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Cyan-Blue Luminescence and Antiferromagnetic Coupling of CN-Bridged Tetranuclear Complex Based on Manganese(III) Schiff Base and Hexacyanoferrate(III)

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Abstract

A new tetranuclear cyanide-bridged MnIII–FeIII complex based on manganese(III) Schiff base and hexacyanoferrate(III) units, [Mn(L)(MeOH)2][{Mn(L)}{Fe(CN)6}{Mn(L)(MeOH)}].2MeOH, [H2L = N,N′-bis(2-hydroxy-1-naphthalidenato)-1,2-diaminopropane] (1), has been synthesized and characterized by elemental analysis, UV–Vis, FT-IR, PXRD, single crystal X-ray analyses, magnetic and photoluminescence measurements. Complex 1 consist of one trinuclear cyanido-bridged anion, in which [Fe(CN)6]3− anion bridge [Mn(L)]+ and Mn(L)(MeOH)}]+ cations via two C≡N groups in the cis positions, and also one isolated manganese [Mn(L)(MeOH)2]+ cation. DC magnetic susceptibility and magnetization studies showed that complex 1 indicates an antiferromagnetic coupling between low-spin Fe(III) and high-spin Mn(III) through the cyanide bridges. In addition, the complex 1 displays a strong cyan-blue luminescence emission in the solid state condition at room temperature. This behavior might be seen easily from the chromaticity diagram. Thus, the complex may be a good promising cyan-blue OLED developing electroluminescent materials for flatted or curved panel display applications due to the fact that it has such features.

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Acknowledgements

The authors are grateful to the Research Funds of Muğla Sıtkı Koçman University (BAP–2018/008) for the financial support and Balikesir University, Science and Technology Application and Research Center (BUBTAM) for the use of the Photoluminescence Spectrometer. The authors are also very grateful to Prof. Dr. Andrea Caneschi (Laboratory of Molecular Magnetism, Department of Chemistry, University of Florence) for the use of SQUID magnetometer and helpful suggestions.

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Authors and Affiliations

  1. Department of Physics, Molecular Nano-Materials Laboratory, Mugla Sitki Kocman University, 48050, Mugla, Turkey

    Adem Donmez & Hulya Kara

  2. Scientific Research Projects Coordination Unit, Mugla Sitki Kocman University, 48050, Mugla, Turkey

    Adem Donmez

  3. Department of Physics, Balikesir University, 10145, Balikesir, Turkey

    Mustafa Burak Coban & Hulya Kara

  4. Center of Sci and Tech App and Research, Balikesir University, 10145, Balikesir, Turkey

    Mustafa Burak Coban

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  1. Adem Donmez
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Correspondence to Hulya Kara.

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Donmez, A., Coban, M.B. & Kara, H. Cyan-Blue Luminescence and Antiferromagnetic Coupling of CN-Bridged Tetranuclear Complex Based on Manganese(III) Schiff Base and Hexacyanoferrate(III). J Clust Sci 29, 951–958 (2018). https://doi.org/10.1007/s10876-018-1404-4

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