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A Single-Molecule Magnet Tetranuclear [Mn III3 MnIVO3Cl] Complex with Bis(diisopropylphosphinyl)imide Ligands

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A Correction to this article was published on 29 October 2019

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Abstract

Treatment of Mn(OAc)2·4H2O with 3 equiv. HN(iPr2PO)2 in the presence of nBu4NCl in acetonitrile resulted in isolation of a tetranuclear {Mn III3 MnIV} complex [Mn4(μ3-O)3(μ3-Cl)(μ-OAc)3{N(iPr2PO)2}3]·0.5C6H14 (1·0.5C6H14), and a dinuclear {MnIIMnIII} complex [Mn2{N(iPr2PO)2}{μ2,η3-(iPrPO2)NH(iPr2PO)}2{η2-(iPrPO2)NH(iPr2PO)}2]·0.25AcOH (2·0.25AcOH) with bis(diisopropylphosphinyl)imide ligands. The solid-state structures of two complexes have been established by single-crystal X-ray crystallography. The tetranuclear complex 1 belongs to a family of {Mn III3 MnIVO3X} single-molecule magnets (SMMs) with effective energy barrier of 14.3 K by some further magnetic characterizations.

Graphical Abstract

A [Mn III3 MnIVO3Cl]-core-based [Mn4(μ3-O)3(μ3-Cl)(OAc)3{N(iPr2PO)2}3] complex with single-molecule magnet (SMM) behaviour was prepared and structurally characterized, exhibiting slow magnetization relaxation under zero applied dc field with τ0 = 9.0 × 10−7 s and relaxation barrier Ueff = 14.3 K.

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Change history

  • 29 October 2019

    The original version of this article unfortunately published with wrong author group. It also had several mistakes in text. The author group and errors are corrected in this erratum article.

  • 29 October 2019

    The original version of this article unfortunately published with wrong author group. It also had several mistakes in text. The author group and errors are corrected in this erratum article.

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Acknowledgements

This project was supported by the Natural Science Foundation of China (Grant No. 21471003). We thank Prof. Annie K. Powell for the magnetic measurements.

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Authors and Affiliations

  1. Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, 243002, Anhui, People’s Republic of China

    Ying Zhang, Jing-Jing Zhang, Ai-Quan Jia, Zhi-Feng Xin & Qian-Feng Zhang

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  1. Ying Zhang
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  2. Jing-Jing Zhang
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  3. Ai-Quan Jia
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  4. Zhi-Feng Xin
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  5. Qian-Feng Zhang
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Correspondence to Ai-Quan Jia or Qian-Feng Zhang.

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Zhang, Y., Zhang, JJ., Jia, AQ. et al. A Single-Molecule Magnet Tetranuclear [Mn III3 MnIVO3Cl] Complex with Bis(diisopropylphosphinyl)imide Ligands. J Clust Sci 29, 1345–1352 (2018). https://doi.org/10.1007/s10876-018-1442-y

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