization, Hezhou University, Hezhou, Guangxi, 542800, People’s Republic of China

    Xiao-Wei Yan

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  1. Hong-Jing Li
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10876_2020_1802_MOESM1_ESM.docx

Supplementary material 1 (DOCX 238 kb) The structures reported herein have been deposited at the Cambridge Crystallographic Data Centre, CCDC 1979531. For ESI and crystallographic data in CIF or other electronic format see https://doi.org/10.1039/x0xx00000x

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Li, HJ., Wei, XW., Liu, KG. et al. High-Nuclearity Silver-alkynyl Cluster Encapsulating Two Carbonates Generated from Atmospheric Carbon Dioxide Fixation and Co-protected by Diphenylphosphinate Ligands. J Clust Sci 32, 437–443 (2021). https://doi.org/10.1007/s10876-020-01802-x

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