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Structure and Magnetic Properties of a 3d–4f-Doped Hexagonal Heterometallic Cluster

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Abstract

2-(2,3-Dihydroxpropyliminomethyl)6-methoxyphenol (H3L), trimethylacetic acid (Hpiv), Dy(NO3)3·6H2O and Co(NO3)2·6H2O were reacted at 80 °C to obtain a heterometallic hexanuclear cluster [Dy2Co4(L)2(μ3-OH)2(piv)8]·2Hpiv·2H2O (1). X-ray crystallographic study reveals that complex 1 displays a central planar butterfly motif consisting of the Dy III2 Co II2 , with another two CoII ions ‘‘capping’’ around the periphery of the butterfly. Magnetic studies suggest that 1 displays little out-of-phase component of the ac-susceptibilities in zero dc-field, and observed weak imaginary component.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21601038 and 51572050), Guangxi Natural Science Foundation (Nos. 2015GXNSFDA139007 and 2016GXNSFAA380085), Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials (EMFM20162107).

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Author notes

  1. Qi-Zhen Yang and Min-Jia Zheng have contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, People’s Republic of China

    Qi-Zhen Yang, Min-Jia Zheng, Hua-Hong Zou, Hai-Ling Wang, Dong-Cheng Liu, Yan-Cheng Liu & Fu-Pei Liang

  2. Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Fu-Pei Liang

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  1. Qi-Zhen Yang
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Correspondence to Hua-Hong Zou, Dong-Cheng Liu or Yan-Cheng Liu.

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Yang, QZ., Zheng, MJ., Zou, HH. et al. Structure and Magnetic Properties of a 3d–4f-Doped Hexagonal Heterometallic Cluster. J Clust Sci 30, 25–30 (2019). https://doi.org/10.1007/s10876-018-1455-6

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  • DOI: https://doi.org/10.1007/s10876-018-1455-6

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